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The result shows: at different temperatures the outcomings obtained in determining dissociation constants with such two theories can be seen effective, but the doubly reciprocal curves of quenching equation are not conformed to quenching curves based on dynamic and static quenching mechanism as those of fluorescence enhancement.

通过荧光和紫外方法研究盐酸左氧氟沙星、氟罗沙星、加替沙星和沃氟沙星四种喹诺酮类药物与人血清白蛋白的作用,在不同温度下对荧光加强和猝灭理论公式的等价性和精细差异进行了比较,结果表明:在不同温度下两种理论公式尽管在求取解离常数上所得结果都可视为有效,但猝灭方程的双倒数图反而不及荧光加强方程的双倒数图与体现动态、静态猝灭机理的猝灭曲线一致。

After the solution was kept in the dark for five minutes,chloroform was added into it to adsorb selenium formed by previous reaction,then iodine separated out was determined by sodium hyposulfite titration using starch as the indicator,at last the content of selenium dioxide in the sample was foun.

在溶有二氧化硒的0.4~0.5mol/L盐酸介质中,加入过量的碘化钾,于暗处放置5min后,加入三氧甲烷吸附反应生成的硒,以淀粉为指示剂,用硫代硫酸钠标准溶液滴定析出的碘,测得二氧化硒的含量。

In the process of laboratory study, oxycodone was prepared by oxidating thebaine at 6,14-position under oxydol, hydrodeoxidizing 7,8-position double bond and 14-position ether under palladium catalyst. Furthermore, N-methyl of oxycodone was isolated byα-chloro-ethyl chloroformate under anhydrous condition and protection of 14-position hydroxyl to obtain noroxycodone, which was further converted into methylnaltrexone by N-alkylation in presence of cyclopropyl bromomethane, then by isolating 3-position methyl of methylnaltrexone under boron tribromide, becoming hydrochloride to prepare target compound, natrexone hydrochloride.

实验室工艺方面,本文首先用双氧水氧化蒂巴因的6-位和14-位、在钯炭催化下加氢还原7-8位双键和14-位醚合成羟考酮,然后提出并优化了在无水和14-位保护的情况下,用氯甲酸-α-氯乙酯脱去羟考酮的N-位甲基合成去甲羟考酮,再用环丙甲基溴将去甲羟考酮的N-位烷基化合成甲基纳曲酮,最后采用三溴化硼脱去甲基纳曲酮的3-位甲基和成盐酸盐合成盐酸纳曲酮。

We used ITO glass substrate and high purity(99.99%) titanium , put to use sputtering process, add to high purity O2 make it complete the best structure film and the thickness about 1400 . By way of 500℃ anneal could got a better anatase phase, this result could easy reaction with electrolyte to increase electron-transferred. Used as spin casting covering PR on ITO substrate, transferring patterns of array circular shapes on a mask to photography, used optimize temperature and time to hard bake. Finally used HCl to etching underexposed TiO2 area, and acetone to tripper top PR, make it to accomplish pillars shape TiO2 electrode.

本研究使用ITO玻璃基板为底材在以高纯度钛(99.99%)为靶材,利用溅镀方式通入纯氧使其行成高纯度TiO2镀於ITO基板上行成厚度约1400的薄膜,且经500℃高温烧结使其行成最强的锐钛矿结晶相,此晶相有利於与电解液反应进而增加电子的转移,提升太阳能电池最佳的效率,在以旋转涂布方式铺上光阻,以矩阵排列的圆孔光罩曝光、最佳的温度及时间来烘烤、显影后;使用盐酸以等向性湿蚀刻方式蚀刻未曝光之TiO2区域,最后利用鈵铜将最上层光阻去除,使其行成柱状TiO2的电极。

At last, the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by constructing the grey inhibition model of the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles.

