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甲基丙烯酸甲酯

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In the determination of methyl acrylate,butyl acrylate and methyl methacrylate in ambient air,the sample was absorbed with active carbon and resolved with carbon bisulfide,and then determined by GC.

测定环境空气中的丙烯酸甲酯、丙烯酸丁酯和甲基丙烯酸甲酯时,气样采用活性炭吸附,用二硫化碳解析,直接进气相色谱仪检测,根据保留时间定性,外标法定量,能获得良好的线性和较低的方法检出限,不仅精密度、灵敏度和重复性良好,而且可操作性强,易于在环境监测系统中推广。

In the determination of methyl acrylate,butyl acrylate and methyl methacrylate in ambient air,the sample was absorbed with active carbon and resolved with carbon bisulfide,and then determined by GC.After the qulitation by retention time and quantitation by external standard method,the good linearity and low detection limit were got.

测定环境空气中的丙烯酸甲酯、丙烯酸丁酯和甲基丙烯酸甲酯时,气样采用活性炭吸附,用二硫化碳解析,直接进气相色谱仪检测,根据保留时间定性,外标法定量,能获得良好的线性和较低的方法检出限,不仅精密度、灵敏度和重复性良好,而且可操作性强,易于在环境监测系统中推广。

Poly-acrylic acid resin was synthesized by emulsion polymerization with meth-acrylic acid and methyl meth-acrylate as monomers. Which used as enteric film-coating material: aqueous poly-acrylic acid resin Ⅲ. and then desiccate them to resin powder by sprayer.

以甲基丙烯酸与甲基丙烯酸甲酯为共聚单体,用乳液聚合法制备肠溶型水性聚丙烯酸树脂Ⅲ乳液,喷雾干燥成树脂粉末。

The effect of cationic comonomer methacryloyloxy ethyl trimethylammonium chloride on the rate of polymerization,the dissolvability of polymer in THF,the stability and pH value of methyl methacrylate/butyl acrylate/DMC soap-free emulsion were studied systematically.

研究了阳离子型共聚单体甲基丙烯酰氧乙基三甲基氯化铵的用量对甲基丙烯酸甲酯/丙烯酸丁酯/DMC 无皂乳液聚合速率、聚合物在THF中的溶解性、乳液稳定性及pH值的影响。

Polymer A is a acrylic copolymer containing 70% by weight of methacrylic acid and 30% by weight of methyl methacrylate prepared by a catalytic chain transfer method to give a polymer having a number averaged molecular weight of approximately 600 as measured by GPC.

聚合物A是丙烯酸共聚物其含有甲基丙烯酸重量70%,按重量的30%甲基丙烯酸甲酯的催化链转移的方法准备给予聚合物具有的平均人数约600分子量为由GPC测定。

However, common polyacrylate emulsion has some disadvantages such as poor water-resistance, poor film-forming in low temperature, becoming pastiness in high temperature, polluting environment with emulsifier and so on.

由于聚丙烯酸酯乳液具有耐热、耐光和耐老化等优点在涂料工业中得到了广泛的应用,但普通的聚丙烯酸酯乳液还存在耐水性差、低温下不易成膜、高温发粘以及含乳化剂的废液会对环境造成污染等缺点,因此,本文结合无皂乳液聚合和核壳乳液聚合技术,合成了聚丙烯酸丁酯/丙烯酸钠齐聚物,并以此为乳化剂,采用种子半连续法合成了以聚丙烯酸丁酯为核,聚甲基丙烯酸甲酯-苯乙烯为壳的无皂核壳聚丙烯酸酯乳液。

An acrylic resin was synthesized by the radical copolymerization with methyl methacrylate, butyl acrylate and methacrylic acid monomers in solution using benzoperoxide as initiator. Appropriate parameters of monomer ratio, monomer concentration, solvent, and reaction temperature were found by experiment.

以过氧化二苯甲酰为引发剂,采用溶液聚合合成了甲基丙烯酸甲酯-丙烯酸丁酯-甲基丙烯酸树脂,通过实验确定了自由基共聚合适宜的单体配比、单体浓度、引发剂浓度、溶剂以及反应的升温速度。

The title nano-sized polymeric microgels were synthesized by emulsion polymerization method,using divinyl benzene as crosslinking agent and methyl methacrylate,hydroxyl ethyl methacrylate,butyl acrylate as monomers.

通过乳液聚合的方法,以二乙烯基苯为交联剂,用甲基丙烯酸甲酯、甲基丙烯酸-β-羟乙酯、丙烯酸丁酯等丙烯酸酯类单体合成纳米尺寸的聚合物微凝胶粒子。

Two kinds of cross-linked polyacrylate latices with relatively narrow distribution of particle diameters, which are abbreviated to P and P/P, were synthesized by seeded emulsion co-polymerization, respectively. Butyl acrylate and 2-ethylhexy! acrylate were used as comonomers of ACR core, styrene and methyl methacrylate were employed as comonomers of ACR shell, and 1,4-butanediol diacrylate was used as cross-linking agent.

采用丙烯酸丁酯和丙烯酸2-乙基己酯(2-EHA)为核层单体、苯乙烯和甲基丙烯酸甲酯为壳层单体、1,4-丁二醇二丙烯酸酯为交联剂,通过多步种子乳液聚合方法合成了P、P/P两种具有窄粒径分布的共聚丙烯酸酯胶乳。

MaterialsMethylmethacrylate, ethyl acrylate, acrylic acid and methacrylic acid (all A.R. grades, FirstChemical Reagent Factory, Tianjin, China) were puried bydistillation under reduced pressure and kept in therefrigerator.

物料甲基丙烯酸甲酯,丙烯酸乙酯,丙烯酸和甲基丙烯酸(所有机场铁路等级,第一化工试剂厂,天津,中国)的纯化减压蒸馏和留在refrigerator。

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