皂基

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

More levels of nano-SiO〓 lead to larger particle size. An increase in polymerization reaction temperature causes the decrease in coagulum and increase in viscosity and particle size, and the nano-SiO〓 has same effects at certain temperature. When the levels of hydrophilic monomer acrylic acid and hydroxylethyl methacrylate in core composite are increased, the particle size of emulsifier-free emulsion decreases, in spite of the presence of nano-SiO〓.

无皂乳液具有单分散性好、表面洁净、成本低廉、不影响产品性能的特点，首次研究了含或不含纳米粒子的含羟基和羧基的丙烯酸无皂乳液聚合，发现含或不含纳米粒子的无皂乳液聚合后的粒子粒径较大，具有单分散性；较多的纳米粒子导致较大的乳液粒径；反应温度升高，凝聚物含量下降，而乳液粘度和乳胶粒粒径增加，在相同的反应温度下，纳米粒子降低了聚合过程中的凝聚物含量，增加了乳液聚合物的粘度和粒径；不论纳米粒子是否存在，当无皂乳液核组成中亲水单体AA和HEMA用量增加时，乳胶粒粒径均减少。

Low concentration saponins solution can eliminate hydroxy and oxygen free radicel, the effect of eliminating free radicel submits positive pertinence with saponins concentration.

皂甙溶液在较低浓度时对羟基自由基与氧自由基就有一定的清除作用，自由基的清除效果与皂甙的浓度呈显著正相关性。

Sapogenin used by industry but most yams, from which it is isolated, contain a mixture of sapogenins in the glycosidic form.

大多数苷元在C24或C28位有COOH基，故又称酸性皂苷；少数苷元只含醇羟基而呈中性，如人参皂甙、柴胡皂甙等。

Two patent publi cations are of particular relevance here: Chinese patent publication No CN1096031 A claims the use of the spirostane sapogenin, sarsasapogenin, in the treatment of SDAT.

已经相关有专利应用指南说明大量的皂甙配基醇可以用于治疗包括SDAT 的功能，而该类皂甙配基醇，下面介绍两个专利出版物：中国的No CN1096031A宣布治疗SDAT中使用菝葜配基，其中的提示很简单。

Free tryptophane, docosoic acid and methyl 14-methy pentadecanate were isolated and identified as monomeric compounds also for the first time from Panax plants. Malonyl-ginsenoside 〓, ginsenoside Ro,〓, Re,〓,〓,〓(8 saponins) and stigmasterol were isolated and identified for the first time from the fruits and molonyl- ginsenoside 〓 was also the first from the plant of panax quinquefolium.

游离色氨酸、二十二碳酸及14-甲基-十五碳酸甲酯是首次从人参属植物中分离鉴定的杂环α-氨基酸和脂肪羧酸类单体化合物；丙二酸单酰基人参皂甙〓、人参皂甙〓及豆甾醇是西洋参果中首次分离鉴定的8种单体皂甙和1种甾醇化合物，M-〓亦为西洋参中首次分离鉴定的皂甙化合物。

Compound 9 is glycosylated in the presence of TMSOTf with rhamose-derived trichloroacetimidates to provide target trisaccharide Saponin 1, oleanolic acid 3-yl-2,4-di-O-a-L-rhamnopyranosyl -p-D-glucopyranosideCoumpond 18 is prepared with oleanic acid and Bromide 11 through phase-thansfer catalysis glycosylation manner.

三糖皂苷Saponin 1是以葡萄糖齐墩果酸皂苷为起始原料，用BBTZ(1-苯甲酰苯并噻唑)选择性保护葡萄糖3′，6′-羟基得到化合物9，然后以化合物9为糖基受体，进行一步糖苷化可以在化合物9的2′，4′-羟基上同时引入两分子鼠李糖，最后脱掉所有的保护基得到目标化合物Saponin1。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

In this review, the biosynthetic pathway of ginsenosides was introduced and the research progress on enzymes related to ginsenoside biosynthesis , such as 3-hydroxy-3-methyl-glutaryl-CoA reductase, geranyl pyrophosphate synthase, farnesyl pyrophosphate synthase, was summarized in detail.

本文综述了人参皂苷的生物合成途径，并介绍了3-羟基-3-甲基戊二酸CoA还原酶、牻牛儿基二磷酸合成酶、法尼基二磷酸合成酶等人参皂苷合成途径相关酶的研究进展。

And when the pH of α-CB solution approaches to pI, the system presents the lower surface tension and cmc than other forms. Some applied performance of α-CB are examined and the experimental results suggest that α-CB exhibits good foaming performance, excellent lime soap dispersing ability and hard water-resistance capability. This study indicates that α-CB is a candidate for the efficient lime soap dispersant.

对α-癸基甜菜碱水溶液泡沫力、润湿力和钙皂分散力等应用性能的测定结果表明，α-癸基甜菜碱具有中等润湿力、优良的起泡性能、稳泡能力和抗硬水能力，具有用于高效钙皂分散剂的潜能。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。