甲基吡啶

The hydrogen bonding of 1:1 complexes formed between acetamide and three kinds of isomers of picolines have been completely investigated using B3LYP method at various basis set levels from 6-31G to 6-31+G and 6-31++G. The results show that the interaction energies of hydrogen bond complexes between acetamide and picoline isomers have great effects on the values of h_.

2采用密度泛函理论等方法研究了乙酰胺分子分别与甲基吡啶三种异构体分子以1：1的比例形成的氢键络合物，从B3LYP/6-31G到6-31++G基组水平进行了优化，利用结合能数据讨论了焓对作用系数的差异。

This dissertation is dedicated to investigate the pyrolysis of the fuel-bonded nitrogen model compounds,including five-membered ring nitrogen model compound pyrrole and the substituted six-membered ring nitrogen compound 4-methyl pyridine,with vacuum ultraviolet single-photon ionization combined with molecular beam mass spectrometry technique.

本论文利用同步辐射真空紫外单光子电离、分子束取样和反射式飞行时间质谱相结合的技术研究了含氮杂环模型化合物的热解，包括五元环含氮体系、六元环含氮体系和替代的六元环含氮体系(4-甲基吡啶)。

The critical crossover behavior in the ternary electrolyte solutions of water＋3-methylpyridine＋sodium bromide is a matter of debate.

对水＋3-甲基吡啶＋溴化钠三元电解质溶液的临界跨接行为的认识存在着争议。

Adenosine was used as the raw material, dissolved in triethyl phosphate and then esterified with thiophosphoryl chloride under 0~5℃ for 8h without water and oxgen, in alkaline condition provided by 2,6-dimethylpyridine, introducing thiophosphoryl ester to adenosine.Then superfluous triethylamine was added and reacted under 5℃ for 1h to synthesize rough 5'-AMPS.The unpurified product was appled to a DEAE Sephadex A-25 column and eluted with triethylammonium bicarbonate.

用腺苷为起始原料，溶解于磷酸三乙脂中后，在无水无氧环境中及2，6-二甲基吡啶提供的碱性条件下与三氯硫磷以0~5℃下发生酯化反应8h，将硫代磷酸酯引入腺苷，然后再与过量三乙胺在5℃下反应1h，合成粗产品，再用碳酸氢三乙胺作洗脱液，过DEAE Sephadex A-25凝胶柱纯化。

Methods Compound 3 was got via the formation of the amide from 2-chloro-3-amino-4-methyl pyridine and 2-chloronicotinoyl chloride, and then nevirapine was acquired by the aminolysis of 3 with cyclopropylamine in an autoclave, followed by the intramolecular nucleophilic substitution.

以2-氯－3-氨基－4-甲基吡啶为原料，依次与2-氯烟酰氯缩合成化合物3、再与环丙胺高压氨解、最后发生分子内亲核取代反应，成功合成了奈韦拉平。

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Application of organic acid catalysis to the polymerization of pyrroles and pentafluorobenzaldehydes, with the xylene as reaction medium instead of expensive collidine used in the conventional methodology, resulted in a relatively high yield of TPFPPH〓.

本研究利用有机酸如氯乙酸催化吡咯和五氟化苯甲醛聚合，并以二甲苯替代传统方法所用的昂贵溶剂2，4，6-三甲基吡啶，获得了产率较高的TPFPPH〓。

The process of preparation for 2-chloro-5-chlormethylpyridine by cyclopentadiene cyclization needs to do more research by using green process and decreasing the wastes.

2-氯-5-氯甲基吡啶的合成采用环戊二烯环合法，需研发有利于环境的绿色生产工艺，减少三废，治理三废。

The different intercalation behavior of 5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphine into α-zirconium phosphate and γ-zirconium phosphate was investigated.

比较了水溶性卟啉meso-四(4-N-甲基吡啶基)卟啉对具有不同层间距和结构的层状磷酸锆的插层行为。

A new organic dye ,trans,trans-4-｛4-[4-(N,N-diphenylamino)styryl]styryl｝N-methylpyridinium iodide,has been synthesized and structurally investigated.

合成了一种新型有机染料，反式，反式-4-{4-[4-苯乙烯基]苯乙烯基}-N-甲基吡啶碘盐。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。