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电催化

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Their electrochemical behaviors for single solute and mixed systems of hydroquinone(H2Q) and pyrocatechol are investigated.A pair of redox peak of H2Q and two pairs of redox peaks of PC on the composite film electrodes can be obviously distinguished in their mixed systems,which show the composite film electrodes have excellent electrocatalytic activity for two ...

结果表明聚苯胺复合膜电极具有很好的电催化作用,在混合体系中对苯二酚的一对氧化还原峰和邻苯二酚的两对氧化还原峰能够清楚地区分;并且在一定的浓度范围内单组分的浓度与峰电流呈良好的线性关系,说明该电极对苯二酚的测定在定性、定量中具有潜在的应用价值。

Analysis of the treated aqueous solution was conducted with GC-MS,and the main intermediates during phenol degradation were isobutyric acid,malonic acid,benzoquinone,butenoic acid,oxalic acid,maleic acid,succinic acid,hydroquinone,catechol and resorcin.

利用GC-MS分析了苯酚降解主要中间产物为异丁酸、丙二酸、对苯醌、丁烯酸、乙二酸、顺丁烯二酸、丁二酸、邻苯二酚、对苯二酚及间苯二酚等,并据此推测了苯酚电催化氧化的可能反应途径。

The invention relates to a method for treating gaseous VOCs by a solid extraction-electro-catalytic oxidation method and a device thereof. The method has the steps that: firstly, an electromagnetic type air compressor is used for controlling the gas flowing velocity by a glass rotameter so as to ensure contaminations in the contamination solution in a gas washing bottle to be stripped into an electrochemical reactor; secondly, microporous aeration heads are distributed in the electrochemical reactor, after being stripped into the electrochemical reactor, the gas is distributed in the electrochemical reactor by the microporous aeration heads, takes parts in the electrochemical reaction and passes through the cathode of absorptive and conductive porous material and the anode of iron sheet in sequence; thirdly, the treated gas finally flows out from the top end of the electrochemical reactor and enters into the gas absorption solution.

本发明涉及一种固态萃取-电催化氧化法处理气态VOCs的方法及装置,方法步骤:第一步,电磁式空压机通过玻璃转子流量计控制气体流速,将气体洗瓶中的污染物溶液中的污染物吹脱进电化学反应器;第二步:电化学反应器中布有微孔曝气头,气体吹脱进入电化学反应器后,通过微孔曝气头分布于电化学反应器内,参加电化学反应,依次经过通过吸附性导电多孔材料阴极和Fe片阳极;第三步,经处理后的气体最后从电化学反应器顶端流出进入气体吸收溶液。

The electrocatalytic activity of GNFs is significantly higher than that of the spherically shaped citrate-stabilized Au nanoparticles.

金纳米花的电催化活度也比球形的柠檬酸盐稳定的纳米金颗粒高的多。

The morphology, structure, and electrochemical activity of the prepared electrodes have been analyzed by TEM, XRD, and cyclic voltammeter.

电化学循环伏安法测试的结果显示,利用这种方法制备的纳米PtRu/C催化剂对于甲醇氧化具有较强的抗中毒能力和较高的电催化活性。

The catalyst was characterized by transmission electron microscopy, X-ray diffraction and energy dispersion X-ray spectrum.

利用透射电镜、X-射线衍射和能量散射X-射线能谱对催化剂进行了表征,并用循环伏安实验评价了催化剂对甲醇电化学氧化的电催化活性。

The rate constant for the chem. reaction of benzoquinone with reduced GOD was measured, and the advantage of benzoquinone over oxygen as a mediator in bioelectrocatalysis was discussed.

测定了苯醌同还原态GOD的化学反应速度常数,并讨论用苯醌代替氧作为生物电催化中的电子传递体的优点。

The EIS results suggest that proper amount of Ti and Co doping improve the electrochemical catalytical activity on the Mg-based alloy surface significantly.

EIS测试结果表明Ti和Co的替代可以明显提高MgNi型合金表面的电催化活性。

The relationship between current density and overpotential as well as overpotential and cell voltage were examined in different catholyte as well as with of without liquid supporting electrolyte.

结果表明,PbO2–SPE组合电极对羟基新戊醛有一定的电催化活性,并且有较高的电流响应,同时PbO2-SPE膜组合电极在无液相支持电解质时,同样能保持高电流密度和低槽压的优势。

ABSTRACT Objective To research the electrocatalytic action of poly film modifing electrode for determination of ciprofloxacin hydrochloride, an electroanalytic method of content determination CPLX was set up.

目的 研究聚中性红薄膜修饰电极对盐酸环丙沙星的电催化作用,建立一种定量检测CPLX的电化学分析方法。

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