电离解

The experiment shows that the multiphoton ionization mechanism of anisole is parent molecule ionization-dissociation model.

实验结果表明苯甲醚分子的多光子电离机制属于母体分子电离-解离模型。

This dissertation is concerned with the kinetics of the nonequilibrium dissociation and ionization of gases that are significant in the high temperature gas dynamics. There are two parts in the dissertation. In the first part, the kinetics of dissociating gas, a theoretical calculation is made of the nonequilibrium dissociation of the diatomic molecule behind a strong shock wave front.

中文题名高温气体解离和电离动力学研究副题名外文题名 The study of the kinetics of dissociation and ionization in the high temperature gases 论文作者王苏导师崔季平何宇中研究员范秉诚高级工程师学科专业一般力学研究领域\研究方向学位级别博士学位授予单位中国科学院力学研究所学位授予日期2001 论文页码总数125页关键词气体动力学电离复合非平衡解离速率振动－解离耦合馆藏号BSLW /2003 /O354 /1 本论文选取在高温气体动力学中具有重要意义的气体非平衡解离和电离动力学作为研究对象，包括两部分内容。

In this paper, using REMPI-TOF technique, multiphoton dissociation/ionization of sulfur and carbon contained polyatomic molecule has been carried out. The mechanism ofmultiphoton dissociation/ionization was discussed, and some valuable results are obtained. The paper has six chapters.

本论文用共振增强多光子电离-时间飞行质谱等实验技术研究了二硫化碳、甲醇和乙醛分子的多光子解离或电离的动力学过程，对多光子解离或电离产物的产生机理进行了分析和讨论，得到了一些有意义的实验结果。

The ionization and dissociation of polyatomic molecules in femtosecond laserfield were studied in the article.

本论文的主要内容是利用飞行时间质谱仪来探测飞秒激光强场下气体小分子的电离解离。

Our experimental results are helpful in understanding the detailed MPI processes of Acetone and dimethyl sulfide.

这些结果的获得有助于对这两种分子的光电离-解离动力学有更全面详细的认识。

The basic conceptions, including adiabatic ionization energy, vertical ionization energy, superexcited states, photoionization cross section, Rydberg state of atomic and molecular, dissociation and predissociation are discussed in detail.

着重讨论了同步辐射真空紫外光在原子分子研究领域中的应用，详细讨论了光与物质相互作用的一些基本概念，包括绝热电离能、垂直电离能、超激发态、光电离截面、原子分子的Rydberg态及离解和预离解的定义及相关的背景知识。

Comparing with the result of methyl iodide in intense laser field, some differences are observed:(1) at the same laser field intensity, the highest charged fragment ion of methyl bromide was Br(superscript 3+), lower than I(superscript 6+) of methyl iodide;(2) the dehydrogenation channel was observed in the multiphoton dissociation or Coulomb explosion of methyl bromide, but was not observed in the case of methyl iodide;(3) HBr(superscript +) was observed, but there was no similar channel in the case of methyl iodide;(4) for methyl bromide, the valid charge distance of Coulomb explosion increases with the product of p and q; while in the case of methyl iodide, the distance remained almost the same;(5) the producing channel of CH(superscript + subscript m)(m=0, 1, 2) is different from the ionization-dissociation of methyl iodide in which the stepwise dissociation of CH3(superscript +) was thought to be the main channel, CH(superscript + subscript m)(m=0, 1, 2) of methyl bromide are mainly from the products of the direct dissociation of the dehydrogenated parent ions instead of the stepwise dissociation of CH3(superscript +).

与碘甲烷在强场中的实验结果对比发现：(1)在相同的激光场强下，碘甲烷电离解离的最高价碎片离子为I(上标 6+)而溴甲烷为Br(上标 3+)；(2)溴甲烷质谱中存在母体离子的脱氢产物CHBr和CHBr(上标 2+)，而对于碘甲烷，没有检测到这些通道，C-I键首先断开；(3)质谱中存在H^79Br和H^81Br，而碘甲烷的电离解离中不存在HI产物；(4)溴甲烷库仑两体爆炸的有效电荷间距随着两碎片电荷乘积的增大而增大，而对于碘甲烷此间距几乎不随电荷乘积变化；(5)CH(m=0， 1， 2)的主要生成通道可能与碘甲烷不同，不是来自CH3的顺序脱氢，而是来自脱氢母体离子的直接解离。

Ionization-dissociation of methyl bromide in intense laser field was studied using home-built reflection time-of-flight mass spectrometer.

利用自制的反射式飞行时间质谱仪研究了多原子分子CH3Br在强激光场中的电离解离。

In chapter four, the REMPI-TOF-MS of Carbon disulfide is investigated in the range of 283-289nm.

第四章主要报道了二硫化碳分子在283-289nm波长范围内的共振增强多光子电离-解离过程的实验研究结果和分析结果，主要内容有：(1)实验测定了二硫化碳分子的共振增强多光子电离的TOF质一谱和分质量的REMpl谱。

A number of v=0~57 vibration levels were determined and assigned. The levels cover more than 99% of the potential well depth of the state. No evident autoionization was found related to the levels belonging to the 13 g- state above the ionization threshold, implying the distinct character of the doubly excited valence state from the Rydberg states.

并发现13 g-态能级即使超过电离限时亦无明显的自电离倾向，反映了双电子激发态不同于里德堡态的独特性质。13 g-态是碱金属双原子分子电离限以下唯一的3 g-对称性的态和电离限下唯一较纯的双电子激发态，这些结果为分子结构和量子化学的定量研究提供了重要的信息；（2）通过检测Na 3d 3p原子荧光，观察到Na2分子的33 g和43 g+态在3s+3d解离限以上的预解离能级及其转动线宽加宽等。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。