电解质

Thorough analysis of the present hydrate models as the base , contrapose to the deficiencies of present models, we have build a universal natural gas hydrate model base on the state equation which can be used in electrolytical and polarity inhibitors, realized the unite of electrolyte models and alcohol models.

在深入剖析目前水合物模型和实验的基础上，针对现有模型的不足，基于状态方程建立了一个适用于含电解质和极性抑制剂的通用天然气水合物计算模型，实现了电解质与醇类模型的统一。

For systematically studying the quantitative structure-property relationships for electrolytes, the thesis chapter 6, 7 and 8 systematically studied molecular structure and quantitative structure-property relationships, including the relationship between molecular structure and conductivity, anions structure and electrochemistry stability, on anions of 1,2-Dihydroxycyclo-pentenetrione (croconic acid, H_2C_5O_5) and the whole series of dicyanomethylene derivatives, anions of 1,2-dihydroxycyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives, and anions of 1,2-Dihydroxy-cyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives.

为了系统地研究锂盐的分子结构与电解质的关系，论文第六、七、八三章系统地从理论上研究了方酸及其氰基亚氨基衍生物、方酸及其二氰亚甲基衍生物、克酮酸及其二氰亚甲基衍生物等各系列电解质分子结构、分子结构与电导率、阴离子结构与电化学稳定性的关系。

In this thesis, inorganic ions were assembled to films by the interactions of the ions with functional groups of the polyelectrolyte, and then inorganic nanoparticles/polyelectrolyte composites films were prepared through chemical reaction. The properties and application of the films in electrocatalysis were studied.

本论文利用无机离子与聚电解质功能基团间的相互作用，用层层自组装的方法将无机离子组装到膜中，然后通过化学反应制备无机纳米粒子/聚电解质复合膜，考察了复合膜的性质及在电催化方面的应用。

The pores were hexagonally ordered and narrowly diameter-distributed (95±13 nm in comparison with those produced with normal electrolytes using water as the sole solvent

结果表明，有机溶剂贫水电解质体系使得电氧化电压的选取范围比水溶液电解质体系更宽，孔径连续可调，反应条件温和。

Its solution behaviors are similar to and even better than those of corresponding polyelectrolytes singly modified with the same hydrophobe to the added surfactant.

通过溶液共聚，将碳氢和氟碳这两种疏水单体无规地接枝到聚电解质主链上，得到的这类混合改性的聚电解质无论与碳氢小分子表面活性剂还是与氟碳小分子表面活性剂作用均表现出和同种大分子表面活性剂与小分子表面活性剂作用时相似甚至更好的缔合情形。

This research is order to design a membraneless micro fuel cell, using liquid electrolyte to replace Nafion membrane. Liquid electrolyte transports protons by laminar flow.

因此本研究设计一个微型无薄膜燃料电池，使用液态电解质来取代Nafion薄膜，电解质以层流的方式流动来传导质子。

In addition, Pitzer theory was used to analyze the apparent molal volumes of single and mixed electrolyte aqueous solutions. The new Pitzer equation interaction parameters were evaluated. The working equatio...

另外，运用Pitzer理论，估算了不同温度下 39个单一电解质溶液的 Pitzer体积参数；用引入Pitzer体积混合参数与离子强度的关系式得到的方程对混合电解质水溶液的表观摩尔体积进行了计算，结果比较满意。

The densities for HNO3-UO2(NO3)2,NaCI-Na2SO. and KCI-Na2SO4 aqueous ablutions were measured with a high precision densimeter at 25℃. The apparent molal volumes were obtained from the measured densities. An empirical equation is introduced to correlate densities for mixed electrolyte aqueous solutions.

用高精度密度计测量了25℃下 HNO3－UO2（NO3）2， KCI－Na2SO4和NaCl－Na2SO4水溶液的密度从而求出了相应的表观摩尔体积；建立了用于混合电解质溶液密度关联的经验方程，用此方程对9个混合电解质水溶液体系的密度进行了关联，精度较高。

In this part, the densities of sodium benzoate, sodium nitrobenzoate, sodium chlorobenzoate and sodium methylbenzoate in DMFwater mixed solvents have been measured at 298.15K with an Anton Paar Model 55 densimeter. From these densities, apparent molar volumes and partial molar volumes have been calculated, transfer volumes from water to DMF-water mixtures and substituent contributions to the transfer volumes have also been obtained. Solvent and substituent effects are discussed in detail. The Scaled Partical Theory has been applied to the ternary solutions to evaluate the partial molar volumes of cavity formation and the volumes change associated with solute-solvent interaction.

选择了含有取代基团的芳香类有机电解质，主要是苯甲酸钠、硝基苯甲酸钠、氯苯甲酸钠和甲基苯甲酸钠的邻、间、对同分异构体作为研究对象，用DMA 55型振荡管密度计测定了它们在不同质量百分数组成的DMF-水混合溶剂中的密度，利用这些密度数据，计算了表观摩尔体积和偏摩尔体积，得到了这些单取代苯甲酸钠从水到DMF-水混合溶剂中的迁移偏摩尔体积及苯环上不同位置的取代基对迁移偏摩尔体积的贡献值，讨论了溶剂效应和取代基效应，并将定标粒子理论应用于此三元电解质溶液中。

The present development of high temperature proton conductors with high chemical stability as electrolyte materials for protonic ceramic membrane fuel cells is reviewed, as well as the influence of novel element doping strategies on the chemical stability, ionic conductivity and sinterability for BaCeO3-based materials.

重点评述了近期化学稳定性好的高温质子导体电解质材料的发展以及新的掺杂体系对于经典BaCeO3基质子导体在化学稳定性、电导率和烧结活性等方面的作用，分析了高温质子导体作为电解质材料在质子陶瓷膜燃料电池发展中存在的问题和发展的方向。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。