电子异构

In the development of this system, its security epically for resisting SQL Injection is researched primarily. A new resisting SQL Injection method via program validation and strengthening database security is put forward to reinforce the security of the system proposed in this paper.Combined with the practicality of XAUT hospital, this paper designs methods of EPR integration in different structure based on XML existing in centralized and distributive instance is designed, and an ophthalmologic electronic patient record system using XML which is a new hot research topic in the domain of medical system.

本文在对医院信息系统的研究热点——电子病历和XML技术进行研究的基础上，设计了在异构数据环境下基于XML的集中式和分散式的电子病历集成方法，并结合西安理工大学医院眼科的实际情况，设计了一个基于XML的眼科电子病西安理工大学硕士学位论文历系统， xAUT医院信息系统的设计与应用，提高了医院的工作效率和信息化程度，为医院的信息管理带来了方便。

The results indicate that thermal stabilities and decomposition mechanisms of the title compounds derived from the BDE, Ea and static electronic parameters are basically consistent. Homolysis of the N—NO2 bond is the initial step in the thermolysis of the title compounds, the meta-isomers are more stable than the para-isomers, and the ortho-isomers are the most sensitive.

结果表明，由BDE、Ea和静态电子结构参数推断的标题物热稳定性和热解机理的结论基本是一致的，N-NO2键均裂是标题物的热解引发步骤，间位取代异构体较对位取代异构体稳定，而邻位取代的异构体稳定性最差。

The excited-state intramolecular proton transfer tautomerism reaction of 6-methyl-4-hydroxy pyri-midine monomers and dimmers was investigated by the ab initio method with the self-consistent reaction field with Tomas's polarized continuum mode and CIS theories at HF level on the basis of 6-311+G* and 6-31G basis set. By studying the potential energy surface, it was found that the monomer's ground-state proton transfer process together with the excited-state proton transfer process is a molecular system of four energy level, but dimmers were not, which can be used to explain the fact that UV-visible absorption and fluorescence spectra of monomer and dimers all corresponded to quinoid.

采用 ab initio HF理论的组态相关CIS方法和连续溶剂模型PCM，分别在6-311+G*和6-31G水平上研究了6-甲基-4-羟基嘧啶单体及二聚体激发态质子转移的异构化反应；对其反应势能面的研究发现，单体基态和激发态的异构化反应一起可以形成四能级的分子电子体系，而二聚体的却不能，由此解释了单体和二聚体的紫外吸收光谱和荧光发射光谱均对应于酮式构型的原因。

In research and development of the system, mainly concluding key technologies of software-hardware environment analysis, no adapter interlink, terminal simulation, communication, sharing resources, binary file transfer algorithm , concurrent process, database-dumping and sharing, and to accomplish the basic a software design of E-classroom by adopting distribution system concept in minicomputer side , to accomplish the main software design of E-classroom by Winsock in microcomputer side , to study teacher software integration , try to realize transparent communication in the highest limit and sharing resources in the fullest extent , at last, weak and counter measure of the system is given, and the overall objective of heterogeneous computer is given to try to provide resemble system development with theory guide.

该系统的研究与设计过程中主要涉及软硬件环境分析、异型机无网卡互连、终端仿真、异型机通信、资源共享、二进制文件传输算法、并发进程、数据库转储与共享等关键技术，利用DSM分布式系统的概念完成了小型机部分电子教室的基础性软件设计，利用Winsock完成了微型机部分电子教室的主要功能模块，利用并发进程的概念研究了教师机软件的集成问题，使异型机用户之间达到最大限度的透明通信及充分的资源共享，给出了异构电子教室的弱点及解决对策，提出了系统的总体目标，力争为类似系统的研制提供理论指导。

