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电解质

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The concentration of electrolytes in the serum of pika does not be affected by environmental conditions that pika lives.

高原鼠兔血清电解质浓度不受生活环境和食物条件的影响,其机体能自身调节血清离子浓度,以维持电解质在血液中的相对衡定;2。

Electrochemical polymerization kinetics of pyrrole in aqueous solution on the carbon foam electrodes was studied with the charge consumed.

该材料的BET比表面可达500m〓/g,在有机电解质溶液和电解质水溶液中的双电层比电容最大可达174F/g,与普通碳纸相比有质的区别。

This dissertation involves the study of the growth dynamics of colloidal particles under unequilibrium and irreversibility condition. Firstly, it is of interest to investigate whether the ideal diffusion or reaction-limited aggregation universal behavior can be observed for the initially polydisperse practical system of basic yttrium carbonate as well. The fractal structure of basic yttrium carbonate aggregate cluster was observed using transmission eletron microscopy. The aggregation kinetics of basic yttrium carbonate colloids was studed using dynamic 1ight-scattering techniques. At 1.00mol/l NaCl solution the fast diffusion-limited aggregation behavior was observed with an increase in the aggregate size over time described by a power law. The aggregates are characterized by a fractal dimension D=1.82. The disordered and ramified cluster is consisted of primary colloidal particles and tenuous and more open. These are in good agreement with those observed for other colloidal system such as colloidal gold (1.86), silica (1.85) and polystyrene latex (1.82) in diffusion-limited aggregation from the static and dynamic light scattering by Lin. Therefore ideal diffusion-limited aggregation behavior can be observed in practical polydisperse system as well. Smoluchwski and fractal theories were used to obtain the aggregation rate constant for initially polydisperse system for the first time.

本论文研究胶粒的非平衡不可逆聚集动态学,分为两个部分,第一部分是通过实验研究一个新的初始多分散的碱式碳酸钇胶粒实际体系中,聚集标度性质的普适性,即使用透射电子显微技术观测聚集粒子簇的分形结构,使用动态激光光散射研究碱式碳酸钇胶粒的聚集动力学,胶粒带电而产生静电排斥作用使得碱式碳酸钇胶粒处于稳定状态,当加入电解质NaCl溶液时,碱式碳酸钇胶粒间的Debye-Hückel屏蔽距离缩短,从而降低静电排斥能垒,引起胶粒发生不可逆聚集,加入电解质NaCl的浓度为1.00mol/l时,碱式碳酸钇胶粒进行快速聚集,经历扩散控制聚集机理,形成结构疏松、更为开放的分形聚集粒子簇,其分形维数为1.82,碱式碳酸钇胶粒聚集增长动力学遵循幂函数增长规律,与Lin等使用静态激光光散射和动态激光光散射测量硅胶(1.85)、金胶(1.86)和聚苯乙烯胶乳(1.82)在扩散控制聚集状态形成聚集粒子簇的分形维数值以及粒子簇聚集增长的动力学规律相一致,表明胶粒聚集标度性质的普适性质在初始多分散的实际体系中也是存在的,首次由动态激光光散射的实验数据得到初始多分散胶粒分形粒子簇的聚集速率常数,并且其值与Smoluchowski聚集速率理论预期相符。

The present invention discloses a compounded full-solid polymer electrolyte for secondary lithium cell and its preparation method.

本发明公开了一种属于电解质制备与应用技术领域二次锂电池用复合型全固态聚合物电解质及其制备方法。

The Zeta potential and the surface charge density of the membrane were calculated according to Helmoltz-Schmolukovski and Gouy-Chapmann equations.

摘 要:研究芳香聚酰胺纳滤膜在不同电解质溶液中的流动电位,考察膜两侧压差、电解质浓度、离子价态及溶液pH值对流动电位的影响,用Helmoltz-Schmolukovski方程与Gouy-Chapmann方程计算膜表面的Zeta电位与电荷密度。

On electrolyte disturbances, for those who were not given diuretic showed low serum Na(superscript +) or low both Nat and Cl(superscript -); for those who had taken diuretic showed variform.

未用利尿剂病人电解质紊乱全部为低Na或低Na+低Cl,而应用利尿剂的病人电解质紊乱表现多样。

By taking the advantage of thedifferent solubility of polyelectrolyte multilayer before and after UV irradiation andpatterned mask assistanted photolithography, we can obtain patterned robustpolyelectrolyte multilayer.

并利用这一光敏性聚电解质多层膜光反应前后在特定溶剂中溶解性的差异,通过覆模光照以及超声洗脱,制备了图案化的聚电解质多层膜表面。

Influences of different pH values on the UV-Vis absorption spectra of azo polyelectrolyte were studied.

研究了不同pH值的偶氮聚电解质溶液的紫外-可见光谱,结果表明,偶氮聚电解质对pH值具有高度敏感性。

The factors that affected the degradation rate of methyl red are discussed, including the concentration of methyl red, the kind of electrolyte, the concentration of sodium bromide, the anodic current density, the material of electrode, the cathodic current density and the flow rate of oxygen at the catholyte.

探讨甲基红浓度、电解质种类、电解质浓度、阳极电流密度、电极材料、阴极电流密度与阴极室氧气流量等因表对甲基红电分解的影响。

Result of thermogravity analysis showed that the thermal stability of polyvinylamine chloride lowers with increasing in amination degree. Moreover, properties of dilute aqueous solutions of three types of poly chloride with different amination degree were compared by use of viscosimetric, conductometric, and potentiometric measurements. Results showed that both the electrostatic interaction of neighboring groups on the chain and the reduced viscosity of poly chloride are increased with increasing the degree of amination of poly . The equivalent conductivity is decreased with the increasing the concentration of poly chloride and increased with the increasing the amination degree of poly .

研究了聚乙烯胺盐酸盐的热稳定性和水溶液性质,发现:随着胺化度的提高,聚乙烯胺盐酸盐的对热稳定性逐步降低;聚乙烯胺盐酸盐是一种典型的聚电解质,其水溶液的pH值随平均分子量的变化并不明显,而随着聚乙烯胺胺化度的升高,pH值降低;随着聚乙烯胺盐酸盐的平均聚合度由82.3增加到201.8,它的m值(用于表征聚电解质侧链基团之间相互作用大小的常数)从5.13升高到5.58,而当聚乙烯胺盐酸盐的平均聚合度增加到311.4时,它的m值反而降低到了5.48;随着胺化度由55.65%升高到82.36%,m值由3.65提高到5.50;随着聚乙烯胺盐酸盐的平均聚合度的提高,聚乙烯胺盐酸盐的平均解离常数由7.48降低到7.26,同时随着胺化度的提高,聚乙烯胺盐酸盐的平均解离常数也由8.33降低到7.37;随着聚乙烯胺盐酸盐浓度的提高,溶液的摩尔电导率逐步降低,随着聚乙烯胺胺化度和聚合度的提高,溶液的摩尔电导率有所升高;在pH值为4左右时,聚乙烯胺盐酸盐的比浓粘度分别达到极值,而与聚合度的大小关系不大;聚乙烯胺盐酸盐的特性粘数明显高于其原料聚丙烯酰胺的特性粘数,分子量对特性粘数的影响十分明显,胺化度对特性粘数的影响并不显著。

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