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The influence of surfactants CTMAB and CPC on the absorption spectra, calibration curve, and acidity of Al-CAS colouring system was studied.

对表面活性剂[十六烷基三甲基溴化铵和氯化十六烷基吡啶]在吸收光谱、工作曲线和显色酸度等方面对铝-铬天青S显色体系的影响进行了研究。

The platinum terpyridyl acetylide complex containing a simple amine group in the acetylide ligand could be utilized as a chemo-sensor for detection of micromolar concentration of protons by monitoring the changes both in luminescence and color.

实验发现: 1.4-N,N-二甲基苯乙炔为辅助配体的三联吡啶Pt络合物TA在质子存在下吸收和发光变化明显,因此可以通过颜色或发光的变化检测微量质子的存在。

The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-(4-甲基苯基)-6-苯基-2,2'-联吡啶Pt络合物AC,不仅在碱金属和碱土金属的存在下吸收光谱明显改变,更有意义的是,它只有在Mg〓离子存在时能够发光,因此可以通过发射光谱选择性的识别Mg〓,尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

Objective:To explore the cardiac toxicity in rats exposed to aluminum chloride(AlCl3),and the inhibition of 1,2-dimethyl-3-hydroxy-4-pyridone.

目的:研究氯化铝(AlCl_3)染毒对大鼠心脏的毒性及铝螯合剂1,2-二甲基-3-羟基-4-吡啶酮的保护作用。

ObjectiveTo explore cardiac toxicity in rats exposed to aluminum chloride (AlCl3), and to evaluate the protection of 1,2dimethyl3hydroxy4pyridone against toxicity.

目的研究氯化铝(AlCl3)染毒对大鼠的心脏毒性及铝螯合剂1,2二甲基3羟基4吡啶酮的保护作用。

In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2,3-d]嘧啶的方法,此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵,二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

ChinaObjective:To study the antitoxic role of vesicular monoamine transporter 2 (VMAT2) in transpgenic Chinese Hamster ovary cell.Methods:With the technology of transgene from PC12 to CHO,MTT reduction assay was used to detect MPP^+ toxic effect on wild type CHO and transgenic CHO.

利用转PC12细胞基因到CHO细胞中形成的转基因CHO细胞(cDNACHO,采用MTT比色法检测1-甲基-4-苯基吡啶离子(MPP^+对CHO细胞野生株(wtCHO和cDNACHO细胞的毒性作用,并观察利血平-VMAT2的特异性阻滞剂对MPP^+毒性作用的影响。

The optimal separating condition of chromatography analysis was: Shimadzu VP-ODS 150mm4.6mm as chromatographic column; acetonitrile/water (12/88,V/V, Contained 1.25mmol/l phosphoric acid) as mobile phase with flow rate of 1.0ml/min. Macroporous ion exchange resins and activated carbon were applied to enrich the trace level impurities and the main impurities was determined by LC-MS and GC-MS.They were : Benzonitrile , 2-Methyl-8-hydroxyquinoline, 2,6-Pyridinediamine , O-ethyloxime Cyclo-hexanone and compound with 220 molecular weight .

采用离子树脂和活性炭吸附富集这些微量的杂质,并通过液质联用和气质联用对杂质进行了定性分析,鉴定了影响290nm吸收的主要杂质为苯甲腈,2甲基-8羟基喹啉,2,6二氨基吡啶,O-乙基环己酮肟和分子量220的物质。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮,1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2,2-联吡啶,邻菲啰啉,三苯基氧膦)合成了16个稀土红外配合物(Ln=Er,Nd,Yb),获得了其中三个配合物的单晶结构,研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

The electrochemical behavior on tetramethylquinone in n-butylpyridini-um chloride-aluminum chloride, a room temperature molten salt , is dependent on theacidity of this melt.

四甲基苯醌在氯化正丁基吡啶-AlCl_3室温熔盐中的电化学行为,和室温熔盐的酸碱度有关,在碱性熔盐中,四甲基苯醌以不络合的形式存在,电极上的还原过程是一个ECE过程;在酸性熔盐中,形成络合物TQ(AlCl_3)_m,络合数m为1,2,3,随熔盐酸度变化,此外,醌类物质芳香环上的取代基,也影响其电化学性质。

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