RESULT: 1.Ouabain act on lens sodium-pump,under the LM,lens anterior capsular membrane discontinuous,epithelium cells clustered,occluding zonule seperated,lens fiber layers fractured.Under the EM,cells totally hollowed,mitochondria swelling,myelin figure appeared.RT-PCR examine the expression condition of αsubunit of sodium pump on mRNA level,α1、α2 and α3-isoform are all decreased.2.Digoxin act on lens sodium-pump,under the LM,lens cell oedema,linkage distructed,extensive exfoliation.Under the EM,plasma appeared little half-transparant hollow region,mitochondria swelling and ridge disappeared. RT-PCR examine,α1、α2 and α3-isoform are all decreased.3.Amphotericin B act on lens sodium-pump,under the LM,lens epithelium cells linked tightly,arranged in-line,lens fiber layers arranged tightly and regularily.Under the EM,abbundant cellular organes,exuberant cells function indicated. RT-PCR examine the expression condition of αsubunit of sodium pump on mRNA level,α1 and α3-isoform are increased significantly,demonstrated isoform-specific action.4D-thyroxine act on lens sodium-pump,under the LM,lens plasmalemma integrated,cells arranged tightly and regularily.Under the EM,nucleus fission appeared,desmosome half-desmosome and tensile microfilaments linked the cells. RT-PCR examine,α2 and α3-isoform are increased, also demonstrated isoform-specific action.5.Vitamin E act on lens sodium-pump,under the LM,lens anterior capsular membrane continuous and smooth,epithelium cells tightly linked,lens fiber layers appearede hollow region occasionally.Under the EM,lateral membrane high density belt appeared,abundant nucleolus. RT-PCR examine,onlyα1-isoform are increased, demonstrated significantly isoform-specific action.6.DMSO act on lens sodium-pump,under the LM,lens anterior capsular membrane slightly thicker,cells linkage partly distructed.Under the EM,plasmalemma denaturation,mitochondria swelling.RT-PCR examine,α1、α2 and α3-isoform are all altered slightly and haven't significant meanning.

结果：1、哇巴因作用于晶状体钠泵后，光镜下晶状体前囊膜断裂、上皮细胞聚积、闭合连接分离、纤维板层裂隙，电镜下全层细胞空泡化、线粒体肿胀出现髓样结构，RT-PCR法检测晶状体钠泵α亚单位α1、α2及α3三种重整异构体在mRNA水平的表达均减弱。2、地高辛作用于晶状体钠泵后，光镜下晶状体细胞水肿、细胞连接破坏、广泛剥离，电镜下胞质见少许半透明空化区、线粒体肿胀嵴消失，RT-PCR法检测晶状体钠泵α亚单位α1、α2及α3三种重整异构体在mRNA水平的表达均减弱。3、两性霉素B作用于晶状体钠泵后，光镜下晶状体上皮细胞紧密连接、线状排列、纤维板层紧密规整，电镜下细胞器丰富、细胞功能旺盛，RT-PCR法检测α1及α3表达显著增强、具有一定的重整异构作用特异性。4、D甲状腺素作用于晶状体钠泵后，光镜下晶状体质膜完整、细胞排列紧密规整，电镜下胞核见分裂像、细胞间有桥粒、半桥粒及张力微丝，RT-PCR法检测α2及α3表达均增强、亦有一定的重整异构作用特异性。5、维生素E作用于晶状体钠泵后，光镜下晶状体前囊膜连续光滑、上皮细胞紧密连接、纤维板层偶见空化，电镜下囊侧膜内有高电子密度带、细胞核仁丰富，RT-PCR法检测仅有α1的表达显著增强、具有极强的重整异构作用特异性。6、二甲基亚砜作用于晶状体钠泵后，光镜下晶状体前囊膜轻度增厚、细胞连接部分破坏，电镜下质膜变性、线粒体肿胀，RT-PCR法检测晶状体钠泵α亚单位α1、α2及α3三种重整异构体在mRNA水平的表达无显著改变。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

The present calculations demonstrate that O－ associates quickly with C2H4 to form ion-induced dipole complex, which can subsequently isomerize and decompose to various products, corresponding to molecular anions dissociation and associative electron detachment pathways, respectively.

计算结果表明， O－与C2H4经碰撞快速复合形成离子诱导偶极络合物中间体，然后经历异构化、解离生成各种产物，分别对应分子离子异构解离与复合电子剥离反应通道。

The present calculations demonstrate that O(superscript -) associates quickly with C2H4 to form ion-induced dipole complex, which can subsequently isomerize and decompose to various products, corresponding to molecular anions dissociation and associative electron detachment pathways, respectively.

计算结果表明，O与C2H4经碰撞决速复合形成离子诱导偶极络合物中间体，然后经历异构化、解离生成各种产物，分别对应分子离子异构解离与复合电子剥离反应通道。

Cis-C=C configuration on 2 position is easily isomerized to trans-form in environment according to literatures, but cycloproyl do it difficut relatively. So, replacement of 2,3- allyl unit by cyclopropyl group might give a practical method to get over the problem.

为解决脱落酸2位双键在环境中易光异构化为反式结构的问题，依据电子等排体原理，将2，3-位的烯丙型的结构改变为环丙型结构，将可能解决光异构化的问题。

The electronic spectra of C70H2 have been studied, of which the characteristic absorptions are consistent with the experimental results.

在此基础上预测C70F2和C70Cl2的稳定性和电子光谱，表明C70F2四种异构体的稳定性顺序与C70H2一致，而C70Cl2则以21， 42-异构体最为稳定。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