甲醇

In this paper, the short-time photodissociation dynamics of benzanilide in methanol and acetonitrile solution has been studied by resonance Raman techniqueand quantum chemistry calculations.

采用共振拉曼光谱技术和量子化学计算研究了苯甲酰苯胺在甲醇和乙腈溶液中的短时光化学动力学行为。

Sixteen compounds were separated from 80% ethanol extract of Plant A, they were:-lariciresinol,-isolariciresinol,-isolariciresinol 9-O-β-D-glucopyranoside, tanegoside B, apiginin, apigenin 7-O-β-D-glucoside, apigenin 7-O-β-neospheroside, quercetin 3-O-β-D-glucopyranoside, 1, 7-dihydroxy-3, 4-dimethoxyxanthone, 3-O- [α-L-rhamnopyranosyl (1-4 ] -β-D-glucopyranoside-(25S)-5β-spirostan-3β-ol , 3β-O-D-glucopyranoside quinovic acid, mangiferin , 3'-p-hydroxybenzoyl-mangiferin, physcion, benzenyl methanol β-D-glucopyranoside and Vanillic acid.

结果： 1。从植物A的80％乙醇提取物中共分离得到16个化合物，分别为：-落叶松脂醇、-异落叶松脂醇、异落叶松脂醇9-O-β-D-吡喃葡萄糖苷、tanegoside B、芹菜素、芹菜素7-O-β-葡萄糖苷、芹菜素7-O-β-新橙皮糖苷、槲皮素3-O-β-D-吡喃葡萄糖苷、1，7-二羟基-3，4-二甲氧基-口山酮、菝葜皂苷元-3-O-[α-L-吡喃鼠李糖基（1-4）]-β-D-吡喃葡萄糖苷、喹诺酸3β-O-D-葡萄糖苷、知母宁、3′-对羟基苯甲酸-知母宁、大黄素甲醚、苯甲醇-β-D-吡喃葡萄糖苷、香草酸。

The eight VOCs were acetophenone, phenol, benzotrichloride, 1, 3-butadiene, chlorobenzene, methanol, methyl chloroform and methylene chloride. They were mixed together with very low concentrations.

所测定的八种VOCs为苯乙酮，苯酚，三氯甲苯，1，3丁二烯，氯苯，甲醇，三氯代乙烷和二氯甲烷。

Various alcohols are tolerable under the present conditions including benzylic alcohols,allylic alcohols as well as simple aliphatic alcohols.

普通烷基醇如环己醇，甚至最简单的甲醇和乙醇也能顺利反应，产率中等。在这个反应中，磷钨酸能够顺利回收，并在此被用于催化反应，活性没有降低。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

In this thesis betulin was purified by recrystallization with chloroform and methanol mixture, and orthogonal design had been taken to optimize the conditions of recrystallization including the volume and ratio of chloroform and methanol mixtures.

在白桦酯醇的纯化方面目前比较成熟的方法是氯仿+甲醇混合溶剂重结晶来纯化白桦酯醇，本文通过正交设计，得到最优化的溶剂比例和用量。

MATERIAL AND METHODS: Betulin was isolated from dry powder of the bark of silver birch by using ethanol circumfluence, decompress concentration and methanol-chloroform recrystallization.

材料与方法：取一定量的白桦树皮干粉，通过乙醇回流，减压浓缩和甲醇-氯仿重结晶等步骤获得白桦酯醇纯品。

A Theoretical Study on the Reaction Mechanism of Epoxidation Reaction of the 4- Bicyclo

CEPS 思博网--文章书目；-1页数：7 需求点数：28 电子全文：请登入。篇名（4-溴甲基双环[4.4.1]-1，3，5，7，9-十一碳五烯基－3-）甲醇环氧化反应机理的理论研究

The title compound was colorless crystal synthesized via the reaction of 4, 4'-bipyridine and HgI2 in the mixtured solution of methanol and tetrahydrofuran.

标题化合物是双齿配体4，4'-联吡啶与碘化汞在甲醇和四氢吨位呋喃混合溶液中反应得到的无色晶体。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。