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In this thesis, multi-wall carbon nanotubeswas worked as a modified agent. The working electrode was a glassy carbon electrode or graphite electrode. A saturated calomel electrode and a platinum electrode were used as the reference and the auxiliary electrode respectively. Some pharmaceutics'electro-chemical behavior has been studied with great details. The main researches were summarized as follows: The acid-treated CNT was successfully dispersed into the DMF by using ultrasound technology.

本论文以多壁碳纳米管为修饰剂,以玻碳电极和石墨电极为工作电极,铂丝电极为对电极,饱和甘汞电极为参比电极,研究了几种药物的电化学行为及其检测方法,取得了以下研究结果:以N,N-二甲基甲酰胺为分散介质,将酸化后的MWNT超声分散于DMF中,获得分散液。

The battery electrode is characterized in that the battery electrode comprises an electrode frame which is arranged in the battery body, movable electrode particles are piled in the electrode frame, the electrode particles are negative particles or positive particles made of solid electrode material, the electrode frame has net-shaped structure and is connectively provided with an input pipeline and an output pipeline which extend out of the battery body, and the electrode frame is connectively provided with an electrode post head.

其特征在于包括安装在电池体内的电极框,电极框内堆积可活动的电极粒子,所述的电极粒子为固体电极材料制成的阴极粒子或阳极粒子,所述的电极框为网状结构,电极框上连接设置伸出电池体外的输入管道、输出管道,电极框上还连接设置电极接线柱。

the electrode system is one of the most sensitive and crucial parts in eit system.in this paper a method for eit electrode structure and parameter optimizing design,taking example for compound electrode,has been presented,which is based on the coercive equipotential node model of the line electrode.an imitation research plat-form of electrode structure and parameter optimizing design has been developed.by the methods,the variety influ-ences of electrode structure and parameters on reconstructed image and measurement sensitivity can be obtained.this will provide theory basis for the electrode construction optimizing design of real eit system.

eit电极系统是整个eit系统最为敏感和关键的部分之一。本文在线电极强制等势点模型的基础上,以复合电极为例,提出了一种电极结构及参数优化设计方法,并建立了电极结构参数优化设计仿真研究平台。可针对不同电极结构和各种参数变化给出其对eit成像质量和检测灵敏度的影响,进行优化设计,从而为实用化eit系统电极结构设计提供理论依据。

Cyclic voltammetry indicated that there were Cr→Cr, Cr →Cr oxidation reaction on anode, while there were Cr→Cr, Cr→Cr, Cr →Cr deoxidization reaction on cathode. The graphite electrodes treated by acid and heating could enhance the reversibility and kinetic of the electrode reaction. The nature graphite electrodes had been eroded during charge/discharge process, while the graphite electrodes by activation could avoide corroding by hexad chromium ion. The reversibility and kinetic of the electrode reaction of chromium ion on activation electrode had been increased, so which indicated that graphite surface augment oxygenous function corps which could increase electrode hydrophile capability.

循环伏安实验表明:铬液流电池的电极反应非常复杂,在阳极存在Cr→Cr,Cr→Cr的氧化反应,在阴极存在Cr→Cr,Cr→Cr,Cr→Cr的还原反应;热处理的石墨电极和重铬酸钾处理的石墨电极能提高电极反应的活性和可逆性;在充放电实验中未处理的石墨电极发生严重腐蚀;分别用这两种方法处理过的石墨电极具有防止六价铬侵蚀的功能;铬离子在活化处理过的石墨电极上的反应活性和可逆性增加,可以认为:重铬酸钾溶液活化处理和加热处理后的石墨表面的含氧官能团增加,电极亲水性增强。

2 A kind of enzyme and mediator modified electrode is devised by immobilyzing both N-methyl phenazine sulfate and glucose oxidase on the surface of carbon glassy electrode (GOD-NMP-GC electrode), which successfully realizes the electron transfer process between glucose oxidase and carbon glassy electrode.

