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The results show that the quaternary ammonium cations C12 TA(superscript + and C14 TA(superscript +) with short alkyl chain only react with the hydration cation in the interlamerllar space of hydrobiotite, while those with long chain C16 TA(superscript + and C18 TA(superscript +) first react with the hydration cation, then with the kalium cation in phlogopite interlayer.

结果表明:较短链长的季铵盐阳离子C12TA(上标+, C14TA只与水黑云母蛭石晶层中的水合阳离子发生反应;而长链季铵盐阳离子C16TA(上标+, C18TA先同蛭石晶层的水合阳离子交换反应,再与云母晶层中的钾离子发生交换反应。

We used two different intercalation agents to treat clay:the phosphonium saltand the ammonium salt.

我们使用两种不同的插层剂改质黏土:磷盐与胺盐。将黏土预先在水中分散后再用插层剂进行插层。

The result shows that the changing law of saliferous reservoir parameters is a nonlinear relationship with several variables, and it is a very complicated process.

研究结果表明,高含盐油藏储层参数变化呈多元非线性函数关系,变化规律复杂;渗透率变化存在临界值,大于临界值时,渗透率随着驱替速度、驱替量和含盐量的增加而增大,小于临界值时,渗透率随着驱替速度、驱替量和含盐量的增加而减小;注入水性质会对参数变化过程有影响,而对最终变化结果无影响;盐的溶解是储层参数变化的根本原因,岩石颗粒的脱落和运移是储层参数变化的直接原因。

Affinity chromatography materials for kinase;2. To search a suitable process route of purification of kinase in yeast by affinity chromatography, hexokinase was preparatorily purified by salt preciptation.

为确定一条采用亲和层析技术分离纯化酵母中磷酸激酶的较佳工艺路线,采用分步盐析初步纯化己糖激酶,考察硫酸铵饱争度对盐析效果的影响;以ATP为配基,SESA活化纸纤堆素制备亲和层析剂,确定最佳偶联条件和最佳静态吸附pH值后,将粗酶液直接上亲和层析柱,看分离纯化的效果;在载体和配基之问接上1。

The anodic behavior of electrolytic nickel anode in nickel sulfamate plating Solution was investigated,using anodic polarization curves,metallographic observation of cross-sections of nickel deposits,Hull Cell tests with solutions with and without Cl-,F-,bending tests with five solutions of different compositions,and sulfur content analysis in nickel deposit with mass spectrometry.

采用极化曲线、金相观察、赫尔槽电镀试验、弯曲试验和质谱分析方法,研究了氨基磺酸盐镀镍的阳极行为,证明了当在氨基磺酸盐镀液中使用电解镍阳极时,其活化峰值电流和镀液组成有很大的相关性,当镀液中不含F-和Cl-时其阳极活化峰值电流小,阳极处于极化状态,或相当大面积处于极化状态,使氨基磺酸根在极化的阳极表面氧化,从而使含硫化合物夹附于镀镍层,形成镀层内应力,并使镀层成为层状结构,并出现半光亮的外观。

Therelationship between the turbulent kinetic energy and its dissipation rate,whichis widely used to parameterize the dissipation rate in turbulence closure models,is found to hold well for both reversing and rotating flows,but with differentcoefficients.Microstructure profiling measurements at two comparative stations (a deepercentral basin and a local shelf break) in the stratified Yellow Sea are analyzed,with emphasis on tidal and internal-wave induced turbulence near the bottomand in the pyenocline.The water column has a distinct three-layer thermohaline structure,consisting of weakly stratified surface and bottom boundary layers anda narrow sharp pycnocline.Turbulence in the surface layer is controlled by thediurnal cycle of buoyancy flux and wind forcing at the sea surface.while thebottom stress induced by barotropic tidal eurrents dominates turbulence in thebottom boundary layer.The maximum level at which the tidally enhanced mixingcan affect generally depends on the magnitude of the tidal current,and it canbe up to 10-15 m in the Yellow Sea.This suggests that,in the deeper regionsof the shelf seas,turbulent dissipation and mixing are very weak at the levelsbetween the near-bottom tidally enhanced layer and the pycnocline.Therefore,these levels provide a significant bottle neck for the vertical exchanges.In theshallow regions,however,the tidally-induced turbulence can occupy the wholewater colum below the pycnocline.A quarter-diurnal periodicities of the turbulentdissipation rate and eddy diffusivity are found at different heights with evidenttime lag.In the relatively flat central basin,the pycnocline is essentially non-turbulent and internal-wave activity is very weak.Therefore,vertical fluxes acrossthe pycnocline decreased to molecular levels.In contrast,internal waves of variousperiods can be always found near the local shelf break.

