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甲苯

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Catalytic activities and regioselectivities of sodium dihydrogen phosphate for nitrations of toluene were investigated by gas chromatography.

研究了磷酸二氢钠催化甲苯硝化反应的催化活性,通过气相色谱考察了催化剂用量、反应时间、硝化反应温度及催化剂的重复使用等因素对甲苯转化率和产物区域选择性的影响。

In this paper, the effects of different catalyst combinations on the synthesis of α-chloro-dodecanoic acid were investigated, in which a series of acyl chlorides such as 4-toluene sulfonyl chloride, dodecanoyl chloride, chlorosulphonic acid , etc.

本文从烯酮式反应机理出发,以α-氯代十二酸的合成为模型,对酰氯化试剂(对甲苯磺酰氯、十二酰氯、氯磺酸等)和质子酸催化剂(如H型离子交换树脂、氯磺酸、对甲苯磺酸、醋酸等)进行组合和选择,并与文献报道的特殊添加剂乙酐比较,研究不同催化体系在酸催化合成α-氯代脂肪酸时的催化作用。

In this paper, the thermochemistry and thermodynamics parameters of semi-batch reaction were measured by adding toluene into the reactor filled with mixed acid, which can be used for safer operation design.

混酸条件下的甲苯硝化是一个典型的液-液两相反应,本文主要通过自动化实验室反应量热器测试了向混酸中滴加甲苯这一半间歇硝化过程中的热化学和动力学数据,从而进行反应过程的安全性研究。

Methods Seven probe drugs were incubated with or without methyl protodioscin respectively in human microsomes. The specific substrates used in this study were caffeine (CYP1A2), dextromethorphan (CYP2D6), tolbutamide (CYP2C9),-mephenytoin (CYP2C19), chlorzoxazone (CYP2E1), coumarin (CYP2A6) and midazolam (CYP3A4). The concentrations of the substrate metabolites (paraxanthine, dextrorphan, 4-hydroxytolbutamide, 4-hydroxymephenytoin, 6-hydroxychlor-zoxazone, 7-hydroxycoumarin and 1-hydroxymidazolam) were determined by HPLC and LC-MS/MS. Results MPD 1-10 μmolL^(-1 had no significant inhibition on the activities of the seven cytochrome P450 enzymes.

将MPD和CYP450酶7种亚型的特异性探针底物咖啡因(CYP1A2)、右美沙芬(CYP2D6)、甲苯磺丁脲(CYP2C9)、s-美芬妥因(CYP2C19)、氯唑沙宗(CYP2E1)、香豆素(CYP2A6)及咪达唑仑(CYP3A4)与人肝微粒体进行孵化反应,采用HPLC和LC-MS/MS法测定对应的7种代谢产物(1,7-二甲基黄嘌呤、去甲右美沙芬、4-羟基甲苯磺丁脲、4-羟基美芬妥因、6-羟基氯唑沙宗、7-羟基香豆素和1-羟基咪达唑仑)的浓度,通过与对照组比较,确定MPD对以上7种酶活性的影响。

The experimental results indicated that the toluene insoluble material increased with the reaction time and reaction temperature.

结果表明,在较低的反应苛刻度下,甲苯不溶物的产率变化趋势比较平缓,而较高的反应苛刻度下,甲苯不溶物产率则迅速增加。

The effects of catalysts, toluene concentration, gas flow rate and adsorbability were investigated.

研究了有无催化剂、甲苯初始浓度、气体停留时间和吸附性能对甲苯降解的影响。

The joint toxicity was evaluated by different methods, including toxicity unit,additive index, similarity parameter and mixtures toxicity index. The results show that the binary joint effects of phenol and toluol mixed with SDS are synergistic, while the binary joint effect of SDS and nitrobenzene is antagonistic. The environment risk of some compounds will be enhanced because of the joint of SDS.

研究结果表明: 4种不同的评价方法对SDS与取代芳烃苯酚、甲苯和硝基苯的联合效应评价结果具有较好的一致性,即SDS与苯酚、甲苯的二元混合体系的毒性表现为不同程度的协同作用,而与硝基苯则表现为弱拮抗作用;对环境存在风险性的阴离子表面活性剂SDS,当与一些有毒有害物质共存时会增加该类物质的环境风险性。

Treatment of N-p-tolylsulfonylindole 1 with acetyl chloride in dried dichloromethane gave the title compound, N-p-tolylsulfonyl-3-acetyl-indole 2 C17H15NO3S, M(subscript r=313.36 in 89% yield. Single-crystal structure of 2 was determined by X-ray crystallography.2 crystallizes in the triclinic system, space group P-1 with a=10.0264(13), b=12.5913(16), c=14.1621(18)?

N-对-甲苯磺酰-吲哚(1)在二氯甲烷中与乙酰基氯反应得到产率为89%的N-对-甲苯磺酰-3-乙酰基-吲哚(2)(分子式:C17H15NO3S,分子量:313.36),用单晶X-射线衍射方法测定了2的晶体结构并表明:属三斜晶系,空间群为P-1,单胞参数为a=10.0264(13),b=12.5913(16),c=14.1621(18)?

G. the perfumes. The wall forming materials were TDI (2, 4-toluene diisocyanate) or 80/20TDI, triphenyl methane triisocyanate and biphenyl methane-4, 4-diisocyanate , Poly vinyl alcohol was used as protective colloid and GPE2040 was used as the emulsifier.

壁材单体分别使用了2,4-甲苯二异氰酸酯、80/20-甲苯二异氰酸酯、三苯基甲烷-4,4′,4-三异氰酸酯和二苯甲烷-4,4′-二异氰酸酯;保护胶体是聚乙烯醇;乳化剂是聚醚2040;催化剂使用二月桂酸二丁基锡。

The rubber compounds and vulcanizates were swelled in toluene and in toluene over ammonia; bound rubber as well as swelling degree of the vulcanizate were determined.

使混炼胶和硫化胶分别在甲苯甲苯-氨中溶胀,测定了结合胶及溶胀度的变化。

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