甲苯

Herein, three kinds of reaction type of gelators, methylbenzene–2, 4–bis (N, N'–alkyl) urea derivatives were synthesized by using high reactivity of isocyanate and alkylamine.

利用甲苯二异氰酸酯与烷基胺的高反应活性，制备了三种不同烷基链长的反应型凝胶剂甲苯–2， 4–二脲。

65 The methyl group on the benzene ring greatly facilitates the nitration of toluene.

苯环上的甲基使甲苯非常易于硝化苯环上的甲基使甲苯非常易于硝化。

In order to solve the problem of producing large amounts of wastes and undesired o-nitrotoluene in synthesis of p-nitrotoluene with the mixed concentrated mineral acids,the catalytic activity of phosphotungstic acid for selective nitration of toluene was studied and the optimum conditions for preparing the catalyst were investigated.

为解决硝硫混酸对硝化甲苯过程中因甲苯的非选择性硝化产生的o-MNT和大量废酸对环境的危害，研究了磷钨酸对甲苯硝化反应的催化活性。

The results show high selectivity when the temperature is controlled at 50 CC , and the nitrated reaction time is 90 mm, toluene is nitrated by using 95% nitric acid as nitrating reagent at the presence of acetic anhydride, 1.0g silicotungstic acid catalyst is calcinated at 300℃ for 1.5h. The o/p (ratio of ortho to paro isomer of toluene nitration) ratio is 0.89 in product distribution of toluene nitration, lower than 1.67 using sulfonitric acid as catalyst. The yield of products is 91.6%.

结果表明，在醋酐存在条件下，以CCl4为溶剂，以质量分数为95%的硝酸为硝化剂，反应温度控制在50℃，反应60 min， 1.0g经300℃焙烧1.5h后的硅钨酸催化剂，对甲苯表现出强的区城选择性，甲苯硝化产物o/p值（甲苯硝化产物邻位和对位异构体的质量比）达0.89，较硝硫混酸的1.67显著降低，产物收率达到91.6%。

A new production technology of high-quality trimellitic anhydride with the liquid-phase air-oxidation from 1,2,4-trimethylbenzene was developed.

偏苯三酸酐的生产方法主要有偏三甲苯气相空气氧化法、偏三甲苯液相硝酸氧化法、偏三甲苯液相空气氧化法和间二甲苯甲醛液相空气氧化法。

Results The mixing, loading and storing processes of the construction, might generate lots of occupational hazards, including toluene, dimethylbenzene, trimethylbenzene, isopropanol, butyl alcohol, propanol, methyl methacrylate, butyl acetate, methyl isobutyl ketone, methyl ethyl ketone, acetic ether, nitro-cotton, n-hexane, n-heptane, carbinol, ethanol, ethyl propionate, diisobutyl ketone, glycol ether, isoamyl acetate, 2,4-toluene diisocyanate, isophorone, noise, power frequency electric fields.

结果 该项目在混兑生产和装卸、仓储过程中，可能产生的职业病危害因素主要有甲苯、二甲苯、三甲苯、异丙醇、丁醇、丙醇、甲基丙烯酸甲酯、乙酸丁酯、甲基异丁基甲酮、丁酮、乙酸乙酯、硝化棉、正己烷、正庚烷、甲醇、乙醇、乙酸丙酯、二异丁基甲酮、乙二醇乙醚、乙酸异戊酯、2，4甲苯二异氰酸酯、异佛尔酮、噪声、工频电场。

The results show that photocatalyst TiO2 improves the removal rate of toluene in not only the nitrogen plasma field (NTP-P-O2/N2) eradiating ultraviolet light but also the argon plasma field eradiating visible light. This supports the idea that both the UV light and the high-energy electron in the plasma field can activate TiO2. Furthermore, the toluene removal rate in NTP-P-Ar system is 5% higher than that in NTP-P-O2/N2 system, confirming that high-energy electron has greater effect on the degradation performance of toluene, as compared with UV light.

结果表明：在发射紫外光的氮等离子体场(NTP-P-O2/N2)中和发射可见光的氩等离子体场中，TiO2：均能提高体系的甲苯去除率，说明等离子体场中产生的紫外光和高能电子均能激活光催化剂TiO2；NTP-P-Ar体系中的甲苯去除率较NTP-P-O2/N2：体系中的约提高5%，说明等离子体场中高能粒子对甲苯降解性能的影响要强于紫外光的影响。

The process includes the following steps: dissolving bromine in halogenated hydrocarbon, dropping the bromine solution into reactant system comprising pentabromo toluene, halogenated hydrocarbon, free radical initiator and hydrogen peroxide at 50-65 deg.c, and heating to 60-78 deg.c for reflux reaction until the reactant system becomes transparent; filtering the resultant to obtain solid product, washing with carbon tetrachloride and water separately and vacuum drying to obtain pentabromo benzyl bromide.

具体步骤为：将五溴甲苯、卤代烃、自由基引发剂和过氧化氢组成的反应体系加入到三颈瓶中，将0.07～0.1mol的溴溶于50ml卤代烃配成溶液，在50-65℃温度下滴加到反应体系中，滴加时间为50-70分钟，然后升温至60-78℃温度下回流反应，至反应体系逐渐变透明，且不再产生气泡时，将所得产物过滤，得到固体产物，分别用CCl 4 和水洗涤，真空干燥，即得到五溴苄基溴；其中，五溴甲苯与溴的摩尔比为1∶0.7-1∶1.0，溴与过氧化氢的摩尔比为1∶1.0-1∶1.4，自由基引发剂加入量为五溴甲苯重量的1-10％，卤代烃的加入量为反应体系体积的40％-100％，所用溶剂可以直接进行下一批反应，不需要更换溶剂或蒸馏提纯。

Also produce 1000 tons inorgnic fluorides series products per year, They are of good quality and mainly sold abroad.

现有年产3000吨三氟甲苯、8000吨对氯三氟甲苯、5000吨4-氯-3，5-二硝基三氟甲苯和年产1000吨无机氟化盐规模的生产能力，产品生产稳定，质量上乘，并远销国内外。

Ethane＞ toluene＞1, 3, 5-trimethylbenzene＞methyl isobutyl ketone＞1, 4-Dioxane＞isoprene＞ 1, 2, 4-trimethylbenzene＞cyclohexane＞1, 3-Butadiene＞methyl butyl ketone were the most reactive VOC species in PRD.

化学活性排名前十位的化合物为：乙烯＞甲苯＞1，3，5-三甲苯＞甲基异丁基酮＞1，4-环氧乙烷＞异戊二烯＞1，2，4-三甲苯＞环己烷＞1，3-丁二烯＞甲基丁基酮。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。