甲苯氧基

Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂，甲苯为溶剂，甲基铝氧烷为助催化剂催化降冰片烯的聚合。

Hydroxyl octanoic acid(1) was synthesized from heptaldehyde by a four-step reaction of nucleophilic substitution,displacement reaction,acid hydrolysis and deaminization.

以正庚醛为原料，经过亲核取代、置换反应、酸水解及碱化脱氨等4步反应合成了制备3，6-二己基-1，4-二氧杂-2，5-二酮的中间体——α-羟基辛酸(1)；1经对甲苯磺酸催化脱水得辛交酯。

Two kinds of di aniline derivative s connected with oxamethylene bridge or azamethylene bridge were synthesizied by condensation of o nitrophenol and ethylene dibromide (1,4 dibromobutane)or 4 chloro 3,5 dinitrobenzotyifluoride and ethylene diamine(1,6 hexandiamine)and consequent reduction.

由邻硝基苯酚和二溴乙烷以及由4－氯－3， 5－二硝基三氟甲苯和乙二胺为原料通过桥接、还原合成两类由氧亚甲基或氮亚甲基桥联的双苯胺衍生物。

The research indicated that under the compound use of hydroquinone and methyl quinone or independent use of phenothiazines or nitrogen oxygen free radical made the polymerization retarder, opposite-methyl-phenylsulfon made the esterification catalyst, toluol made the backflow including water condition, the acid mellowly compared to when it was 1.15, the production rate of the synthesis methylacrylic acid polyethylene glycol single methyl ether (400) ester may achieve 98.9%, was extremely similar to the overseas product functional group structure.

研究表明，在氢醌、甲醌复合使用或者单独使用吩噻嗪、氮氧自由基哌啶酮作阻聚剂，对甲苯磺酸作酯化催化剂、甲苯作回流带水的条件下、酸醇比为1.5时，合成的甲基丙烯酸聚乙二醇单甲醚(400)酯产率可以达到98.9%，与国外产品官能团结构十分相似。

Our use Co2 as a catalyst in this work, exploring new way to produce nitrobenzoic acid from nitrotoluene under the prue oxygen in basic medium.

本文探讨了以乙酰丙酮钴为催化剂，分子氧为氧源，在NaOH-CH_3OH的反应环境下，氧化硝基甲苯制备硝基苯甲酸的新方法。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

Based on reviewing of functionalization of saturated carbon by catalytic oxidation with metalloporphyrins and metal phthalocyanines as a mimic of the enzyme cytochrome P-450, two reaction systems of which one was the preparation of 4, 4'-dinitrostilbene-2, 2'-disulfonic acid from 4-nitrotoluene2-sulfonic acid and the other was the preparation of 4, 4'-bis (dimethylamino -diphenyl) phenylmethanol from 4, 4'-bis (dimethylamino-diphenyl) phenyl methane , were specifically studied as carfunctionalization and oxyfunctionalization of saturated carbon.

本文在全面综述金属卟啉和金属酞菁类模拟细胞色素P-450酶催化剂催化氧化饱和碳原子功能化的基础上，选择由4-硝基甲苯-2-磺酸制取4，4'-二硝基二苯乙烯-2，2'-二磺酸和由4，4'-二苯基甲烷制取4，4'-二苯基甲醇两个反应体系进行饱和碳原子碳功能化和氧功能化的具体研究。

Apple polyphenol extracts had stronger deoxidizing capacity, antioxidant activity and scavenging effects on superoxide an...

苹果多酚提取物具有较强的还原能力和抗氧化活性，对脂质过氧化产生的超氧阴离子自由基具有较强的抑制作用，且在试验浓度范围内其最大抑制率优于同浓度二丁基羟基甲苯的效果。

According to the results of the examination, the stronger the electron-withdrawing protective group of imines, the better the cis-selectivity of the reaction, 68% yield, trans:cis is 99:1 diastereoselectivity could be leaded by Ts-imines (4-methyl-N-methylene-benzenesulfonaides) with a substituent [2,4-(CH3O)2C6H3], Substrate scope investigation revealed that a wide variety of ketenes and imines could react smoothly to afford corresponding,β-lactams.

实验结果表明，亚胺的保护基团吸电子能力越强，越有利于顺式产物的生成。对甲苯磺酰基保护的取代基为2，4-二甲氧苯基的亚胺参与的该反应可得到68%的产率，反式：顺式=99：1的非对映选择性。底物拓展过程中发现Staudinger反应适用于多种不同的亚胺与烯酮。

Ethane＞ toluene＞1, 3, 5-trimethylbenzene＞methyl isobutyl ketone＞1, 4-Dioxane＞isoprene＞ 1, 2, 4-trimethylbenzene＞cyclohexane＞1, 3-Butadiene＞methyl butyl ketone were the most reactive VOC species in PRD.

化学活性排名前十位的化合物为：乙烯＞甲苯＞1，3，5-三甲苯＞甲基异丁基酮＞1，4-环氧乙烷＞异戊二烯＞1，2，4-三甲苯＞环己烷＞1，3-丁二烯＞甲基丁基酮。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。