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This paper introduces using industry naphthalene to production process to deeply process watering_oil in spare time of production so as to achieve industry acenaphthene and methylnaphalene etc.

利用工业萘生产装置,在工业萘生产的空余时间,对洗油进行深加工,制取工业萘及甲基萘等产品,实现一套装置的多种使用,提高企业经济效

The company with high technical content, product quality, its products -methyl naphthalene,-methyl naphthalene, acenaphthene industry, quality of wash oil, residual oil, etc., the main focus on the supply in Shanxi, Henan, Shandong and other places.

该公司技术含量高,产品质量可靠,其生产的产品α-甲基萘、β-甲基萘、工业苊、中质洗油、残油等,主要集中供应于山西、河南、山东等地。

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂,由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4,4'-二氯甲基联苯和1,5-二氯甲基萘等进行一锅化缩合反应,以38~89%的产率合成了14种芳并呋喃化合物。

Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.

适用于水互溶的有机溶剂包括芳香族碳氢化合物,如甲苯,二甲苯,萘,四氢萘和甲基萘;氯代芳香族碳氢化合物,如氯苯,氟,氯萘和萘;酯类,如醋酸丁酯,醋酸乙酯,苯甲酸甲酯,苯甲酸乙酯,苄酯,苯甲酸正丁酯,苯,醋酸丁酯乳酸,乳酸苄,二甘醇二丙酸酯,邻苯二甲酸二甲酯,邻苯二甲酸二乙酯,邻苯二甲酸二丁酯,二(2乙基己基)酯;醇有6个或更多碳原子,如己醇,辛醇,苯甲醇,苯乙醇,苯氧基乙醇,丙醇和苯氧基苯氧丁醇;醚至少有5个碳原子,最好荤5-14醚,如苯甲醚和phenetol;硝化棉,纤维素醚,醋酸纤维素,低气味石油蒸馏;松节油;白酒,石脑油isopropylbiphenyl;萜类,植物油,矿物油,挥发油;和天然油,以及任何两个或两个以上其混合物。

The separation and purification processes of 2,6-DMN from coal and petroleum tar are reviewed.

文摘:本文介绍了2,6-二甲基萘的用途和制备方法;综述了从煤焦油和石油中分离提纯2,6-二甲基萘工艺。

Preparation of 2,6-dimethylnaphthalene(2,6-DMN) through transalkylation reaction of methylnaphthalene and 1,2,4,5-tetramethylbenzene is one of methods with excellent exploitation value and potentiality.

甲基萘和1,2,4,5-四甲苯转移烷基化合成2,6-二甲基萘(2,6-DMN)是最具研究价值和开发潜力的方法之一。

Synthesis of β-methylnaphthoquinone without any catalyst in the CH_3COOH-H_2O_2 system by oxidation of β-methylnaphthalene is researched. We have discussed the feasibility of the technology.

在不添加任何催化剂的条件下,以冰醋酸为溶剂,用过氧化氢氧化β-甲基萘制取β-甲基萘醌。

Alkylation of methylnaphthalene and methanol over HZSM-5 zeolite can make 2, 6-dimethylnaphthalene (2, 6-DMN) and the product stream contains isomers of 2, 6-DMN and unreacted MN, which requires efficient separation.

甲基萘和甲醇为原料,采用HZSM-5烷基化催化剂制取2,6-二甲基萘(2,6-DMN)。由于产物中含有2,6-DMN的异构体以及未反应的MN,需对反应产物进行有效分离。

Methyl 6-acylnaphthalene from 2-methylnaphthalene was synthesized via acylation using acetic anhydride and propionyl chloride as the acylating agents with catalyst aluminum trichloride in homogeneous liquid phase system.

为制备重要的化合物2-甲基6-酰基萘,提高酰化产物的收率和纯度,以2-甲基萘为原料,分别研究了乙酸酐和丙酰氯为酰化剂时的酰化反应,对酰化反应的产物进行了GC、FT-IR和GC-MS表征;对酰化反应的影响因素进行了研究。

Washing oil distillate from coal tar is rich in such valuable organic chemical materials as quinoline,α-methyl-naphthalene,β-methyl-naphthalene, diphenyl, indole, acenaphthene, fluorene, etc.

煤焦油洗油馏分中富含喹啉、α-甲基萘、β-甲基萘、联苯、吲哚、苊、芴等宝贵的基本有机化工原料,介绍了这些组分的分离提取及其在精细化工中的应用,煤焦油的深加工对资源综合利用及精细化工的发展具有重要意义。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

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