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甲基丙烯酸

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OBJECTIVE: To observe the biocompatibility and fibrovascular condition of methl-methacrylate modified PHEMA hydrogel orbital implant.

目的:观察通过甲基丙烯酸改性聚甲基丙烯酸β羟乙酯水凝胶义眼台的生物相容性和纤维血管化情况。

The technological conditions with methylacrylic acid and hexadecanol as raw-material and the synthesis of hexadecyl methylacrylate by direct-esterification are studied.

研究了以α-甲基丙烯酸和十六醇为原料采用直接酯化法合成α-甲基丙烯酸十六酯的工艺条件。

Aniline-BP was used as CTC system to initiate the polymerization ofMMA under UV irradiation, PMMA prepolymer with aromatic imino endgroup was prepared.

以苯胺-BP为CTC体系,在紫外光辐射下,引发甲基丙烯酸甲酯聚合,得到了含有芳亚胺端基的聚甲基丙烯酸甲酯预聚物。

In the polymerization procedure,S--α-phenyl ethylamine was used as target template molecules,methacrylic acid was selected as functional monomers, ethylene glycol dimethacrylate or divinylbenzene as crosslinker, azobisisobutyronitrile or benzophenone was used as irritator.

以S--α-苯乙胺为模板,甲基丙烯酸为功能单体,分别以二甲基丙烯酸乙二醇酯、二乙烯基苯为交联剂,偶氮二异丁睛或二苯甲酮为引发剂,采用了本体聚合法、悬浮聚合法合成了一系列的S--α-苯乙胺印迹聚合物。

First, according to documents report, the complexes of poly (methacrylic acid-co-methyl methacrylate) network with poly stabilized by the hydrogen bonds were designed and synthesized.

首先根据文献报道,设计并合成了聚(甲基丙烯酸-co-甲基丙烯酸甲酯)网络及其与聚乙二醇的氢键聚合物网络复合物。

And we also modify the surface of the glass fiber reinforcedunsaturated polyester with the G-02 and G-04. It reacts with the materials surface layer whenthe Composite solidifies. It gets a lower critical surface tension, high contact angle. Theproperty of waterproof and oilproof has improved.

并且利用已有的活性物质(甲基丙烯酸六氟丁酯G-02,甲基丙烯酸十二氟庚酯G-04)处理玻璃纤维增强不饱和聚酯的表面,在基体固化时,实现在材料表层参与固化反应,获得特低临界表面张力、高接触角特性,使处理后的玻璃钢表面具有一定的疏水疏油性能。

Secondly,UV spectrophotometry was adopted to research the combination action on SM_2 and SIZ with MAA and 4-Vp.The combination action of functional monomer with template molecules were produced in the results. Then,the prediction imprinting principle of SM_2 and SIZ were given. The diagrams of infrared spectrum were analysed in MAA and 4-Vp and IMPs of SM_2. It was discoved that the absorbability peak of C=C function group in the IMPs were turn to be very low ,but the function group of carboxylic acid and pyridyl in the IMPs were no evidence change, and the condition was created in the molecular recognition of MIPs. Thermal Analysis was adopted to research IMPs ,in which ,a better thermal stability and its decompose temperature were showed in the results.

其次,本文利用紫外分光光度法研究磺胺二甲嘧啶和磺胺异噁唑与甲基丙烯酸或4-乙烯基吡啶的结合作用,结果表明,溶液中的功能单体与模板分子之间产生了结合作用,并预测磺胺二甲嘧啶和磺胺异噁唑印迹机理;分别分析了功能单体甲基丙烯酸、4-乙烯基吡啶、磺胺二甲嘧啶和磺胺异噁唑分子印迹聚合物的红外谱图,经过对比发现制得的印迹聚合物中C=C双键峰很小,并且功能键羧酸键和吡啶氮没有明显变化,这为聚合物特异识别特性创造了条件;利用综合热分析仪,对分子印迹聚合物进行综合热分析,结果表明分子印迹聚合物具有较好的热稳定性,分解温度也较高。

The encapsulated TiO〓 particles by polymer were obtained with soapless emulsion polymerization of methyl methacrylate in water in the presence of the pretreated TiO〓 particles.

一种是用偶联剂钛酸丁酯对亲水性TiO〓粒子进行预处理,钛酸丁酯与TiO〓表面羟基反应,交联到TiO〓粒子表面,使TiO〓粒子表面由亲水性转变为憎水性,改善无机粉体与有机单体的亲合性,再进行TiO〓存在下甲基丙烯酸甲酯的无皂乳液聚合,即可得到TiO〓-PMMA复合粒子:另一种方法是用表面活性剂对TiO〓进行预处理,再进行TiO〓粒子存在下甲基丙烯酸甲酯的无皂乳液聚合,TiO〓粒子表面可形成一层均匀的聚合物膜,提出了包覆机理,指出单体在无机粉体表面发生聚合的关键是预先在粒子表面形成聚合场所,即吸附一层表面活性剂。

Solution polymerization and amide reaction were used to synthesize the multifunctional comb-type amphiphilic polymer, stearyl methacrylate/ methylacrylic acid-ethanolamine-ethanediamine-folic acid polymer.

利用溶液聚合和成酰胺反应合成了多功能梳状两亲性共聚物,聚甲基丙烯酸-甲基丙烯酸十八酯-乙醇胺-乙二胺叶酸。

A micro-monolithic column was prepared by in-situ free radical polymerization of stearyl methacrylate with ethylene glycol dimethacrylate in the presence of the initiator AIBN and a mixture of porogens including iso-amyl alcohol and 1,4-butanediol.

甲基丙烯酸碳酰十八酯为单体,乙叉二甲基丙烯酸酯为交联剂,异戊醇和1,4-丁二醇为二元致孔剂,偶氮二异丁腈为引发剂,原位制备了具有强疏水性的SMA整体微柱,并利用此整体微柱在普通高效液相色谱仪上测定滴眼液中氧氟沙星的含量。

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