对强层化季节黄海两对比性站位(分别位于中央海盆区与局地陆坡区)处层化、内波以及湍流混合特征的研究结果表明:1、强层化季节的陆架海水体一般呈现显著的三层热盐结构,在水体近乎混合均匀的上混合层与潮流底边界层之间为强跃层;2、近表层水体的湍流混合强度主要由海表浮力通量的日变化与海表风强迫控制,而在潮流底边界层内,潮混合是水体热量、物质、动量与能量垂直交换的主要机制;3、潮混合影响的深度由潮流大小决定,在黄海,一般可达10-15 m,因此,在水深较深的区域,在跃层与潮混合所至深度范围的上界之间存在湍流混合非常弱的区域,这显著抑制水体内物质的垂直通量,为物质垂直交换的瓶颈,而在水深较浅的区域,潮混合影响范围可至跃层底部,因此物质在跃层以下整个水体中混合非常均匀,当跃层内间歇性强混合发生时,可以产生显著的跨跃层物质输运;4、近底潮致强湍流耗散缓慢地向上传播,底上不同深度处垂直湍扩散系数也具有显著的位相差异,且二者均随时间呈现四分之一周日周期的变化;5、在地形较为平坦的中央海盆区,内波活动非常微弱,因此跃层内湍流混合非常弱,垂直扩散系数为分子扩散水平,跨跃层物质通量受到显著抑制,而在地形变化较为显著的局地陆坡区,内波活动非常活跃,除内潮的影响外,高频内波与内孤立波的影响也很显著,因此跃层内存在很强的间歇性强混合,内孤立波存在的区域,水体湍流混合显著增强。

DM the three-phase embedded electrode salt bath is the rectangular structure, the outer covering welds by the angle steel and the steel plate, in puts in gallbladder which the steel plate makes, in the gallbladder is uses sets up the salt bath which the brick and the standard brick compose, in the gallbladder is mainly uses in preventing outside the fused salt permeating heat insulating layer and the salt bath, when salt bath damage is advantageous hangs the repair.

DM型三相埋入电极盐浴炉系长方形结构,外壳由角钢及钢板焊成,内放钢板制成的内胆,内胆中是采用立砖及标准砖组成的盐槽,内胆主要是用于防止熔盐渗入保温层及盐槽外,当盐槽损坏时便于吊出修理。

The reaction and influence involving the mechanism of crystal and the interior flow field was developed when impeller machine transferring bittern .Based on the measurement through PIV and numerical simulation,the reason that deposition mass rate and removal mass rate is changed along with the increase of crystal layer was analyzed. Moreover,the viewpoint was developed that the change is the result of the reaction among temperature gradient,velocity gradient,turbulent intensity and the temperature stress within the crystal layer.

提出叶轮机械输送卤水时,结盐过程与内部流场相关且相互影响、相互作用,并在进行PIV内流测试和数值模拟的基础之上,综合运用多学科理论,依据Kern-Seaton模型,分析了沉积率与脱除率随盐析层增长而发生变化的原因,提出了这种变化是温度梯度、速度梯度、湍动度及盐析层内部温度应力等各种因素交叉影响的结果。

Aimed at the problem of the salt bed wellbore creep and shrink under the drilling,based on the elasto-plastic mechanics theory and the head creep equation,the new formula of the control wellbore shrink rate was derived with in case of the plane strain and uniform in-situ stress,which was different from the old formula.

针对钻井过程中钻遇的盐层段井眼蠕变缩径问题,利用弹塑性力学理论,蠕变本构方程采用Heard蠕变方程,在平面应变和均匀地应力假设下,推导出控制井眼收缩的钻井液密度新公式,该公式与前人推导的公式不同。

In order to safe and fast drilling in creeping salt bed in S84 Well, some technological practices were adopted, such as unsaturated salt water drilling fluid system, measurement technique of formation creeping rate and homoion effect technique, which can solve some problems during drilling operations in creeping salt beds.

S8 4井在钻进过程中遇到塑性蠕动非常严重的盐膏层,为安全快速钻进,采取了应用欠饱和盐水钻井液体系、地层蠕动速率测定技术、同离子效应技术等工艺措施,较好地解决了该井盐膏层钻井存在的一些问题,为日后钻穿盐膏层提供了借

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