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电催化

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The results of asymmetric reduction of latent chiral ketones by carbonyl reductase showed that the enzyme had a high specificity for pentanone in aliphatic ketones and for the acetophenone derivates that contained a withdrawing group at α-position.

利用羰基还原酶不对称催化还原潜手性酮类化合物发现,对于芳香酮类化合物,酶对α位为强电负性基团的底物专一性较强;对于脂肪酮类化合物,酶对五碳脂肪酮的专性较高。

The smaller the electronegativity is, the higher oxidation activity is. Thus phosphomolybdic acid shows better catalytic oxidation activity than phosphotungstic acid.

由于磷钨酸中的钨可以脱出并少量沉积到催化剂表面,而且从电负性来说Mo-O的键能小于W-O,键能小的杂多酸有较强的氧化性,所以钼系杂多酸催化活性要好于钨系杂多酸。

Due to the tremendous potential applications in the field of catalysis, photics, electrics, magnetics and so on, mesoporous rare-earth oxides have gradually attracted the attention of many researchers.

介孔稀土氧化物由于在催化、光、电、磁等领域具有巨大应用潜力,已逐渐成为一个研究的热点。

The synthesis of terephthalic acid by indirect electro-oxidation was studied and the optimum conditions were examined.

研究用UV/TiO2悬浮液光催化氧化和间接电氧化相结合的方法降解一种模型有机污染物———碱性品红。

The electroactive species Fe2+ can be transported easily through the thin films of KVFe6 to the underlaying glassy C electrode surface to be oxidized directly at less pos. potential, and it can also be oxidized at the film at more pos. potential by means of redox sites in the film.

电活性质点Fe^3^+可穿透六氰亚铁钒薄膜在玻璃碳基体电极表面于较负电位处直接氧化,也可经VHF膜中氧化还原点位的媒介在较正电位处理膜-溶液界面及膜内部发生催化氧化。

Mesoporous zincum sulfide materials have the unique character of photoelectricity, with nicer applying foreground in photocatalysis、photoconducting device、photochromic materials、electrechromic materials and so on .

硫化锌介孔材料具有独特的光电性质,在光催化、光电器件、光致变色材料、电致变色材料等方面展示良好的应用前景。

Traditional fuel cells work by using a catalytic material to oxidise a fuel, such as hydrogen, and make an electric current flow between two electrodes.

传统的燃料电池是通过催化材料来氧化燃料,然后使两电级间产生电流。

Glutathione S-transferase, an important detoxification enzyme in mammalian cells, canalizes the conjugateion of GSH with electrophilic xenobiotics to facilitate their excretion from the body.

Glutathione S-transferase 为哺乳动物细胞中一重要的解毒酵素,它可以催化GSH与攻击DNA的亲电性外来物质结合,并将之代谢排出体外。

Chiral nonracemic fluoro-organic molecules with a fluorine atom on a stereogenic center are readily prepared via chiral electrophilic fluorinating reagent-mediated enantioselective fluorinations, substrate-controlled enantioselective electrophilic fluorinations, chiral metal complexes and asymmetric catalyst—directed catalytic enantioselective fluorinations.

高光学活性的手性氟化物可通过手性亲电氟化试剂诱导的立体选择性氟化反应,基于底物的手性氟化反应以及手性催化剂诱导的不对称催化氟化反应等来制备。

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