甲基萘

Synthesis of 1-［(4, 6-Dimethyl-2-pyrimidinyl)azo］-2-naphthol and Its Color Reaction with Cobalt

1-［4，6-二甲基-2-嘧啶）偶氮］-2-萘酚的合成及其与钴

The asymmetric polymerization of methyl methacrylate is carried out using the chiral binaphthyl crown ether macrocyclic compounds binding n-BuLi or t-BuOK as chiral initiator at -78℃.

以手性联萘冠醚为配体，络合n-BuLi，t-BuOK等有机金属化合物形成手性引发剂体系，初步探讨了甲基丙烯酸甲酯单体的聚合反应。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光，这是由于手性重复单元-6，6′-二(4-三氟甲基苯基)-2，2′-二正辛氧基-1，1′-联萘和单元2，2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

The free radical scavenging properties of six Aloe species are to be investigated in some modified chemical system. The antioxidant was purified by silica column and thin layer chromatography and analyzed by HPLC. A fraction was purified from A. brevifolia Mill showed the most effective scavenging activities on 〓 and ·OH (66. 01% and 38. 98% respectively). With the analysis of IR spectrum, UV spectrum and mass spectrum, the structure of FA was identifed as 8-C-D-glucopyranosyl-2- [2-hydroxy] propyl-5-methyl-7-hydroxychromone. Its scavenging activity on free radicals is higher than that of aloe-emodin. Its antioxidant activity may be due to the phenoxyl on glucosyl chromone which can be react with free radicals and form relatively stable free radicals.

本研究利用分别产生超氧阴离子自由基和羟自由基的化学模型体系研究比较了不同品种芦荟提取物的清除活性氧自由基的抗氧化作用，进一步利用硅胶柱结合薄层层析法和反相高压液相色谱法，从短叶芦荟叶子中首次分离了具有较强自由基清除能力（超氧阴离子自由基和羟自由基清除率分别为66.01％和38.98％）的成分FA，利用红外光谱、紫外光谱和质谱等仪器分析结果推断出该活性成分的分子结构为8-C-吡喃葡萄糖-2-[2-羟基]-丙基-5-甲基-7-羟基对氧萘酮，它的自由基清除能力高于芦荟大黄素，是一种天然抗氧化剂。

The photocycloaddition of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane 3 primarily,but that of 2-NpCN gave azetine 6 asthe major and cyclobutane 5 as the minor product in low conversion photolysis.

在低转化光解情况下，1-萘甲腈(1-NpCN)和2，3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3，但2-NpCN主要得到氮杂环丁烯6和少量的环丁烷5，三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应，表明TFA与基态及单激发态1-NpCN生成非光反应的复合物，它也淬灭(1-NpCN-DMB)激基复合物。

The photocycloaddn. of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane I primarily, but that of 2-NpCN gave azetine II as the major and cyclobutane III as the minor product in low conversion photolysis. The photocycloaddn. of 1-NpCN with DMB is retarded by increasing amts. of trifluoroacetic acid which is shown to form non-photoreactive complexes with ground state as well as with singlet excited state 1-NpCN. It also quenches the *(1-NpCN-DMB) exciplex.

在低转光解情况下，1-萘甲腈(1-NpCN)和2，3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3，但2-NpCN主要得到氨杂环丁烯6和少量的环丁烷5，三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应，表明TFA与基态及单激发态1-NpCN生成非光反应的复合物，它也淬灭^*(1-NpCN-DMB)激基复合物。

By bioactivity-guided isolation, 14 compounds were obtained from the active fractions. 13 of them were determined as 9,9'-dihydroxy-8,8'-dimethoxy- l,r-methyl-lH,lH'-[4,4']binaphtha

本研究利用稻瘟霉筛选体系对红葱的60％乙醇提取物及其氯仿、正丁醇和水的萃取部分进行了活性筛选，并对活性部位的活性化学成分进行了跟踪分离，从中分离得到十四个化合物，利用物理化学和光谱学的方法对其中十三个化合物的结构进行了鉴定，分别为9，9'-二羟基-8，8'-二甲氧基-1，1'-二甲基-1H，1H'-[4，4']双萘并

When 45% methanol solution containing 0.5 mmol/L hexamethylene tetraamine was used as the pump carrier, the pump flow rate and output pressure achieved 0.58 mL/min and 0.79 MPa at 4950 V, respectively. By using the pump carrier as the mobile phase, benzene and naphthanlene were separated on baseline by the EFA system.

在4950 V的外加电压下，以含0.5 mmol/L六亚甲基四胺的45%甲醇溶液为泵载流，电渗泵的流量和输出压强分别为0.58 mL/min和0.79 MPa，以泵载流为流动相，该系统对苯和萘进行了反相色谱分离。

A method combining HPLC, a post-column derivation device and a fluorescent detector was used to determine residues of ten carbamate pesticides （aldicarb sulfoxide, aldicarb sulfone, oxamyl, methomyl, 3-hydroxy carbofuran, aldicarb, propaxur, carbofuran, carbaryl and methiocarb） in 68 vegetable and 32 soil samples under four different cultivation systems （traditional kailyard, open field vegetable base, green house and paddy） were collected from a certain city in South Jiangsu.

本研究采用高效液相色谱-柱后衍生-荧光检测法分析了苏南某市4种不同种植方式下（传统菜地、露天蔬菜基地、大棚蔬菜基地和水稻田）68个蔬菜样品和32个土壤样品中10种N-甲基氨基甲酸酯类农药（涕灭威、涕灭威砜、涕灭威亚砜、杀线威、灭多威、残杀威、克百威、3-羟基克百威、甲萘威和灭虫威）的残留量，结果表明在蔬菜中检出的氨基甲酸酯农药残留水平多处于0.2～23μgkg^-1，土壤中为0.1～10μgkg^-1；土壤中3-羟基克百威和灭虫威全部检出，其最高检测浓度分别为10μgkg^-1和1.64μgkg^-1，其他农药仅有少数检出。

N-(6-methyl-2-pyridine)-amino-methylene-diethyl malonate was produced by condensation reaction of 2-amino-6-methyl pyridine with ethoxymethylene diethyl malonate under optimal conditions that n(2-amino-6-methyl pyridine)∶n(ethoxymethylene diethyl malonate) is 1∶1.3, reacting time 45 min and temperature 130 ℃,the yield of this reaction was 96%,which was 6% higher than that of literature.

在250℃的反应温度下，分别以二苯醚、石蜡油和邻苯二甲酸二乙酯为热载体进行成环反应，得到4-氧-7-甲基-1，8-萘啶-3-羧酸乙酯的收率分别为88.6%、56.3%和61.2%，确定二苯醚为最佳热载体，并发现反应温度对产率的影响最大，原料配比次之，反应时间基本无影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。