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甲基丙烯酸

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Through replacing copper Tri-fluoroacetate by copper α-methacrylic in Metal Organic Deposition process, the total amount of fluorine in YBCO precursor solution was reduced by about 50%. As a result, the calcination period for YBCO precurse film was dramatically reduced.

在金属有机盐沉积法制备YBCO薄膜的工艺中,采用无F的α甲基丙烯酸铜取代原来的三氟乙酸铜,可以降低前驱溶液中大约50%的氟含量。

The research of polymer/layered silicate nanocomposite was introduced detailedly, including the classify, property and the latest research advance. On the basis of consulting the document and the exploratory experiment, the experimental method which first creative preparing poly (acrylonitrile-vinyl acetate)/raontmorillonite nanocomposite by emulsion intercalation copolymerization was established; the structure and property of polyacrylonitrle different molecule weight with inorganic mineral super fine nanocomposite was reseached. The reaction principle of PMMA by photo-initution was explored. The mixture principle with productor condition, property of PE/Clay nanocomposite milt insert was seal prived. By PS/Clay nanocomposite munufacture, the monomer ins-polymerization and polymerial solution was proved.

在查阅文献和探索性实验的基础上,确定采用乳液原位插层聚合方法首先创制了聚/蒙脱土纳米复合材料,利用正交实验得出了最佳实验条件,通过X射线衍射和红外光谱对纳米复合材料的结构进行表征,研究了复合材料的溶解性能,并测定了其溶液的绝对粘度;研究了不同相对分子质量的聚丙烯腈与不同的无机矿物超细粉复合材料的结构与性能;探讨了在蒙脱土中光引发聚甲基丙烯酸甲酯的反应机理;通过聚乙烯与粘土的纳米复合材料制备,探讨了热塑性树脂熔融插层复合机理与最佳工艺条件和复合材料性能关系;通过聚苯乙烯与蒙脱土纳米复合材料制备,验证了单体原位聚合插层和聚合物溶液插层机理。

The magnetic polymer complex microspheres with core-shell structure were synthesized by copolymerizing of pyrrolidone acid and methacrylic on surface of Fe3O4 particles modified by OP, using potassium persulfate as a initiator.

以N-乙烯基吡咯烷酮和甲基丙烯酸为原料,过硫酸钾为引发剂,采用乳液聚合的方法共聚包埋自制的磁流体Fe3O4,制得了Fe3O4/P核壳复合微球。

The semiconductor nanocrystalline surface is modified by using organic overlay method. As an organic overlay,-methacrylic restrains the reuniter between the grains in the latter process. Furthermore, it can combine with empty bond of atom at grain surface state and eliminate the surface state.

应用有机包覆的方法对纳米颗粒进行了表面修饰,作为包覆剂的α-甲基丙烯酸有效抑制了后处理工艺中纳米颗粒间的团聚现象,在纳米颗粒表面形成帽层,并与粒子表面态的原子悬键进行配位,这对消除表面态是非常有益的。

Two multifunctional agent, glycidyl methacrylate and refined ricinoleic acid , were adopted to modify EPDM in situ during compounding and vulcanization process. The effects of the modifiers on vulcanization behavior, processiability, different properties of the vulcanizates were investigated.

为此,选择了含有极性基团的多官能团小分子改性剂甲基丙烯酸缩水甘油酯和精制蓖麻油酸,在橡胶混炼和硫化过程中对EPDM进行原位改性,研究了原位反应技术对过氧化物硫化EPDM橡胶的反应特性、加工性能、力学性能、热性能、耐老化性能、耐屈挠疲劳性能及与金属的粘合强度等性能的影响,并探讨了其改性的机理。

In order to improve the interfacial adhesion between the matrix and inorganic particles, the SiO2 nanoparticles were modified with polymethyl methacrylate and silicane couplant KH507 respectively, and then the SiO2/PVC composites were prepared via the melt blending method. The microstructure and mechanic properties of SiO2 nanoparticle filled PVC composites were investigated by FT-IR.

利用表面原位接枝聚合在纳米二氧化硅颗粒表面引入聚甲基丙烯酸甲酯高分子链段,用共混法制备了nano-SiO2/PVC复合材料,研究了不同界面特性时SiO2/PVC复合材料的力学性能。

A novel polymer of Poly(diglycidyl maleate-co-stearyl methacrylate) was synthesized and its structure was characterized by ~1H NMR. Its self-assembly behavior was studied in different solvents. It was found that vesicles and tubule-liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA)/THF/EtOH system. And spheral aggregates were obtained in P(DGMA-co-SMA)/THF/H_2O system while the spheral aggregates were converted into rod-liked aggregates and line-liked aggregates after aged for different time.

合成了带含环氧基侧链和十八烷基侧链的聚(马来酸二缩水甘油酯-co-甲基丙烯酸十八酯),用~1H NMR对所得的共聚物进行了表征;研究了其在选择性溶剂中的自组装行为,发现P(DGMA-co-SMA)/THF/EtOH体系可以通过自组装形成囊泡形自组装体和支化的管状自组装体,P(DGMA-co-SMA)/THF/H_2O体系最初自组装形成球形自组装体,随着陈化时间的延长,球形自组装体逐渐融合成长条形自组装体和线形自组装体;探讨了自组装过程的机理,建立了可能的自组装过程模型。

The evaluation method and physics meaning of every parameter in the viscosity relationship equation were elaborated using theologic experiment data, and the viscosity relationship equation be referred to in the literature were appraised using simulate data and experiment data.

利用聚甲基丙烯酸甲酯乳胶体系的流变数据,阐述该粘度关系方程式中各参数的求值方法及其物理含义。同时也用数值模拟数据以及实验数据,评价了文献中所提到的粘度方程。

The dispersion and stability of BaTiO〓 suspensions with tribasic ammonium citrate and ammonium salt of poly as dispersants were investigated respectively by means of sediment experiment and rheology measure, and the optimal dispersion conditions were obtained.

通过沉降实验和流变性测量,研究了分散剂柠檬酸三铵、聚甲基丙烯酸铵分别对BaTiO〓悬浮体的分散和稳定作用,确定了分散剂最佳使用条件。

A series of UV curable waterborne hyperbranched polyester s with different acid/amine terminal rate,which contained -OH?-COOH and methacrylic chain end groups,and were partly neutralized with thertiary amine,were synthesized from trimellitic anhydride,epichlorohydrin,glycidyl methacrylate and triethylamine.

以偏苯三酸酐、环氧氯丙烷、甲基丙烯酸缩水甘油酯、三乙胺合成了末端羧基与氨基不同比例的一系列可UV固化的高支化聚酯,研究了末端官能团对合成产物水溶性、粘度以及凝胶转化率的影响。

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