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Polycarbosilane lower the electronic structure and properties of PCS is a kind of high-molecular compound, the main chain by alternating silicon and carbon atoms of the silicon and carbon atoms are connected to hydrogen or organic group, molecular chains of linear or branch structure.

低聚碳硅烷的电子结构及其性质的研究聚碳硅烷是一类高分子化合物,其主链由硅和碳原子交替组成,硅和碳原子上连接有氢或有机基团,分子链为线形或枝化结构。

Alterations of country rocks are complicated and multiple, and mainly are silicification, talcization,biotitization and dolomitization, Quartzite at the bottom of the second formation of the Langshan Group is the result of silicification.

围岩蚀变类型较多而且复杂,主要有硅化、滑石化、黑云母化和白云岩化。狼山群第2岩组底部的石英岩是硅化作用的产物。

The main shortages in ferrosilicon disintegration and the cause are analysed.

分析了引起硅铁粉化的主要原因,提出了控制硅铁粉化的措施。

The measurement of 1/f noise in amorphous, microcrystalline and polymorphous silicon film was performanced with a self-design semiconductor system.

研究不同厚度的非晶、微晶和多形硅三种氢化硅薄膜的热导率结果表明微晶硅薄膜的晶化增大了薄膜的热导率。

The experimental results show that the content of SiC in RBSC increases with carbon content while α-SiC is chosen as a filler. However, the residual carbon would appear in specimens when the carbon content exceeds 30% by weight. Using carbon felt, the reaction-formed SiC particles are small and uniform in size and distribution. However, when carbon felt is impregnated with phenol resin, the reaction-formed SiC is nonuniform in size and distribution. X-ray diffraction shows that the fabricated RBSC is composed of α-SiC,β-SiC, and free Si. The polytype of SiC is related to the reaction-heat during sintering.

结果表明:选用α-SiC+C粉的混合物作为生坯,SiC相的体积分数随生坯中wC的增加而增加,但过大的wC将使硅化后的试样出现残碳;选用碳毡作为生坯,反应烧结碳化硅的显微组织特点是C/Si反应生成的碳化硅颗粒均匀细小,并呈线状分布在游离硅中;浸渍过树脂的碳毡硅化处理后的显微组织特点是反应生成的碳化硅颗粒粗大且呈不均匀分布。X射线衍射结果也表明,反应烧结碳化硅陶瓷由游离Si、α-SiC、β-SiC组成,试样中不同晶型碳化硅的出现与C/Si反应的放热过程有关。

Calculation of loss and gain of components in parentage and altered rocks during metasomatism, reveals that, in rubification and afforestation belts, the components brought in were K〓, CO〓, H〓O, and the components brought out were SiO〓, Ca〓 and Na〓, implying that the early ore-bearing hydrothermal fluids were rich in CO〓 and H〓O. SiO〓 brought out from potassic and chlorite alteration zones could serve as the main source for SiO〓 necessary in the formation of quartz veins, of silicification and of bericitization at shallow depth.

说明早期成矿流体为富含CO〓、H〓O等的碱性流体,其中钾化、绿化带中带出的SiO〓等是浅部石英脉、硅化、绢英岩化中硅质的主要来源,带出的Ca〓与成矿流体中的CO〓结合形成碳酸盐化,带出的Na〓则在浅部形成钠长石脉。

The chemistry behavior research of wollastonite indicated that the silicon-potassium fertilizer has a chemical active in organic acid.The factors affecting manurial effect of silicon-potassium fertilizer are not only soil pH and desilicification,but also content and type of organ in the soil.Wollastonite chemistry behavior indicates that silicic acid can be dissolved out from silicon-potassium fertilizer in chlorhydric acid solution if pH of solution is not smaller than 2. The drop of apparent density,increase of DBP sorptive rate and specific surface for leavings indicate that hydrated silicon oxide is polyporous,and those mineralogic feature presignify that silicon-potassium fertilizer has a role of conservation of both Moisture and Fertility and improving soil structure.After active ingredient releasing,silicon-potassium fertilizer leaves half the substance (non-active ingredient)in soil.

熟料单矿物在酸溶液中的化学行为研究表明,硅钾肥矿物在有机弱酸中的化学活性较好,影响硅钾肥肥效发挥的因素是土壤pH值和土壤的去硅化程度,还有土壤有机质的含量与种类;硅灰石在盐酸溶液中化学行为表明,在反应体系pH不小于2的情况下,硅钾肥矿物大量溶出硅酸根组分;溶解残余物表观密度降低、DBP吸着率和比表面积增加表明水合二氧化硅是以多孔形式存在,为硅钾肥具有保水保肥、改良土壤结构的提供了矿物学依据。

The result demonstrates that only a few phosphides contribute to spontaneous crumbing of the RE silicide alloy by reacting with water and forming oxide or phosphorus oxide. The phosphorus content is not the crucial factor of disintegration of the alloy studied.

结果表明:含磷稀土硅化物合金中只有少部分磷化物能够水化,生成氧化物或含磷氧化物,从而对合金粉化起作用;在本实验研究范围内,磷含量不是稀土硅化物合金粉化的决定因素。

In this project, we have prepared conveniently Si-Mg 1,1-difunctional group reagents-α-silylvinyl Grignard reagents by hydromagnesiation of alkynylsilanes; Se-Br 1,1-difunctional group reagents-α-bromovinylselenides by hydrobromination of alkynylselenides; Sn-Br and Sn-I 1,1-difunctional group reagents by hydrozirconation of alkynylstannanes followed by halogenating reaction.

本项目通过炔基硅烷的镁氢化反应,方便地制得了Si-Mg 1,1-双官能团试剂-α-硅基烯基镁化物;通过炔基硒醚的溴氢化反应,方便地制得了Se-Br 1,1-双官能试剂-α-溴代烯基硒醚;通过炔基锡烷的锆氢化反应,继而卤代方便地制得了Sn-Br和Sn-I 1,1-双官能试剂。

Silicified wood,also being called tree fossil or wood fossil,whatever its internal quality is much higher,it still has fossil identity and high quality silicified wood can not be called tree fossil jade.

硅化木,又称树化石、木化石,无论它的内在品质多么优良,依然是&化石&身份,不能把优质硅化木称为&树化玉&。

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