甲基苯胺

Anilido-imino nickel complex 1 {(C6H3Me2-2,6)N=CH-5-NO2-C6H3N (C6H3Me2-2,6)}NiBr was first synthesized, and its catalytic behavior toward polymerizations of norbornene and ethylene in the presense of methylaluminoxane were investigated in detail. The complex activated with methylaluminoxane exhibited high activities for norbornene polymerization.

首次合成了苯胺基亚胺镍配合物1{(C6H3Me2-2，6)N=CH-5-NO2-C6H3N(C6H3Me2-2，6)}NiBr，研究了其在助催化剂甲基铝氧烷的作用下对降冰片烯、乙烯的均聚以及对降冰片烯和乙烯的共聚的催化性能。

Mehtod: animals were given intraperitoneally normal saline(10ml/kg.d), phenobarbital (40mg/kg.d) and puerarin (100, 200mg/kg.d) respectively for seven days. Then the levels of hepatic microsomal CYP and cytochrome b5(Cytb5), and the activities of aniline hydroxylase and aminopyrine N-demethylase were determined by spectrophotography.

实验动物分别腹腔注射生理盐水、苯巴比妥（40mg/kg.d）、葛根素（100和200 mg/kg.d），给药7d后，用分光光度法测定肝微粒体CYP和细胞色素b5(Cytb5)的含量，以及苯胺羟化酶和氨基比林N-脱甲基酶的活性。

Mehtod: The animals were given intraperitoneally normal saline(10ml/kg.d), phenobarbital (40mg/kg.d) and puerarin (100, 200mg/kg.d) respectively for seven days. Then the levels of hepatic microsomal CYP and cytochrome b5(Cytb5), and the activities of aniline hydroxylase and aminopyrine N-demethylase were determined by spectrophotography.

实验动物分别腹腔注射生理盐水、苯巴比妥（40mg/kg.d）、葛根素（100和200 mg/kg.d），给药7d后，用分光光度法测定肝微粒体CYP和细胞色素b5(Cytb5)的含量，以及苯胺羟化酶和氨基比林N-脱甲基酶的活性。

This invention discloses an intermolecular charge transfer chromogen with triphenylamine group, with a formula indicated by (1), wherein: R1 is hydrogen atom or methyl group or methoxyl group, R2 is hydrogen atom or 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group.

本发明公开的含三苯胺基团的分子内电荷转移生色团，具有式1所示的结构式，其中R 1 为氢原子或甲基或甲氧基，R 2 为氢原子或2-(5，5-二甲基-3-乙烯环己烯基-2-烯亚基)丙二腈基。

Two kinds of di aniline derivative s connected with oxamethylene bridge or azamethylene bridge were synthesizied by condensation of o nitrophenol and ethylene dibromide (1,4 dibromobutane)or 4 chloro 3,5 dinitrobenzotyifluoride and ethylene diamine(1,6 hexandiamine)and consequent reduction.

由邻硝基苯酚和二溴乙烷以及由4－氯－3， 5－二硝基三氟甲苯和乙二胺为原料通过桥接、还原合成两类由氧亚甲基或氮亚甲基桥联的双苯胺衍生物。

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

After the diazotization ,2-aminophenol-4-(2-'carboxy)sulfanil phenylamine was coupled with acetoacetanilide,2-naphthol,1-phenyl-3-methyl-5-pyrazolone,1-naphthol-4-sulfonic acid,separately to get the different diazotized compounds,then complexed with potassium chromium sulfate or cobaltous chloride to obtain the yellow,orange,red,purple,blue and other colour dyestuffs.

2-氨基苯酚-4-(2'-羧基)磺酰苯胺重氮化，分别与乙酰乙酰苯胺、2—萘酚、1-苯基-3-甲基-5-吡唑啉酮、尼文酸、1-乙酰氨基-7-萘酚等偶合，得到不同的偶氮化合物，然后分别与硫酸铬或氯化钴进行络合反应，得到黄、橙、红、紫、蓝多种颜色染料，并进行了毛织品的染色实验。

It is manufactured through kneading, cold pressing and post-treatment; and the materials for the synthetic brake shoe include butadiene-acrylonitrile rubber, phenolic resin, graphite, iron powder, barium sulfate, potash feldspar powder, composite fiber, sulfur, hexamethine tertramine, polymethylene aniline, 2-mercaptan benzothiazole, zinc oxide and toluene.

同时本发明的提供了采用捏合、冷压、后处理工艺来制造新型高摩擦系数合成闸瓦。组成新型高摩擦系数合成闸瓦的各组分重量百分比如下：丁腈橡胶为6.20％，酚醛树脂为10.00％，石墨为15.00％，铁粉为11.03％，硫酸钡为30.00％，钾长石粉为5.00％，复合纤维为20.20％，硫磺为1.00％，六次甲基四胺为1.00％，聚亚甲基聚苯胺0.12％，2-硫醇基苯并噻唑0.15％，氧化锌0.30％，甲苯8.0％。

Aniline-BP was used as CTC system to initiate the polymerization ofMMA under UV irradiation, PMMA prepolymer with aromatic imino endgroup was prepared.

以苯胺-BP为CTC体系，在紫外光辐射下，引发甲基丙烯酸甲酯聚合，得到了含有芳亚胺端基的聚甲基丙烯酸甲酯预聚物。

On the contrary, the existence of electron-donating groups on the benzene ring would prolong reaction times and decrease the yields.

使用苯胺为反应底物考察了各因素的影响，在优化的反应条件下，苯胺的转化率可达到99.7％，N-甲基-N-苯基氨基甲酸甲酯的收率为83.2％。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。