电催化作用

The degradation experiments of benzamide by photocatalysis and electrically assisted photocatalysis demonstrated that the extra electric field had the obvious assistant effect on photocatalysis and the benzamide degradation rate by EAP was much higher than that by photocatalysis. When the electrode potential of photocatalyst was -0.05V/SCE, the removal efficiency of benzamide could be 95% in 120min.

苯甲酰胺降解试验表明，外加电场对光催化氧化技术具有较强的辅助作用，电助光催化氧化技术的处理效率远远高于光催化氧化技术，当施加的电极电位为-0.05V时，苯甲酰胺在120min时的去除率可达95%。

With the deposition of Pt, a rough electrocatalytic Pt layer would form on the surface of Ti alloy.

在腐蚀介质的作用下，Pt与Ti的化合物分解，Pt沉淀到晶体表面造成Pt在合金表面形成凹凸不平的Pt电催化层。

Under the same conditions, the electrocatalytic ability of the electrode was higher than that of the pure Pt electrode.

结果表明Pt-Ru微粒电极对甲醇的电氧化显示出催化作用， Ru的加入提高了电极的抗中毒能力。

In the first part of this work, it has been demonstrated that the ordered mesostructure of OMC plays an important role in the electrocatalytic activity towards the thiols and the destruction of this structure results in the decrease of such properties.

在论文第一部分中，我们介绍了介孔碳在硫醇类物质的电催化活性中所起的重要作用，以及介孔碳结构的变化导致这些性质的下降。

The direct electroreduction of nitrite requires large overpotential on most electrode surfaces, however, various transition-metal complexes were proved to be good catalysts for nitrite reduction.

NO〓〓的直接电还原需要很高的过电位，但各种各样的金属配合物被证明是NO〓〓电还原的良好催化剂，而我们在实验中惊奇地发现一系列饱和未取代的和稀土取代的杂多化合物对NO〓〓还原产生良好的催化作用。

In order to improve the electrocatalytic activity of the anode in the Direct Methanol Feul Cell, three kinds of transition metal substituted phosphomolybdic acid modified platinum electrodes were prepared, and the electrochemical behavior in the sulphuric acid solution of transition metal substituted phosphomolybdic acid modified platinum electrodes and their electrocatalytic effects of methanol oxidation were studyed. The anti-poison effect to carbon monoxide of the prepared electrodes were studied by the carbon monoxide adsorbing.

为了提高直接甲醇燃料电池阳极催化活性，本文研究了三种过渡金属取代磷钼酸修饰铂电极在硫酸溶液中的电化学行为及对甲醇的电催化氧化作用，并利用一氧化碳吸附实验评价了三种过渡金属取代磷钼酸修饰铂电极的抗一氧化碳毒化性能。

The present dissertation deals with:(1) Exploring the feasibility of the CO〓 methanation and the conversion CH〓/H〓 into C〓 hydrocarbons under plasma with catalyst at ambient temperature and atmosphere.(2) Designing a reactor and preparing some catalysts suited for the conversion of carbon dioxide via the cooperation effect of plasma and catalysts.(3) Optimizing reaction conditions of conversion carbon dioxide to C〓 hydrocarbons in the proposed process.(4) Studying the reaction mechanism of conversion carbon dioxide to C〓 hydrocarbons under plasma by using in situ OES technology.(5) By the results of characterizing coked catalysts, exploring the reasons that result in the coking of catalyst and the paths for decreasing the deposit in the catalyst under plasma.(6) Analyzing the energy efficiency of the plasma catalysis and exploring the paths for improving the energy efficiency.

论文的主要研究工作包括：（1）探索脉冲电晕等离子体与催化剂共同作用CO〓／H〓甲烷化和由CH〓/H〓合成C〓烃反应的可行性；（2）研制等离子体催化CO〓转化的反应器和适配的催化剂；（3）优化等离子体催化CO〓转化制C〓烃反应的工艺条件和电参数；（4）利用原子发射光谱原位技术对等离子体反应的诊断结果，对等离子体催化CO〓转化制C〓烃反应的机理进行推断；（5）通过对积碳催化剂的表征结果，分析积碳的类型及其成因，并探讨减少积碳的途径；（6）通过对等离子体催化CO〓转化制C〓烃反应能量效率的分析，探讨提高等离子体催化反应能量效率的途径。

And the anodic peak potential shifted negatively 245mV. The test indicates that cauliflowers have a outstanding effect on Electrocatal yticOxidation and the test is very sensitive, fast and selective.

该电极与纯碳糊电极的性能进行比较，证明花椰菜对V_c有明显的电催化氧化作用，检测灵敏、快速、选择性好，同时，提高了电极的稳定性和重现性。

The following main results are obtained: The TiO_2 photocatalyst with small crystallite size, high surface area, narrow and uniform pore size distribution, and microporous frameworks could be prepared out by applying MW radiation in the preparation process. The microwave-induced fluorescence technique verified for the first time that microwave enhanced the formation rate of hydroxyl radical, leading to the increase in the photocatalytic efficiency. Compared with the conventional catalyst, TiO_2 prepared by MW dielectric heating owns a higher UV absorption ability, and its optical absorption edge and photovoltaic response are shifted toward the short wavelength region, resulting in increase of photooxidation efficiency. The photocatalytic conversion and the mineralization ratio of acetaldehyde are increased respectively by 30% and 40% over the TiO2 prepared by MW radiation when compared to the TiO2 prepared by the conventional heating. For the MW-assisted photocatalytic reaction over the MW-prepared TiO2, production of hydroxyl radicals is enhanced by 22.5%, and the photocatalytic conversion is accordingly increased by 20%. Similarlly, applying MW also increased the photocatalytic conversion and the mineralization ratio of acetaldehyde over TiO2/Al2O3 sample.

论文得到如下主要结果和结论：(1)微波介电加热TiO_2 溶胶可得到晶粒度小、光催化活性高、比表面积大和孔径分布窄而均一，且微孔发达的TiO_2光催化剂；在溶胶干燥处理过程中微波可使催化剂表面缺陷增加，进而导致光催化反应过程有更多的活性羟基自由基产生；(2)微波制备能显著增强TiO_2 样品的紫外光吸收率，并使其光吸收和光伏响应阈值发生蓝移，从而提高TiO_2的氧化还原能力；(3)与常规加热法所制TiO_2比较，微波法制备的TiO_2对乙醛的光催化降解转化率提高30%，CO_2生成率提高40%以上；(4)与未加微波辐射时相比，发现在光催化反应过程中施加微波，TiO_2 的羟基自由基生成速率提高了22.5%，相应CH_3CHO 光催化降解转化率提高了20%；对Al_2O_3/TiO_2催化剂，CH_3CHO 光催化降解转化率甚至提高了33%，同时CO_2 的生成率也都大幅度提高；(5)微波辐射可改变光催化降解乙醛的产物分布，推断施加微波时乙醛光催化降解按照羟基自由基引发的链式反应机理进行，微波&非热效应&起主要作用。

Electrocatalytic oxidation is further carried out in the presence of the ·OH radical scavenger tert -butyl alcohol, which indicates that both direct and indirect oxidation are responsible for the degradation of phenol.

加入·OH清除剂叔丁醇的研究表明，本体系中苯酚的电催化氧化是由直接氧化和间接氧化的协同作用共同去除。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新