电解还原

In this work,the kinetic effects were considered and a new type electrolytic cell with mercury electrode was designed.

本文介绍用电解还原Hg-EDTA所释放的EDTA滴定水溶液中铅、镉、汞离子的分析技术。

Uranium solution is obtained electrolytically by reducing uranyl ion on mercury cathode. The effect of the addition of various aminopolycarboxylic acids (such as EDTA, DTPA, CyDTA and TTHA) and organic water-miscible solvents (such as CH3OH, C2H5OH and CH3COCH3) on the stability of ura-nium in air has been investigated. The absorption spectra of uraniumand uraniumin 1 mol/l and 9mol/l hydrochloric acid solutions are examined.

本文采用汞阴极电解还原法制备了铀溶液，研究了在盐酸介质中各种氨羧络合剂乙二胺四乙酸二钠、二乙三胺五乙酸、1，2-环已烷二胺四乙酸、三乙基四胺六乙酸和水溶性有机溶剂甲醇、乙醇和丙酮的存在对铀稳定性影响，测定了在不同盐酸浓度中铀和铀的吸收光谱。

The results showed that inner electrolysis reduction of iron filings played an important role in final degradation and decolorization of dyeing wastewater.

采用测定反应产物苯胺方法及添加EDTA的对照实验对反应过程中的铁屑的内电解还原和铁离子的絮凝作用进行研究。

Electrolytic reduction of o-nitrophenol to aminophenol at a copper cathode was conducted inalkaline solution.

在碱性介质中，以硐为阴极电解还原邻硝基酚以制备邻氨基酚。

In general, the chrome-included solution with the rain shows alkalescent, so it shows significant practical value to electrolyze and reduct Cr6+ in alkalescent media directly to dispose the extraction of chromium residues to disposal the chromium waste pollutant.

一般情况下，雨水淋淅出的含铬液体呈弱碱性，因此，直接在弱碱性介质中采用电解还原Cr~(6+)来处理铬渣浸出液，以治理铬渣污染具有实际意义。

The invention relates to an electrochemical method for preparing ultra-fine tantalum powder, wherein it uses the mixture slat flux with CaCl2 or CaCl2 as electrolyte; composites Ta2O5 powder/block with metal collector as solid cathode; uses graphite or inertia anode as anode; uses reference polar to control the electrolysis level, under inertia gas to electrolyze at 500-1000Deg. C; and the electrolysis time should make electrolysis electricity reach needed amount; reduces Ta2O5 into ultra-fine metal tantalum powder.

本发明涉及一种超细钽粉的电化学制备方法，以CaCl2或者含有CaCl2的混盐熔体为电解质，将Ta2O5粉末或块与金属集流体复合作为固态阴极，以石墨或惰性阳极作为阳极，用参比电极控制电解电位在惰性气氛保护下进行电解，电解温度控制在500-1000℃，控制电解时间使电解电量到达到理论所需电量及以上，将五氧化二钽电化学还原为超细金属钽粉。

The experimental results indicated that saturated —N=N— bonds of dyes can be easily deoxidized by scrap iron, and the intermediate product aniline was produced.

实验结果表明，染料的偶氮键易被铁屑内电解还原，反应过程中有中间产物苯胺生成。

After a supplementary alkaline saponification treatment, the rice oil alkali purification waste was made into aqueous solution for further electro-hydrogenation.

碱法精炼米糠油的下脚料——皂脚，经补充皂化，配成水溶液，进行电解还原处理后，作为单一油脂原料，制成了可供使用的肥皂。

The degradation of azo dye by iron internal electrolysis deoxidization and microwave induced oxidation were investigated respectively.

研究了铁屑内电解还原及微波诱导氧化降解偶氮染料的反应历程，采用胶束毛细管电泳法对照跟踪了2种不同降解方法下的中间产物变化。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。