甲醇

To be studied the preparation technology of benzylalcohol from benzyl benzoate in high yield, The relation of the amount of NaoH, the amount of water, the time, the temprature on the yield of benzylalcohol are discussed, The method of improving benzylalcohol yield were determinded, The highest yield of the benzylalcohol is 90%.

利用甲苯氧化生产苯甲酸装置苯甲醛塔底物料制备苯甲醇的方法，讨论了碱量、水量、反应时间、反应温度与苯甲醇收率的关系，探讨了提高苯甲醇收率的方法，苯甲醇收率基本达到90%以上。

The domestic demand of acetic acid up to 1,440,000-1,620,000 tons can be anticipated in 2010, if 60% is produced by methanol, 520,000 tons of methanol will be consumed;③Methanol can be used as feedstock to directly produce various pesticides ,such as fenitrothion, omethoate, dipterex etc., we anticipate that approximately 340,000 tons of methanol will be used to produce pesticides in 2010.④ Various medicines use methanol as feedstock, such as sulfanilamide, vitamin B6 etc., we anticipate that approximately 180,000 tons of methanol will be used to produce medicines in 2010.⑤ In the duration of dye production, methanol can be used as feedstock or solvent, such as s carlet base RC, disperse red GLZ, phthalocyanin ⑥ Synthetic resin also need methanol as feedstock such as organic glass, we anticipate that about 70,000 tons of methanol will be used to produce synthetic resin and plastics in 2010;⑦Synthetic fibers and synthetic rubber industry, will use methanol about 800,000 tons in 2010;⑧ At present, the production of MTBE is increase rapidly, there are 27 set of plants, total production capacity is 620,000 tons every year, and the demand is about 800,000 tons, there is gap between demand and supply.

预计2010年我国醋酸的需求量将达144～162万吨，按甲醇羰基法占60%计，将需求甲醇达52万吨；③多种农药的生产直接以甲醇为原料，如杀螟松、乐果、敌百虫等，预计到2010年甲醇用于生产农药约为34万吨；④多种医药药品以甲醇为原料，如长效磺胺、维生素B6等，预计到2010年甲醇用于医药约为18万吨；⑤染料生产过程中用甲醇作原料或溶剂，如红色基RC、分散红GLZ、阴率子GRL、酞菁素等等，预计2010年甲醇用量约为10万吨；⑥有机玻璃等合成树脂也需用甲醇为原料，预计到2010年甲醇用于生产合成树脂与塑料用量约为7万吨；⑦合成化纤与合成橡胶工业，2010年甲醇用量约为13万吨；⑧我国MTBE生产正处于快速增长期，现有MTBE装置27套，总生产能力62万吨/年，而年需求量约80万吨，有一定缺口。

For Texaco water gas,the methanol synthesis is based on formyl route under high concentration of CO(15%-16% in volume).

认为合成甲醇在相同的工艺操作条件下，由于反应气体成分的不同，造成了反应途径的区别，即焦炉气制甲醇在高CO2的条件下(体积分数6%～9%)，甲醇合成反应主要是以甲酰基途径合成；徳士古水煤气制甲醇在高CO条件下(体积分数15%～16%)，甲醇合成反应主要是以甲酸基途径合成。

Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料，甲醇为溶剂，先制成甲醇钠的饱和甲醇溶液，再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠，最后在强酸作用下与甲醇进行缩醛化反应合成了4，4-二甲氧基-2-丁酮，过程总收率达到73.1%，纯度98.7%。

Its commercial technologic processes and products,such as Acetic Acid Production by Carbonylation of Methanol,Formyl Morpholine,Steam Reforming Catalyst,Low Pressure Methanol Synthesis,Dimethyl Formamide Production by Dehydrogenation of Methanol,Dimethyl Ether Synthesis by Methanol Dehydration,Hydrogen Production by Methanol Cracking,Methanol Synthesis Catalyst,PSA Gas Separation Devices, and etc.,have been applied in more than 800 plants over fields including chemical industry,petrochemical,food, metallurgy,machinery,military industry.Many technological products were exported to American,European,Asian countries as well as Hong Kong,Macao and Taiwan.Remarkable economic and social benefits are achieved.

