硅剂

Research on techniques for the synthesis of ACR impact modifier with core-shell structure;2. Preparation of polymer-tungsten-silica composite microspheres with multi-layer core-shell structures;3. Organosilicon-acrylate micro emulsion with core-shell structure was synthesized with OP-10,JFC and amyl alcohol nonionic compounded emulsifier by means of seeded emulsion polymerization.

运用种子乳液聚合工艺以OP-10/JFC/戊醇非离子复合乳化剂合成了具有核-壳结构的有机硅-丙烯酸酯微乳液，研究了复合乳化剂类型、丙烯酸酯单体、有机硅单体加入方式和含量、pH值、硫醇对微乳液聚合过程中稳定性和光泽度的影响，通过差示扫描量热仪和透射电镜对微乳液的结构进行了表征。

Organosilicon-acrylate micro emulsion with core-shell structure was synthesized with OP-10,JFC and amyl alcohol nonionic compounded emulsifier by means of seeded emulsion polymerization.

运用种子乳液聚合工艺以OP-10/JFC/戊醇非离子复合乳化剂合成了具有核-壳结构的有机硅-丙烯酸酯微乳液，研究了复合乳化剂类型、丙烯酸酯单体、有机硅单体加入方式和含量、pH值、硫醇对微乳液聚合过程中稳定性和光泽度的影响，通过差示扫描量热仪和透射电镜对微乳液的结构进行了表征。

Fujian Fuzhou SanBang chemical Industry Co., Ltd have developed and produced the invest casting S-GRJ-1430 and S-GRJ-830 colloidal silicon and exothermic padding with feedex for special purpose,and also produced the series colloidal silicon for fire resistant material,paint,food,battery and iron,and it concurrently manages many kinds of invest casting materials of antifoam agent,wetting agent,fused quarez powder and stone,mulgrain flour,mulgrain sand and slag catcher.

产品：精密铸造专用S-GRJ-1430、S-GRJ-830硅溶胶和冒口发热保温剂。耐火材料、涂料、食品、电池、钢铁专用系列硅溶胶。消泡剂、润湿刘、熔融石英砂粉、马来粉、马来砂、除渣剂等精密铸造辅料。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示：复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素，它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性，还有乳液涂膜的接触角等造成不同程度的影响；引发剂主要影响反应速率和凝胶率；丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度，有机硅单体主要影响涂膜的吸水率等；聚合反应温度主要影响乳液的反应速率和转化率等；搅拌强度主要是影响到聚合过程的凝胶率。

Using B Grade bauxite as bone material and A Grade bauxite as powder,different binder composition castable for permanent lining fo fundish were studied,with cyanite and sillimanite as expansion additives and Zimujie clay as sinter additive and plastic additive.

以B级高铝矾土熟料为骨料，A级矾土熟料为基质料，同时加入蓝晶石、硅线石为膨胀剂，紫木节粘土为烧结剂、塑化剂，研究了分别采用硅灰、高铝水泥、水玻璃、复合结合剂等为结合剂的不同配方组成的浇注料。

When TiO〓 content is increased, the surfacial energy formed by crystals may be reduced, the devitrification degree, strengthened and the content of wollastonite in crystal phase raised; if Cr〓O3〓 content is increased, the crystal size is enlarged, and the content of diopside in crystal phase, raised; if the sulphide content is increased; the reduction atmosphere is heightened and the content of wollastonite become bigger.

晶核剂浓度研究表明，晶核剂浓度不同，对基础玻璃析晶强度，晶相含量和晶体尺寸有一定的影响，当TiO〓含量增加时，可以降低晶体形成的表面能，析晶强度增大，晶相中硅灰石含量增多；Cr〓O〓含量增加，晶体尺寸增大，晶相中透辉石含量增加；硫化物增多，还原气氛增大，同时硅灰石含量增多。

The system is composed of polysilicic ions and polyaluminous ion s with the participation of polyaluminous ion s, the Si-O specific line which is inherent in the examination of infrared spectrum is gradually reducing and becoming a broad belt, the non-ion bond reactions between polysilicic ion and polyaluminous ion is proved by observasion with electron microscopy.

稳定胶体态的硫硅聚铝和氯硅聚铝是性能优良的絮凝剂，体系中含有聚硅离子和聚铝离子。红外光谱测试固有的Si—O特征峰随聚铝离子的引入逐渐衰减，变成较宽的带，聚硅离子与聚铝离子间存在着一种非离子性的健合作用，电镜摄像观察证实了这一结论

The method adopts the following steps: after mixed, phosphorus source, silicon source, aluminum source, an organic template agent, water and a precursor of the SAPO molecular sieve are hydrothermally crystallized for at least 0.1 hour at the temperature ranging from 110 to 260 DEG C to obtain the SAPO molecular sieve; wherein, the preparation method for the precursor of the SAPO molecular sieve has the following steps:, the molar ratio is 0.03 to 0.6 R:(Si0.01 to 0.98: Al 0.01 to 0.6: P0.01 to 0.6): 2 to 500 H2O; wherein, R stands for mixture solution of raw materials which is blended by the phosphorus source, the silicon source, the aluminum source, the an organic template agent and water of the template agent;, the mixture solution of raw materials prepared in step reacts at the temperature which is at least 50 DEG C lower than the crystallization temperature for at least 0.1 hour.

本发明通过采用包括以下步骤：将磷源、硅源、铝源、有机模板剂、水和SAPO分子筛前驱体混合后在110～260℃的温度下水热晶化至少0.1小时获得SAPO分子筛；其中SAPO分子筛的前驱体的制备包括以下步骤：将摩尔配比为0.03～0.6R∶(Si0.01～0.98∶Al0.01～0.6∶P0.01～0.6)∶2～500H 2 O，式中R代表模板剂的磷源、硅源、铝源、有机模板剂和水混合成原料混合液；将步骤制备的原料混合液在低于晶化温度至少50℃的温度下反应至少0.1小时的技术方案较好地解决了该问题，可应用于含氧化合物制烯烃催化剂的制备过程。

In order to overcome the restriction of raw materials in producing humic acid silicified products, a new technology with humic acid and silicified agent as the main raw materials is developed, based on abundant tests.

针对目前生产腐植酸硅化产品原料受限的缺点，在大量试验的基础上，确定了一条以腐植酸和硅化剂为主要原料的生产工艺，合成了一种与有机硅腐植酸钾性能相当的硅化腐植酸钠产品GFN-1，对其常规性能指标和在清水及无固相聚合物钻井液体系中、在膨润土浆和低固相钻井液体系中应用指标，耐温性能进行了对比实验。

After the project completion, it has 100,000 tons / year organic single silicon productive capability( accounted by the methyl chloride silicon hydride), 45,000 tons/ year organic silicon including 20,000 tons/year silicon oil, 10,000 tons/ year silicon rubber, 6,000 tons /year silicone, 6,000 tons/year silicon hydride resin acceptor, and 3,000 tons/year others.

项目建成后生产有机硅单体10万吨/年，生产有机硅产品4.5万吨/年，其中硅油20000吨/年，硅橡胶10000吨/年，硅树脂6000吨/年，硅烷偶联剂6000吨/年，其它3000吨/年。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。