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Using cetyl trimethyl ammoniunm bromide as templating agent, the mesoporous TiO_2 with special performance was synthesized by a tartaric acid sol-gel method. The UV irradiation was used in this process.

以十六烷基三甲基溴化胺为模板剂,采用溶胶-凝胶法,在溶胶-凝胶制备过程中引入紫外光照辐射,制备出具有一定特殊性能的中孔TiO2材料。

The preparation process includes the following steps: mixing 10 mM concentration water solution of chloropalladic acid and 12.5-25 mM concentration water solution of ammonium hexadecyl trimethyl bride in the volume ratio of 1 to 20, heating to 65-95 deg.c, adding 100 mM concentration water solution of ascorbic acid in the volume ratio to the water solution of chloropalladic acid of 0.16 to 1 to react for 30 min, centrifugal separation to collect precipitate, water washing, and drying to obtain cuboidal nanometer Pd material.

该钯纳米长方体材料的制备方法的步骤和条件法如下:把体积比为1∶20的10mM氯钯酸水溶液和12.5-25mM十六烷基三甲基溴化铵水溶液混合,加热至65-95℃,然后加入与10mM氯钯酸水溶液的体积比为0.16∶1的100mM抗坏血酸水溶液,反应30分钟,将溶液离心分离,收集到的沉淀用水洗涤,干燥,得到钯纳米长方体。

In the ammonifying procedure, al cohol is used as solvent or phase transfer catalyst is added. The results sh ow that the reaction time decreases evidently and the yield of bactericide in creases further.

在产品制备的胺化步骤,作者采用乙醇作为溶剂或加入相转移催化剂,明显缩短了合成时间,使产品双烷基二甲基溴化铵的产率得到了进一步提高。

The effect of short chain monohydric alcohols (ethanol, n-butanol) and dihydric alcohols (ethyleneglycol, 1,4-butanediol) on the aqueous two-phase system of cationic and anionic surfactants is studied.

研究了短链一元醇和二元醇(乙二醇、1,4-丁二醇)对正负离子表面活性剂混合溶液(十二烷基硫酸钠-十六烷基三甲基溴化铵-水)双水相的影响。

The addition of 0.2 mmol/L of cetyltrimethylammonium bromide could change the direction of electroosmotic flow.

由于在背景电解质中加入了0.2 mmol/L十六烷基三甲基溴化铵,因而电渗流的方向与传统的毛细管区带电泳中电渗流的方向相反。

To the best of our knowledge, the relationship of surface acitivity of catanionic surfactant with temperature has not been revealed, and the catanionic surfactant has not been employed in organic reaction also.In this work, surface tensions of equimolar cetyl trimethylammonium bromide-sodium dodecyl sulfate at different temperatures were determined and compared with those of corresponding individual surfactants.

为扩展复配体系的应用,本论文选取等摩尔十六烷基三甲基溴化铵—十二烷基硫酸钠复配体系及它们的单一体系为研究对象,观察到随着温度的升高,CTAB及SDS表面活性变化不大,而等摩尔CTAB-SDS的表面活性显著增强,这是由于升温减弱了其强烈的静电作用,并通过溶解性实验结果进一步证实。

In this dissertation, the sodium bentonite was modified using hexadecyl trimenthyl ammonium bromide and cationic polyacrylamide.

本文以市售钠基膨润土为原料,分别以十六烷基三甲基溴化铵和阳离子聚丙烯酰胺为改性剂,制各了新型复合插层有机膨润土。

Surfactants of Hexadecyl trimethyl ammonium bromide and alkyl polyoxyethylene have a slow dying at a higher temperature and have accelerated dying at a lower temperature while leather dying with the curcuma dye.

而表面活性剂十六烷基三甲基溴化铵及平平加O对姜黄素在皮革的染色在较低温度下有一定的促染作用,在较高温度下有一定的缓染作用。

The sodium bentonite was modified by organic reagent hexadecyl trimenthyl ammonium bromide and cationic polyacrylamide. The structures of modified organo-bentonite and the effect of concentration of the intercalating reagent and reacting time on decoloring capacity were studied.

用阳离子有机改性剂十六烷基三甲基溴化铵和阳离子聚丙烯酰胺复合插层改性钠基膨润土,分析了改性膨润土的结构,研究了改性剂质量浓度及二次改性时间对复合插层膨润土脱色效果的影响。

The effects of the surfactants, trioctyl phosphine oxide, sodium dodecyl sulfonate and hexadecyl trimethyl ammonium bromide, on the extraction rate of Co^2^+ were investigated. The acceleration in the kinetics in contributed to the associated molecule~2 TOPO taking part in the extraction process directly. The decrement effects of SDS or CTMAB on the rate of extraction kinetics of Co^2^+ with HDEHP were also observed, which caused by the adsorption of molecules of SDS or CTMAB on the interface and decreased the interfacial adsorption amount of HDEHP. In addition, the extraction rate was reduced by a bigger margin in HDEHP-SDS system. This can be explained in terms of the formation of an electric field at the interface.

研究体系中加入不同表面活性剂所引起萃取速率的不同改变:三辛基氧化膦因与HDEHP形成可萃取的Co^2^+活性分子缔合物,降低了萃取过程活化能而使反应加速;十二烷基磺酸钠和十六烷基三甲基溴化铵因占据发生萃取反应的界面区,减小了HDEHP与Co^2^+反应的机会而使反应减速; SDS还因其在界面形成较强的负电场,造成Co^2^+的附加势能而使萃取速率有更大幅度的降低。

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