将NMP-GC电极与葡萄糖氧化酶结合,制作了GOD-NMP-GC电极,该电极可快速实现电极=NMP介体=GOD活性中心=葡萄糖之间的电子长程转移,并且用循环伏安法对酶催化反应进行了研究;用含丰富乳酸脱氢酶的乳酸杆菌与NMP-GC电极相结合,制作了介体微生物电极,并检测到GC电极=NMP=LDH活性中心=乳酸之间的非均相电子转移。

A 2. 5~5. 5 MHz transducer was used according to the acoustic depth of the heart examined. Group B was used x-ray fluoroscopy (a Philip mono-rotatable C arm X-ray equipment) as image guide with routine method reported by american college of cardiology cardiovascular technology assessment committee. TTE guiding CSC in site: The guide wire was inserted into left subclavicular vein and inferior vena cava and it was displayed clearly by TTE. The sheath could be displayed clearly too by TTE. CSC was put through the sheath into right atrium in prone position and was thoroughly showed by TTE via untypical parasternal four-chamber view.

本研究对60例心内电生理检查患者,应用TTE作为影像学引导的可行性和临床应用的方法学进行了探讨,并对5只犬TEE引导射频导管消融术时大头电极导管到位的可行性进行了动物实验研究,具体为:(1)专用冠状窦电极导管置放时TTE引导的可行研究;(2)普通电极导管置放时TTE引导的可行研究;(3)专用冠状窦电极导管和普通冠状窦电极导管置放时TTE的对比研究:(4)TTE引导His束电极导管和右室电极导管到位的临床应用研究;(5)TTE在心内电生理检查中的应用研究;(6)TEE引导射频导管消融术大头电极导管到位的实验研究。

The method by drying/adsorption was used to prepare DNA adsorptively modified electrodes, and thus-resulting DNA-modified electrodes were electrochemically and spectroscopically characterized, including cyclic voltammetry, scanning tunneling microscopy, Raman spectroscopy, in-situ UV/Vis reflection spectroscopy, X-ray photoelectron spectroscopy, and alternating current impedance. Some information about the state of DNA immobilized on electrode surfaces was obtained.

鉴于此,本论文工作首先利用简便的干燥吸附法制备获得DNA吸附修饰电极,采用电化学方法及多种谱学仪器方法如STM,XPS,Raman,交流阻抗,UV-Vis现场光谱等对DNA修饰电极进行了表征,获得了有关DNA在电极表面状态等有价值的信息;又采用自组装单分子层修饰技术,制备出DNA共价键合修饰SAM/电极,并对制备条件进行了优化,利用XPS及电化学方法对修饰电极进行了表征。

The opaque main bus and auxiliary electrodes are combined with a transparent electrode portion that overlies the main bus and the auxiliary portions to form the display electrodes.

不透明的主和辅电极被与透明电极部分合并以形成显示电极,该透明电极部分覆盖在主汇流和辅电极部分。

The array chip takes a flexible transparent polyimide thin membrane as the base, the lower surface can form a cross comb-shaped array multimicroelectrode, the electrode group is composed of two comb-shaped microelectrode array electrodes which are mutually crossed but not contacted with the electrical structures not being connected, and the microchannel between the both internal electrodes of the electrode group serves as the service passage; the array chip is inversely buckled on the fusion pool, and the cross comb-shaped array multimicroelectrode on the array chip correspondes to the cell electric fusion pool and falls in the cell electric fusion pool.

阵列芯片以柔性透明聚酰亚胺薄膜为基底,下表面通过蚀刻形成交叉梳状阵列化微电极组,电极组由两个相互交叉、互不接触、电气结构上互不连接的梳状微电极阵列电极构成,电极组内部微电极之间的微通道为工作通道;阵列芯片倒扣于融合池上,其上的交叉梳状阵列化微电极组与细胞电融合池相对应,落于细胞电融合池中。

In this experiment, BSA and chitosan are taken as cross-linking reagents, and nanoparticles gel and uricase are cross-linked on egg membrane.

本研究将改性纳米SiO_2凝胶和尿酸酶通过交联剂固定于蛋膜上,将酶膜紧贴于铂盘电极表面,然后以自制铂片电极为对电极、甘汞电极为参比电极,组成三电极体系,测定体液中尿酸的浓度。

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