电离常数

Using relativistic multi-configuration Dirac-Fock theory,we calculate the transition data of 3dj-nfj'(n=5,6,7) for the M-shell from an Ni-like Au ion to an As-like Au ion using the GRASP programme with the corepolarization,quantum electrodynamical effect and Breit correction.

根据扩展的相对论多组态Dirac-Fock理论计算得到的Au^47＋～Au^53＋离子的平均离子寿命、能级能量和能级简并度，计算了各离子的电离速率常数、复合速率常数和配分函数，并由此得到了离子间的电离-复合平衡常数。

The exact effective nuclear charge numbers have been defined andcalculated with the mean radius of the initial orbital of the active electron toconsider the combined -effects of relativity and screening in an actualtranstition calculation . The electron impact ionisation cross sections and thecorresponding ionisation rate coefficients of Li like ions 〓、〓、〓、〓and〓 have been calculated by using our calculated effective nuclearcharge numbers.

我们考虑并修正了原始理论中对屏蔽常数物理意义的不正确定义和算法，更精确考虑了其它电子对被电离电子的屏蔽效应以及相对论收缩对有效核电荷数的影响，得到了更可靠的有效核电荷数，并给出了更好的电离截面结果。

The non linear regression applied to relation of the proton change number of acid with the proton concentration may improve the precision of pKa determination.

它首先牵涉到有机酸在溶剂中的电离形式[1]，然后是电离平衡常数中活度系数的测定[2]，再者是非水质子溶剂或有机-水溶液中质子浓度的精确测定。

A relative formula was nrived between the ionization equilibrium constant and the chnarge density on that oxygen of hydroxide radical, and then the pH values of the colour ranges of these indicators was calculated with satisfaction.

提出了此系列指示剂的电离平衡常数和羟基中氧上的电荷密度的关系式，计算了这类指示剂的变色pH范围。

The ionization constant of H2CO3 is much higher than that of H2S in the solution , whereas the mole of CO2 is much lower than that of H2S in the sour gas of Feixianguan Formation.

在溶液中碳酸的电离常数大大高于氢硫酸，飞仙关组高含硫气藏天然气组分中的CO2相对于H2S的质量亏损和储层中有富轻碳的高温方解石充填晚期溶孔、裂缝表明储层中的晚期溶解作用是由硫酸盐热还原过程中生成的CO2引起的。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。