通过对2—苯基丁腈缓蚀性能的理论预测和试验验证,认为利用某一类苯腈类化合物的缓蚀性能与分子结构关系,从理论上预测同类型苯腈类化合物的缓蚀性能是可能和合理的。灰色理论研究结果表明,苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构参数的关系,可用GM(0,3)模型描述。

A new defluorination idea is presented. During the process of producing phosphoric acid with chlorhydric acid and phosphate rock, the extraction reaction of the phosphate rock is accompanied with the defluorination reaction. Feed-grade calcium hydrogen phosphate according with international standard can be made by filter and neutralization without any deflourination agent.

采用全新的脱氟理念,在使用盐酸与磷矿制取磷酸的过程中,磷矿的浸取反应与除氟反应同步进行,在不添加任何除氟剂的条件下,浸取液经过过滤,中和,就可以制出符合国标要求的饲料级磷酸氢钙。

The gold NPs on the surface of PPy acted as the"seeds"for growing consecutive particle film on the surface of PPy film in the chloroauric acid aqueous solution containing NH2OH·HCl served as the reducing agent.

最后利用膜表面上的金纳米粒子作为&种子&,在盐酸羟胺和氯金酸的水溶液中,通过多次生长的方式,在吡咯的表面生长一层致密的金纳米粒子。

The chemistry behavior research of wollastonite indicated that the silicon-potassium fertilizer has a chemical active in organic acid.The factors affecting manurial effect of silicon-potassium fertilizer are not only soil pH and desilicification,but also content and type of organ in the soil.Wollastonite chemistry behavior indicates that silicic acid can be dissolved out from silicon-potassium fertilizer in chlorhydric acid solution if pH of solution is not smaller than 2. The drop of apparent density,increase of DBP sorptive rate and specific surface for leavings indicate that hydrated silicon oxide is polyporous,and those mineralogic feature presignify that silicon-potassium fertilizer has a role of conservation of both Moisture and Fertility and improving soil structure.After active ingredient releasing,silicon-potassium fertilizer leaves half the substance (non-active ingredient)in soil.

熟料单矿物在酸溶液中的化学行为研究表明,硅钾肥矿物在有机弱酸中的化学活性较好,影响硅钾肥肥效发挥的因素是土壤pH值和土壤的去硅化程度,还有土壤有机质的含量与种类;硅灰石在盐酸溶液中化学行为表明,在反应体系pH不小于2的情况下,硅钾肥矿物大量溶出硅酸根组分;溶解残余物表观密度降低、DBP吸着率和比表面积增加表明水合二氧化硅是以多孔形式存在,为硅钾肥具有保水保肥、改良土壤结构的提供了矿物学依据。

The specific heat of the emeraldine base form of polyaniline and the emeradine salt of polyaniline has been measured at temperatures between 1.8 and 45K. The experimental results have been interpreted in terms of the contributions from both the crystalline and the amorphous phases characterizing the polymer.

我们测量了聚苯胺及其掺杂盐酸后在1.8K至45K的热容,利用声子-分形子模型来处理非晶态对比热的贡献,对获得的数据进行处理,发现EB和ES的比热数据均不符合德拜理论,超出德拜模型的比热来源于非晶态的贡献。

The extremities were titanic, and there was no response to touch stimulations.Our results suggested that Pentobarbital sodium inhibited neuronal firing through GABA_A receptors, therefore the local field potentials and neural firing rates were inhibited; Urethane acted on many kinds of receptors including inhibitory and excitory ones, so the local field potentials did not change significantly; however, because of the multiform receptors on the neurons, the changing of firing rates to different neurons were not the same; Ketamine mainly acted on the NMDA receptors, therefore the local field potentials and neural firing rates were enhanced, and most neural firing rates would be increased.

从这三种麻醉剂的底层作用机制来看,戊巴比妥钠通过作用于GABAA受体对神经细胞发挥抑制性作用,因此表现为场电位和神经元放电的降低;氨基甲酸乙酯同时作用于多种受体通道,既有兴奋性受体,也有抑制性受体,因此,对场电位的影响不大,但对单个神经元来说,每个神经细胞上的受体通道分布差异较大,因此,单个神经元的放电频率变化会有所不同;盐酸氯胺酮主要作用于兴奋性的NMDA受体,故整体场电位活性增加,多数神经元的放电频率也会有所升高。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。