电化学

ABSTRACT In this dissertation, the electrochemical performances of perovskite bi-functional oxygen electrodes are studied.

本论文以系统研究钙钛矿型双功能氧电极的电化学性能为工作目的。

Monolayer.2. A Novel Sensor Based on Layer-by-Layer Hybridized Phosphomolybdate and Poly on a Cysteamine Modified Gold ElectrodeA novel sensor have been constructed by layer-by-layer hybridizing phosphomolybdate and poly on a cysteamine modified gold electrode.

磷钼杂多酸和聚二茂铁硅烷多层组装膜修饰电极及其电化学行为采用层层组装法在金电极上组装多金属氧酸盐阴离子和聚阳离子聚二茂铁硅烷，交替沉积多层膜，构建了杂多酸-PFS多层膜修饰的金电极。

On the basis of ascertaining that phosphomolybdic acid modified platinum electrode has higher catalytic activity to methanol oxidation , three kinds of transition metal substituted phosphomolybdic acids were synthesized, and the IR spectrum indicated that the compounds still kept Keggin structure.

在证实了磷钼酸修饰铂电极对甲醇氧化具有较高活性的基础上，合成了3种过渡金属取代的磷钼酸，通过红外光谱测试仍为Keggin结构，并制备了过渡金属取代磷钼酸修饰铂电极，研究了修饰铂电极在硫酸溶液中的电化学行为及对甲醇的催化氧化作用。

In order to improve the electrocatalytic activity of the anode in the Direct Methanol Feul Cell, three kinds of transition metal substituted phosphomolybdic acid modified platinum electrodes were prepared, and the electrochemical behavior in the sulphuric acid solution of transition metal substituted phosphomolybdic acid modified platinum electrodes and their electrocatalytic effects of methanol oxidation were studyed. The anti-poison effect to carbon monoxide of the prepared electrodes were studied by the carbon monoxide adsorbing.

为了提高直接甲醇燃料电池阳极催化活性，本文研究了三种过渡金属取代磷钼酸修饰铂电极在硫酸溶液中的电化学行为及对甲醇的电催化氧化作用，并利用一氧化碳吸附实验评价了三种过渡金属取代磷钼酸修饰铂电极的抗一氧化碳毒化性能。

UV-Vis spectra show that the absorbance values at characteristic wavelengths of the multilayer films increase almost linearly with the number of chitosan/PTA bilayers, suggesting that the deposition process is regular and highly reproducible from layer to layer. XPS and FTIR spectra confirm the incorporation of chitosan and PTA into the films. AFM images indicate that the surface of the multilayer films is rough. The result of CV shows that the multiplayer films maintain good electrocatalytic activity of phosphotungstate acid.

UV-Vis结果显示多层膜在特征吸收峰处的吸光度数值随膜双层数增加逐渐增大，呈良好的线性关系，表明多层膜是均匀组装的；XPS和FTIR结果证实了壳聚糖和磷钨酸被组装到膜上，AFM图形显示膜表面有一定的粗糙度，CV结果说明多层膜保留了磷钨酸的电化学性质。

It was found that photochemical deposition of Hg occurred at the layer of TiO2 covering the surface of titanium electrode under UV irradiation, the adsorption of sulfadiazine on the photochemically deposited Hg was stronger than that on the electrochemically deposited Hg, and a method for the determination of sulfadiazine was proposed by the adsorptive stripping voltammetry based on photo-chemical deposition of Hg on Ti electrode.

该研究发现采用紫外光照射钛电极表面氧化钛层能够光催化还原Hg(上标致2+)生成Hg微粒，在Ti基电极上光化学沉积Hg比电化学沉积Hg对磺胺嘧啶具有更强的吸附作用，基于光化学沉积Hg/Ti电极建立了一种吸附溶出伏安法测定磺胺嘧啶的方法。

The photophysical properties, thermal properties, electrochemical properties of all compounds and electroluminescence properties of some compounds were investigated detailedly.

我们详细研究了各种化合物的光物理、热物理和电化学性质以及部分化合物的电致发光器件性能。

Considerable attention has really been focused on ionic liquids as "green" alternatives to classical environmentally damaging organic solvents in many fields such as in organosynthesis, material, catalysis, electrochemistry, biochemistry, physicochemistry, separation and so on. However, there have been only a few examples of chiral ILs have been reported so far, and ILs possessing chirality are having been synthesized aimed at application in asymmetric catalytic reaction.

离子液体在许多领域如电化学、有机合成、催化、生物化学、物理化学、材料及分离等的绿色替代溶剂技术引起了人们的重视，然而，有关手性离子液体的合成与应用的报道比较少，含有手性片段的离子液体不断被合成出来并期望在不对称催化反应中得到应用，但是成功的例子不多，使用手性离子液体在不对称催化反应中还在初始的探索阶段。

Methods The changes of the diameters and the NO on gerbils' pial diameter microvessels were measured by using Laser Doppler and electrical chemistry. The ultrastructure of gerbils'cortex microvessels was observed.

方法采用激光多普勒、电化学和超微病理方法分别测量和观察沙土鼠软脑膜微血管管径、NO含量和脑皮层微血管超微结构的变化。

In order to improve the electrochemical performance of LiCoO2, the majorities of researchers are working on the adjustment and substitution of the lay element, in order to increase the extract and deintercalated quantity and overcharge-resistant ability, the method pillaring in the interbed is brought forward for strengthening the structure stability.

目前为了改善LiCoO2的电化学性能，多数研究者进行的是层板元素的调控和替换，但实际效果仍不甚理想，我们采取层间柱撑金属离子的办法来提高材料的结构稳定性，以增加LiCoO2材料的锂离子可脱嵌量以及耐过充电压。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。