甲基乙二醛

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

Part I is devoted to the desensitizing mechanism of a widely-used dentine desensitizer that is the aqueous solution of 35% 2-hydroxyethylmethacrylate plus 5% glutaraldehyde. HEMA, GA and the mixture of HEMA + GA were used to interact with dentin, collagen, hydroxyapatite and bovine serum albumin individually.

Gluma由35％的甲基丙烯酸羟乙酯与5％的戊二醛的水溶液组成，是一种常用的牙本质脱敏药物，但关于其脱敏的机理一直有争论。

The results showed that there were 8 kinds of aliphatic, 5 kinds of esters, 2 kinds of aldehydes, 2 kinds of nitrogen sulfur heterocyclic rings and one kind of hydrocarbon, alcoholics, ketone, lactones respectively in the analyzed 21 kinds of aroma components, and the content of furfural,β-methyl valeric acid, palmitic acid, nicotine, neohytadiene were higher, next were acetyl ethyl propionate, caleric acid, phenyl ethyl acetate, hydroxylic diethyl succinate.

结果表明，在分析出的21种香气成分中，分别有脂肪酸类8种，酯类5种，醛类2种，氮硫杂环类2种，烃类、醇类、酮类、内酯类各l种，其中相对含量较高的物质成分是糠醛、β-甲基戊酸、十六碳酸、烟碱、新植二烯，其次是乙酰丙酸乙酯、异戊酸、苯乙酸乙酯、羟基丁二酸二乙酯等。

A series of methyl 2,7,7-trimethyl-5-oxo-4-aryl1,4,5,6,7,8- hexahydroquinoline -3-carboxylate were synthesized by the reaction of aromatic aldehydes,dimedone and methyl acetoacetate using ammonium acetate as catalyst in glycol under microwave irradiation with 82%～98% yields in 4～6 min.

微波辐射下以芳醛、达咪酮、乙酰乙酸甲酯为原料，乙二醇为溶剂，醋酸铵为催化剂合成了一系列2，7，7-三甲基-5-氧代-4-芳基-1，4，5，6，7，8-六氢喹啉-3-羧酸甲酯化合物，反应时间4~6 min，产率82%~98%。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先，分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料，经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物，将它们与乙二胺缩合生成希夫碱配体，得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

The α-monobromination of 2-pentone,4-methyl acetophenone,4-methoxyacetophenone,6-methoxy-2-acetylnaphthane,2,2,5,5-tetramethyl-3-hexanone,cyclooctanone,cyclododecanone with respectively,were studied.

研究了离子液体三溴化1-丁基-3-甲基咪唑[Br3]对2-戊酮、4-甲基苯乙酮、4-甲氧基苯乙酮、6-甲氧基-2-乙酰基萘、2，2，5，5-4-甲基-3-己酮、环辛酮、环十二酮、丁醛等羰基化合物的α-溴化反应。

Ethyl alcohol, 3-methyl-4-oxo- pentanoic acid, acetic acid butyl ester, 2-methyl-butanoic acid ethyl ester, diethyl phthalate,-2,4-Decadienal were the same volatiles d from the 10 cultivars.

其中共有组6种，为乙醇、3-甲基-4-羰基戊酸、乙酸丁酯、2-甲基丁酸乙酯、邻苯二甲酸二乙酯、-2，4-癸二烯醛。

WANG Wei-Ting, GUO Lian-Jun, QU Ling, WANG Fang, LU Qing, QIAN Jia-Qing(Department of Pharmacology, Tongji Medical College, Huazhong Universityof Science and Technology, Wuhan 430030, China)By using decapitating, intravenous injection of saturated MgCl2 and legation of bilateral carotid arteries with vagi, theeffects of 1-(2,6-dimethylphenoxy)-2-(3,4-dimethoxyphenylethyl- amino) propane hydrochloride on survival time in mice were studied. With the model of cerebral ischemia for 20 min and reperfusion for 10 min, effects of DDPH on the superoxide dismutases activity and malondialdehyde content in brain tissue and pathological changes were studied.

采用断颅，iv饱和MgCl2溶液及结扎双侧颈总动脉和迷走神经等法造成小鼠脑缺血模型，观察1-(2，6-二甲基苯氧基)-2-（3，4-二甲氧基苯乙氨基）丙烷盐酸盐对小鼠脑缺血后存活时间的影响；采用小鼠脑缺血（20 min）再灌注(10 min)模型，观察DDPH对脑组织超氧化物歧化酶活性，丙二醛含量及组织病理损伤的影响。

Some technologies,including olefines from methanol,oxalates and ethylene glycol from carbon monoxide,carbon dioxide-based polymers,chemicals from the syngas prepared by biomass gasification,acetone and butanol by fermentation,and chemicals from acetylene,ethanol,glycerol,furfural,hydroxymethyl furfural and starch,were reviewed.

包括甲醇制烯烃，一氧化碳制草酸酯和乙二醇，乙炔化学品，二氧化碳聚合物，生物质气化合成化工产品，发酵法生产丙酮、丁醇，乙醇衍生化工产品，甘油合成化工产品，糠醛和羟甲基糠醛合成化工产品，淀粉合成化工产品等重要的石油替代化学品生产技术被介绍。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。