甲醇羰基化合成醋酸，甲酰吗啉，转化催化剂，低压合成甲醇，甲醇脱氢制二甲基甲酰胺，甲醇脱水制二甲醚，甲醇裂解制氢，合成甲醇催化剂，变压吸附制氢等成套工业装置和产品应用于全国800多家化工，石化，食品，冶金，机械，军工等企业，并出口美国，欧州，亚州等国及港，澳，台地区。

It is shown that the methanol dimer and methanol cluster are the predominant species of methanol in gaseousness. So we believe that rather the methanol dimer is the original reactant of the methanol dehydration reaction to dimethyl ether than the mono-methanol.

研究表明，在气相中，甲醇分子主要以二聚体和多聚体的形式存在，据此提出甲醇脱水反应的原始反应物是甲醇二聚体，而不是单个甲醇分子。

Kinetics of methanol dehydration to dimethyl ether on modified kaolin catalyst was studied in an integral reactor under normal pressure. It is deduced that the surface reaction of methanol molecule adsorbed on the active site of catalyst with methanol molecule in gas phase is the rate determining step. The hyperbolic type kinetic equation r=ksbMpM2/(1+bMpM+bpE) is obtained according to the theory of langmuir even adsorption and using the R-E mechanism.

采用积分反应器，考察了常压下在改性高岭土催化剂上甲醇脱水生成二甲醚的反应动力学，根据Langmuir均匀吸附理论，采用R-E机理，推断吸附的甲醇分子与气相主体中的甲醇分子发生的表面反应为速率控制步骤，得到双曲线型动力学方程为： r= ksbMpM2 /(1+bMpM+bpE)（r为反应速率， ks为反应速率常数， bM为甲醇的吸附平衡常数， b为二甲醚和水的吸附平衡常数之和， pM、 pE分别为甲醇、二甲醚的分压）。

Several kinds of important downstream products of methanol are introduced,such as formaldehyde,methylformate,methylamine,and so on.

介绍了甲醇的几种重要的下游产品，如甲醛、甲酸甲酯、甲胺等，提出应大力生产和发展甲醇下游产品，并进一步拓宽甲醇的应用领域，加快甲醇应用新技术的开发工作。

The method on trans fatty acids analysis in food is very important. The effects of methylate sodium, potassium hydroxide, sulfuric acid and boron trifluoride in methanol and their different concentration and dosage on TFA analysis were studied. The chromatographic condition and the influence of time and temperature on the esterifation of TFA using boron trifluoride in methanol were optimized. A method for analyzing TFA were established by GC based on boron trifluoride in methanol and RT-2560(100m×0.25mm×0.2μm) capillary column.

研究了甲醇钠－甲醇、氢氧化钾－甲醇、浓硫酸－甲醇和三氟化硼－甲醇4种甲酯化试剂的浓度、用量及甲酯化时间和温度对反式脂肪酸检测的影响，优化了色谱条件，建立了以三氟化硼－甲醇法甲酯化，RT-2560(100m×0.25mm×0.2μm)毛细管柱为基础的反式脂肪酸气相色谱检测方法，C18：1-9 t， C18：1-11 t， C18：2-9 t， 12 t和C22：1-13 t 4种反式脂肪酸的最小检出浓度在0.774.08 mg/kg之间。4种反式脂肪酸不同添标浓度回收率为98.44%101.23%，重复测定的相对标准差在0.22%1.31%之间，有较好的准确度和重现性。

Given the current complexity of industrial recovery of 3'-methyl-2'-butenyl 3, 3-dimethyl-pentenoate and the decomposition problems with 2-methyl-1-butene, research was conducted on a process for direct recycling of MBDP involving an ester exchange reaction of MBDP with either methanol, trimethyl orthoacetate, or solutions of methanol and trimethyl orthoacetate.

针对目前工业上回收3，3-二甲基－4-戊烯酸－3'-甲基－2'-丁烯酯工艺复杂、异戊烯大量分解问题，研究了MBDP直接返回循环使用工艺，MBDP与甲醇、原乙酸三甲酯或与甲醇原乙酸三甲酯混合溶液进行酯交换反应的回收新工艺，比较了四异丙基钛酸酯、甲醇钠、氢氧化钾用作酯交换催化剂的效果，筛选出回收MBDP&一锅煮&最佳工艺：按照n：n：n：n＝1.0：9.8：9.2：0.05物质的量比投料，74℃~78℃反应21h，MBDP转化为贲亭酸甲酯和异戊烯醇，单程转化率87.7%，用85%的磷酸中和甲醇钠，蒸出甲醇，直接用于合成贲亭酸甲酯。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。