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电催化

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The electrocatalytic reoxidation properties of guanine, adenine, and theirmixture by the Iron hexacyanoferrate films were determined and show differentelectrocatalytic properties in K+ and Na+ aqueous solutions.

铁赤血盐薄膜在K+和Na+的电解液中对於鸟嘌呤、腺嘌呤和该混合状态下显示有不同的电催化氧化性质。

The results show that single phase of La0.3Ca0.7FeO3 can be obtained at 800℃ for calcining 2 h, and the sample with 17.9 nm belongs to rhombohedral crystal system. Moreover, oxygen electrodes have obviously electrocatalytic activity.

结果表明:800℃焙烧2 h得到完整的晶体,晶体粒子大小均匀,粒径为17.9 nm,为菱形晶系;同时该氧电极具有明显的电催化特性。

A direct method to prepare nanometre catalyst of positive electrode for methyl alcohol fuel battery is to add strong oxidant to a mixed solution of manganese nitrate and some other metal nitrate, to coat them on the graphite electrode to have catalyst precursor produced, then to prepare the non-platinum nanometre catalyst of metal ion-doped manganese dioxide with carbon as a carrier by thermolytic reaction of the in-situ precursor. The prepared catalyst has the advantages of high electrical catalytic activity of methyl alcohol, high performance to protect against CO poison and low price, and it can lower the battery manufacturing cost effectively as well as can raise the entire electrical property of the battery so that the price performance and the market competitive edge of the battery are enchnaced effectively.

一种直接甲醇燃料电池阳极纳米催化剂的制备方法是在硝酸锰和其它金属硝酸盐的混合溶液中加入强氧化剂,涂抹于石墨电极上制成催化剂先驱体,通过先驱体在原位的热分解反应来制备以碳为载体的金属离子掺杂二氧化锰非铂纳米催化剂;制得的催化剂具有高的甲醇电催化活性、高的抗CO毒化性能以及低廉的价格等优点,可以有效地降低电池的制造成本,提高电池的整体电性能,从而有效地提高直接甲醇燃料电池的性能价格比及市场竞争能力。

This research is the combination of enzyme immunoassay and voltaic enzyme sensor.

研究的技术背景电催化酶促反应,文中对其动力学进行了理论分析。

The factors such as voltaic density and pH are the systematic research in the process of degrading p-nitrophenol.

探讨了电流密度、电解质浓度、初始pH等因素对电催化氧化对4-硝基苯酚效果的影响。

Electrochemical voltametric methods and in-situ electrochemical surface-enhanced Raman spectroscopy were used to investigate the electrooxidation behavior of ethanol in different media on a roughened platinum electrode.

采用常规电化学伏安技术和电化学原位表面增强拉曼光谱(in-situ SERS)技术研究了不同介质中乙醇在粗糙铂电极上的电催化氧化行为。

It is found that CH3OH adsorbs on PANI-Fc electrode before its electrocatalytic oxidation and the methanol oxidation can start at 2M CH3OH.

研究发现,在 CH3OH 的电催化氧化之前,它首先吸附在电极表面上,甲醇氧化的起始浓度为 2M。

The agglomerates of Pt nanoparticles have also been found to exhibit significant electrocatalytic activity for the oxidation of methanol.

研究还发现团聚态的Pt纳米粒子对甲醇氧化具有较好电催化特性。

Compared with the bare carbon paste electrode, the anodic peak potential shifted negatively by 0.152V and the cathodic peak potential shifted positively by 0.161V for CVs of hydroquinone on the CAW modified carbon paste electrode. The reversibility of the reaction became obviously better, showing the high electrocatalytic activity of CAWs to electrochemical oxidation of Hydroquinone.

与未加碳原子线的空白碳糊电极相比,碳原子线修饰碳糊电极可使对苯二酚的氧化峰负移0.152V,还原峰正移0.161V,ΔEp减小了0.313V,反应的可逆性明显变好,说明该电极具有较高的电催化活性。

Anode materials for hydrogen production by electrolyzing seawater were investigated.

对具有析氧抑氯选择电催化性能的海水电解制氢用绿色环保阳极材料进行了研究。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

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