甲醇

Alkylation of methylnaphthalene and methanol over HZSM-5 zeolite can make 2, 6-dimethylnaphthalene (2, 6-DMN) and the product stream contains isomers of 2, 6-DMN and unreacted MN, which requires efficient separation.

以甲基萘和甲醇为原料，采用HZSM-5烷基化催化剂制取2，6-二甲基萘(2，6-DMN)。由于产物中含有2，6-DMN的异构体以及未反应的MN，需对反应产物进行有效分离。

The cyclic voltammetric behavior of platinum-ruthenium alloy catalysts was studied by using the powder microelectrode technique and glass carbon electrode.

利用玻碳电极和粉末微电极测试甲醇在Pt-Ru/C催化剂上的循环伏安曲线。

At each fixed solvent composition,the mean activity coefficients of KI decrease at first and then increase with KI molality increases.At each fixed KI molality,the activity coefficients decrease with an increase of methanol in solvent mixtures.

目前文献报道较多的是单一电解质在混合溶剂中活度系数的测定[2-5]以及混合电解质体系活度系数的测定[6-9]，但KI在甲醇-水混合溶剂中的活度系数测定尚未见报道。

The optimum reaction conditions were found finally. The results showed that the suitable conditions are under methanol solvent reaction temperature 40℃,the concentration of catalyzer TS-1 0.6%.,reaction time 60 minutes,propylene pressure 0.4Mpa under methanol solvent.Under Supercritical fluid system,the reaction temperature was 33.7℃(supercritical and near critical temperature),the reaction pressure was 7.58Mpa(near critical pressure and critical pressure range. propylene ), propylene pressure 0.65Mpa, reaction time 45min, cosolvent molality 4%.

而超临界体系下反(来源：4e56ABC论文网www.abclunwen.com)应温度适宜在近超临界和临界温度(33.7℃)以上，反应压力也是接近临界压力或者处于临界压力范围(7.58Mpa)，丙烯压力是0.65Mpa，反应时间45min，共溶剂甲醇摩尔浓度4%，在此反应条件下，反应的转化率98%，选择性96%，收率94%，与传统条件相比较，收率提高了20%左右。

The molecular radius and molar volume in gas, the dipole moment in gas, water and methanol, the sum of negative Mülliken charges and the frontier molecular orbital were also calculated at the same level.

在气相条件下计算了分子的半径及分子的体积，并在气相、水和甲醇介质中计算了分子的偶极矩、分子中原子的Mülliken电荷、分子的前线轨道。

The present invention adopts the technical proposal of adopting ZSM-5 mesoporous molecular sieve raw powder with a silicon-aluminum mol ratio SiO2Al2O3 of 20 to 1000 and a weight percentage of 20 to 100 percent as well as at least one caking agent selected from SiO2, clay and Al2O3 to extrude, tablet or spray into shape; then treating for 1 to 8 hours by 0.1 to 3 mol/l of at least one ammonium liquor from ammonium nitrate, ammonium chloride or ammonium sulphate or 0.1 to 8.5 mol/l of at least one acid liquor from muriatic acid, nitric acid, vitriol or acetic acid under a temperature of 20 to 90 DEG C; then using steam to treat for 2 to 15 hours under the temperature condition of 400 to 700 DEG C; using a liquor of 0.1 to 3mol/l selected from at least one of oxalic acid, citric acid or maleic acid under a temperature condition of 20 to 90 DEG C to dip for 2 to 5 hours to obtain the modified molecular sieve catalyst, thus better solving the problems.

本发明通过采用硅铝比SiO2/Al2O3为20～1000重量百分比计20～100％的ZSM-5介孔分子筛原粉与余量的选自SiO2、粘土或Al2O3中至少一种粘结剂挤条、压片或喷球成型；再经过0.1～3摩尔/升选自硝酸铵、氯化铵或硫酸铵中的至少一种铵溶液或0.1～8.5摩尔/升选自盐酸、硝酸、硫酸或乙酸中的至少一种酸溶液在温度20～90℃下处理1～8小时；然后在温度为400～700℃条件下水蒸汽处理2～15小时；再用0.1～3摩尔/升选自草酸、柠檬酸或马来酸中至少一种在温度为20～90℃条件下浸渍2～5小时得所需改性分子筛催化剂的技术方案较好地解决了该问题，可用于甲醇转化制丙烯的工业生产中。

By the end of 2005, its production capacity reached 330,000 T/Y urea, 300,000T/Y Synthetic Ammonia, 100,000T/Y sulfur compound fertilizer, 200,000T/Y hi-concentrated compound fertilizer, 80,000 T/Y vitriol, 30,000 T/Y muriatic acid, 50,000 T/Y carbinol and so on.

到2005年底，年生产规模已达到：合成氨30万吨，尿素33万吨，硫基复合肥10万吨，高浓度复合肥20万吨，硫酸8万吨，盐酸3万吨，甲醇5万吨、碳酸氢铵20万吨。

ConclusionThe methanol extract of the leaf of L. rethenicum Murr shows good scavenging effect on DPPH.,.OH and .O.

结论黑果枸杞叶片甲醇提取物对DPPH·，·OH和O·- 2自由基均具有较好的清除作用。

OH and superoxide free radical(O.- 2).MethodsThe methods of DPPH.,Salicylic Acid and pyrograllol auto-oxidation were used to assay the scavenging the extract from the leaf of L. rethenicum Murr. on the three free radicals.

方法采用DPPH法、水杨酸法、邻苯三酚自氧化法分别测定黑果枸杞叶片甲醇提取物清除DPPH自由基、羟自由基和超氧自由基的能力。

Goal compound synthesis namely: Take the vanillic acid as outset raw material, obtains 4- hydroxyl - 3- anisole methyl formate with the methyl alcohol reflux conditions, then after the etherification, the nitration, the return to original state, the ring closure response obtains 6- methoxy - 7- animal pen oxygen radical kui zuo lin - 4- alkone, then passes through the chlorination, the substitution aniline, to escape responses again and so on animal pen oxygen radical, etherification to obtain the goal compound; The goal compound and the diethylamine had the amine substitution reaction to obtain TM1, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(N, N- two ethyl aminos) third oxygen radical] kui zuo lin; Through zuo has the etherification with the Austria niter to respond obtains TM2, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(2- methyl - 5- nitryl imidazole) third oxygen radical] kui zuo lin.

目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。