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电子云

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At the normal state, porphyrin molecules do not have EPR signal. However, light excitation may cause a transition of porphyrin molecules from singlet to triplet. At the same time, the change from diamagnetism to paramagnetism occurred to porphyrin molecules. In this case, the two un-paired electrons are nearby each other and cause a strong interaction, giving EPH signal with sharp peak at g = 2.000. The g value increased with an increase in electron cloud density.

常态下卟啉分子没有EPR信号,在光的激发下,卟啉分子由原来的逆磁性分子变成顺磁性的激发三重态分子,这种激发三重态分子在分子轨道上具有两个未成对电子,这两个电子相距很近,彼此之间发生很强的相互作用而产生电子,它的g值随卟啉共轭体系平均电子云密度增大而变大。

At the normal state, porphyrin molecules do not have EPR signal. However, light excitation may cause a transition of porphyrin molecules from singlet to triplet. At the same time, the change from diamagnetism to paramagnetism occurred to porphyrin molecules. In this case, the two un-paired electrons are nearby each other and cause a strong interaction, giving EPR signal with sharp peak at g =2.000. The g value increased with an increase in electron cloud density.

常态下卟啉分子没有EPR信号,在光的激发下,卟啉分子由原来的逆磁性分子变成顺磁性的激发三重态分子,这种激发三重态分子在分子轨道上具有两个未成对电子,这两个电子相距很近,彼此之间发生很强的相互作用而产生电子,它的 g 值随卟啉共轭体系平均电子云密度增大而变大。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为:芳胺与七氟异丙基碘的物质的量比1:1.1~1.5,连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3,相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1,溶剂总用量使苯胺浓度在0.5~1.0 mol/L;反应温度10~20℃;溶剂采用乙醚。取代基供电子性越强,反应时间越短,产率越高;氨基的对位优先反应,氨基的邻位较难发生反应;且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

Its response is dominantly assigned to the ultrafast distortion of the electron cloud.

其超快响应主要归因于玻璃中电子云的超快畸变。

Have had the intense function fromthis the explanation preparation and DNA, matched the body the planearyl residue groups and bases to insert the DNA double spiral plane,caused the plane aryl residue groups and bases the electronic clouddensity to have the change.

由此说明配合物和DNA发生了强烈作用,配体的平面芳基基团插入了DNA的双螺旋平面,导致平面芳基基团的电子云密度发生改变。

I can see many electron cloud suddenly vanish on the originally track,then jump to the higher energy level track.

我可以看到很多电子云突然间在自己原本的轨道上消失,然后跃迁到更高能级的轨道上。

Each of the radio lobe, both with a high magnetic field high-energy electron cloud.

每个射电瓣都是具有较高磁场的高能电子云

The two molecules get closer, the electron cloud overlap, so that two molecules repel each other.

两个分子靠得更近时,电子云互相重叠,使两个分子互相排斥。

At the same time, electron cloud density of the nitrogen atom may be taken as the key factor to be correlation with the biodegradation property.

同时还提出了用捕收剂分子中N原子上的电子云密度可作为衡量捕收剂生物降解性的重要参数。

Most of the atom's volume consists of a cloud of electron s that have very small mass and negative charge.

原子核被弥散的电子云环绕,电子是带负电的几乎没有质量的粒子。

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