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相转变

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The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生,是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力,与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8),每个中心金属都桥连两个TTF-ph-tfac配体。

The influence of the number of carbon atoms in flexible spacer on their mesomorphic state, clear temperature, phase-transition temperature is studied by using of DSC.

最后用DSC进行检测,考察了柔性链上碳原子数对介晶相态、清亮点温度和相转变温度的影响。

Results of Mn doping implied that samples located at rhombohedral-tetragonal morphotropic phase boundary. Small MnCO3 doping resulted in indistinct transition from rhombohedral to tetragonal.

Mn 掺杂NBT-BT 体系的测试和分析表明,适量的MnCO3 添加将有利于处于准同型相界的NBT-BT 样品从三方相向四方相转变

The packing arrangements in their mesophases of the polymers were influenced by the end functional group obviously. All the polymers with amide-substituted group showed the partly interdigitated bilayer smectic phase structure.

另外,聚合物的热行为和相转变行为受液晶聚合物的末端键接基团影响显著,所有末端包含酰胺基团的侧链偶氮苯聚合物在液晶温度均形成了部分穿插的双层近晶相结构。

Liposomal entrapment efficiency of urokinasein by MREV is as high as 65%, which is not evidently influenced by incorporation of phospholipid derivatives such as DSPE-PEG-RGDS and Stearyl RGDS.

改良反相蒸发法在磷脂相转变温度以下制备脂质体以提高包封率的效应在尿激酶上得到了很好的体现。

Study PhthCS Lyotropic Cholesteric thermotropic liquid crystal phase transition was found when the concentration of more than 46%, the system of cholesteric liquid crystal phase and gel phase coexistence, gelation occurred after the formation of liquid crystal phase.

研究了PhthCS溶致胆甾液晶的热致相转变,发现当浓度超过46﹪时,体系中胆甾液晶相与凝胶相共存,凝胶化发生在液晶相形成之后。

The results show that α-Al2O3 in the two kind s of coatings decreases while the γ-Al2O3 increases after spraying. Rutile-TiO2 transforms to brookite-TiO2 and the inners tress of coating was increased so as to aggravate the expansion of cracking. The pores are small but dense in the conventional coating while bigger but loose in the nano-structured coating. The pores in the nano-structured coating exist almost inside the partially melted region. The pores generated during spraying and the cracks generated during the course of thermal oxidization because of thermal stress are the direct reasons why coatings fail.

结果表明:2种粉末在喷涂之后,涂层中的α-A12O3均有所减少,生成了γ-Al2O3,金红石TiO2相转变成了板钛矿型TiO2相,增加了涂层的内应力,加剧了裂纹的扩展;常规微米涂层中的孔洞细小但密集,纳米涂层中的孔洞较大但不密集,且大部分的气孔都存在于部分熔化区的内部;涂层在喷涂过程中所生成的气孔以及热氧化过程中由于热应力而产生的裂纹是造成涂层失效的直接原因。

It has been well known that the activity of a BN particle might increase to a large extent when its size minished to several nanometers. As a result, the temperature and pressure required for the phase transformation will decrease accordingly.

氮化硼纳米颗粒的物相稳定性研究已有的研究结果表明:当氮化硼颗粒的粒度减小到纳米量级时,它的活性显著提高,发生物相转变所需要的温度和压力随之降低。

It implies that the work-hardening effect of shock waves of iron is significant,although the iron specimen has been undergone a e phase transformation in the above pressure range.

这表明,尽管铁试件在上述压力范围内已经历了α→ε相的相转变,而冲击波的加工硬化效应仍然是很明显的。

With an increase in Ca and La contents, the dramatic decrease in Curie point T〓 of films and ceramics was observed, and at the same time, the crystalline phases underwent the transformation from tetragonal into cubic phase.

随掺Ca和La量的增加,薄膜和陶瓷的居里温度T〓显著降低,晶相也由四方向立方相转变

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Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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