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甲酰化

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A mechanism involved in the second [5 + 1] annulation step, includinga formal [5 + 1] annulation and accompanied chlorovinylation, chloroformylation,amination and aromatization reactions, is proposed.

并对第二步反应机理进行了推测,其中包括了一个一般的[5 + 1]加成反应及伴随此加成反应而发生的氯化乙烯化,氯化甲酰化,氨化和芳构化反应。

METHODS: Chemotactic chamber assay was used to investigate the regulatory role of formyl peptide receptor like-1 (FPRL1) in the chemotaxis of PMNs in response to LPS and PD.

用趋化小室方法测定虎杖甙对LPS刺激下多形核白细胞趋化活性及转染了甲酰化肽样受体(FPRL1)基因的293细胞(FPRL1/293)趋化活性的影响。

Microcalorimetric measurements of NH~3 adsorption on catalysts reveal that the remarkable strong acidity and catalytic activity of the Al- promoted catalysts are caused by a change of distribution of acid site strengths and an enhancement in the number of strong and intermediate-strong acid sites effective for the n-butane isomerization and benzoylation of toluene.

NH~3吸附微量热结果表明,Al促进样品的强酸性和催化活性的显著提高是由于样品表面的酸位强度分布发生了变化,有利于正丁烷异构化反应和苯甲酰化反应的中强酸位和强酸位的酸量显著增加。

With α-D-glucose as raw material, 3-O-benzoyl-1,2,5,6-O-diisopropylidene-α-D-allofuranose was synthesized by isopropylene protection , oxidation, reduction and benzoylation.

以α-D-葡萄糖为原料,经异丙叉基保护、氧化、还原、苯甲酰化反应合成3-苯甲酰基-1,2,5,6-氧-二异丙叉基-α-D-呋喃阿洛糖。

A three-dimensional large pore zeolite Hβ is used in the benzoylation of anisole instead of the classical Lewis acid catalysts to synthesize the important fine chemical intermediate 4-methoxybenzophenone.

采用高硅铝比、热稳定性好的三维大孔Hβ沸石替代传统Lewis酸催化剂催化苯甲醚的苯甲酰化反应,合成了重要精细化工中间体4-甲氧基二苯甲酮,收率可达92%。

In the fifth chapter, a series of betulin derivatives including 28-acetoxybetulin, 28-tritylbetulin, 28-benzoylbetulin, 3-O-β-D-glucopyranoside of betulin and some betulinic acid conjugate containing amino acid were synthesized and confirmed by MS and NMR.

第五章分别合成得到了乙酰化白桦酯醇、28-苯甲酰化白桦酯醇、28-三苯甲基化白桦酯醇、3-O-β-D-glucopyranoside of betulin和一系列的白桦酯酸苷氨酸的衍生物,并分别对其进行了结构鉴定。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3,5-二羟基苯甲酸出发,通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物,其中11中是未见文献报道的新化合物。

The influence of the Vilsmeier formylation reaction, the immediate Grignard reaction, the mediate Grignard reaction and the solvents on the synthesis of 2,8-diformyldibenzhothiophene was also investigated.

探索了Vilsmeier甲酰化、直接格氏试剂法、间接格氏试剂法以及溶剂对合成2,8-二甲酰基二苯并噻吩的影响。

Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先,分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料,经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物,将它们与乙二胺缩合生成希夫碱配体,得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

Hexene ; hydroformylation ; rhodium ; supported catalyst ; organic phosphine ; organic-inorganic hybrid

己烯;氢甲酰化;铑;负载型催化剂;有机膦;有机-无机杂化

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。