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相转变

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It is possible to understand the intermolecular interactions during phase transition from microstructure according to the change of T〓.

因此,根据T〓的变化可以从分子间相互作用的微观角度来认识相转变

The thermal stability and specific surface area of the samples are improved by using mesitylene and phosphoric acid .Calcining temperature can affect the pore size and morphology of the samples.

经500℃焙绍5h 后,用磷酸处理的样品仍未出现晶相转变的迹象,表明经均三甲苯和磷酸处理后,样品的热稳定性和比表面积均有一定程度地提高。

Using p-T pseudosections with contours of H20-contents, the medium-low pressure metamorphism for pelite from the Altai orogen was documented. We proposed that the andalusite-type metamorphic zones in Altai were related to the uplifting of kyanite-type zones and are characteristic of isomorphic transformation between aluminosilicates. Generally, it is difficult for the low-pressure metamorphic assemblages to reach an equilibrium state.

利用p-T视剖面图和饱和水含量等值线的行为研究阿尔泰造山带泥质岩石的中低压变质作用发现,阿尔泰地区红柱石型变质带的发生与蓝晶石型变质带的抬升有关,主要发生铝硅酸盐矿物之间的同质多相转变,低压变质矿物组合未能达到热力学平衡状态。

The mechanism of the phase transition is proposed based on the experimental results.

基于实验结果。提出了该过程中的相转变机理。

These polymers exhibit typical fibrillar morphology in the films. During heating in DSC, all the polymers substituted with alkoxy on phenylene show a nematic phase.

三、通过X-射线衍射、示差扫描量热仪和形貌表征等手段研究了苯环上取代基烷基、烷氧基长度对聚合物形貌、相转变过程等的影响。

Phase transformation and morphological change of blended powder of Fe and Si (The Proportionment of atom: Fe:Si=3:1) were studied during high-energy ball milling.

研究了Fe和Si(原子比为:Fe:Si=3:1)混和粉末在高能球磨过程中的物相转变和形貌变化。

The main reason is that bending-strain induces the microstructure phase-transformation of the pentacene polymorphic film from "thin-film phase" to "triclinic bulk phase",which results in the performance degradation of OTFTs.

其主要原因是,pentacene薄膜在反复的变化弯曲作用后,薄膜内部发生了微观结构的相转变过程,从而导致器件性能的降低。

Phase transformation of AlN in AlN/VN nanomultilayers and its effect on the mechanical properties of films.

AlN在AlN/VN纳米多层膜中的相转变及其对薄膜力学性能的影响。

This project is going to investigate the crystallization of polymers in scCO2 and to study the polymorphism and solid-phase transition of crystallizable polymers with different molecular structure and different tacticity in scCO2 for accumulating the fact of crystallization of polymers in the titled surrounding, revealing the rule of solid-phase transition of polymers in scCO2 and exploring the mechanism responsible for these phenomena.

本项目研究聚合物在scCO2中的结晶行为,研究不同分子结构、不同等规程度聚合物的同质多晶现象与固相转变,积累现象、寻找规律、探求机理。

Their thermotropic phase behavior was investigated by differential scanning calorimetry and POM. It was found that T(subscript S-N) w and T(subscript N-I), of PMMAZO was slightly increased with the increased of the mass ratio of liquid crystal block segments. PEO and PMMA block affected the liquid cystal behavior of PMMAZO. Meanwhile, PMMA and PMMAZO obviously influenced the crystals property of PEO segments3 which was decreased as the increase of molecular weight of PMMA and PMMAZO segments.

以差示扫描量热仪和偏光显徽镜研究了ABC三嵌段共聚物PEO-b-PMMA-b-PMMAZO的热力学相转变行为,发现随着PMMAZO链段的质量百分比的增加,三嵌段共聚物中PMMAZO链段的T和T逐渐提高;同时,PMMA和PMMAZO链段的长短影响PEO链段的结晶性,随着液晶段PMMAZO和PMMA链段分子量的增加,PEO链段的结晶性减弱。

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