甲基丙烯酸

Polyethylene glycol dimethacrylate, one of the fine chemical intermediates is the main ingredient of anaerobe. With the development of adhesives, the domestic production of polyethylene dimethacrylate has been challenged from many aspects, therefore, to improve the production technics and yields has been the key problem to resolve at present.

缩乙二醇双甲基丙烯酸酯——精细化学品中间体之一，作为胶粘剂中厌氧胶的主剂，在胶粘剂日益发展的今天，国内的缩乙二醇双甲基丙烯酸酯生产受到了很多方面的挑战，因此，改进生产工艺，提高产率是目前缩乙二醇双甲基丙烯酸酯生产首要解决的问题。

At first, the polymerization characteristic of BMA was discussed in the paper, by contrast with MMA, using the instrument dilatometer. It was confirmed that the polymerizing activity of BMA was lower than MMA, and its polymerizing condition was stricter.

本文首先对甲基丙烯酸丁酯和甲基丙烯酸甲酯的聚合特性进行了对比研究，用膨胀计法测定了两者在不同引发条件下的聚合动力学，证实了甲基丙烯酸丁酯的聚合活性比甲酯要低，聚合条件更为严格。

Water, Cyclomethicone, Glycerin, Sd Alcohol 40-B (Alcohol Denat.), Propylene Glycol, Melia Azadirachta Leaf Extract, Lecithin, Arctium Lappa Root Extract, Xylitol, Lactitol, Alpha-Glucan Oligosaccharide, Lactoferrin, Potassium Thiocyanate, Glucose Pentaacetate, Glucose Oxidase, Lactoperoxidase, Glycoproteins, Panax Ginseng Root Extract, Equisetum Arvense Extract, Hydrolyzed Milk Protein, Peg-8, Caprylyl Glycol, Sebacic Acid, Sodium Polyacrylate, Betula Alba Bark Extract, Cupressus Sempervirens Leaf Extract, Hamamelis Virginiana Extract, Avena Sativa Meal Extract, Humulus Lupulus Extract, Silk, Nylon-12, Polyacrylamide, Polymethyl Methacrylate, Butylene Glycol, Salicylic Acid, Lauryl Methacrylate/Glycol Dimethacrylate Copolymer, Tocopheryl Acetate, C13-14 Isoparaffin, Laureth-7, Triethanolamine, Xanthan Gum, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Phenoxyethanol, Chlorphenesin, Benzoic Acid, Methylparaben, Fragrance, Titanium Dioxide

水，环甲硅脂，甘油，Sd Alcohol 40-B，丙二醇，印度楝树叶萃取，卵燐脂，牛蒡根萃取，木糖醇，乳糖醇，α-葡低聚糖，乳铁蛋白，硫氰酸钾，葡萄糖五乙酸酯，葡萄糖氧化酶，乳过氧化物酶，糖蛋白，人参根萃取，问荆萃取，水解牛奶蛋白，聚乙二醇-8，辛乙二醇，癸二酸，聚丙烯酸酯钠，白桦萃取，丝柏叶萃取，金缕梅萃取，燕麦萃取，啤酒花萃取，丝，尼龙－12，聚丙烯醯胺，聚甲基丙烯酸甲酯，丁二醇，水杨酸，甲基丙烯酸十二酯，醋酸盐维他命E，C13-14 异烷烃，月桂醇聚醚-7，三乙醇胺，山羊胶，丙烯酸/C10-30烷基丙烯酸聚合物，苯氧乙醇，氯苯甘醚，苯甲酸，羟苯甲酯，香料，二氧化钛

The influences of N,N'-methene biacrylamide cross-linker,monomer concentration,polymerization time and temperature on swelling ratio were investigated,and reversibility of the hydrogels under various pH conditions at given temperature.

目的通过合成聚丙烯酸-co-α-甲基丙烯酸水凝胶，研究N，N'-亚甲基双丙烯酰胺交联剂、丙烯酸和α-甲基丙烯酸单体浓度、聚合时间对其水凝胶溶胀率的影响，以及温度和不同pH值时水凝胶的pH可逆性。

The main contribution of this paper is summarized as follow:1 Copolymer acrylate resin including hydroxyl, carboxylic and amina(-NH_2) is a new type of antifogging system and ahydrophi- lic antifogging constituents which is not found before.2 Water-soluble acrylate resin hydrophilic antifogging coating material is a new-type environmental protection material which takes ethanol as solvent and whose pastiness is adjusted by deionized water.3 The quality rate of accessory soft monomer ethyl acrylate and accessory hard monomer butyl methacrylate is 6 to 4, the quality rate of functional monomers in all monomers is 20 percent, the quality rate of MAA in the functional monomers is 22 percent, the quality rate of β-hydroxyl ethyl acrylate in the functional monomers is 8 to 10 percent and the remainder of functional monomer is acrylic acid.4 Cross-linking agent methylol acrylamide belongs to self-cross-linking system.

本文的主要贡献概述如下： 1 含有亲水羧基、羟基和氨基(-NH_2)丙烯酸共聚树脂是一种新型高效的防雾体系，用的亲水防雾组分是前所未有的。 2 以乙醇为溶剂制得水溶性丙烯酸树脂具有很好的水溶性能和防雾性能，只需加入去离子水就可以调节它的粘度，是一种新型的环保型防雾材料。 3 辅助软单体丙烯酸乙酯和辅助硬单体甲基丙烯酸甲酯最佳配比为质量比6∶4；官能单体占单体总量的20%，甲基丙烯酸占官能单体总量10～15%，甲基丙烯酸β-羟乙酯占官能单体总量的8～10%，剩下的为丙烯酸。

Molecularly imprinted polymers of sulfamethazine(SM 2 ) were prepared with silica gel as a sacrificial material, methacrylic acid and 4 vinylpyridine(4 Vp) as functional monomers, glycol dimethacrylate as crosslinker. The polymer properties were investigated by static adsorption experiments. Scatchard analysis shows that the adsorption ability of MAA MIP is superior to that of 4 Vp MIP. The dissociation constant of MAA MIP is 9 59×10 -4 mol/L. The value of apparent binding a...

以磺胺二甲嘧啶为模板分子，分别用甲基丙烯酸和4乙烯基吡啶为功能单体，二甲基丙烯酸乙二醇酯为交联剂，采用牺牲硅胶法合成了磺胺分子印迹聚合物，通过静态吸附实验，系统研究了不同单体对聚合物识别性能的影响；Scatchard分析表明，以甲基丙烯酸为单体的聚合物具有较高的吸附能力，其离解常数Kd为959×10-4mol/L，最大表观结合位点数Qmax为3070μmol/g。

Hrough copolymerization of styrene with few quantity of methacrylic acid, maleic anhydrate or 4-vinyl pyridine respectively and of butyl methacrylate with maleic anhydrate, the functional groups carboxyl, simple anhydride and pyridyl have been introduced respectively to the chain of PS or PBma.

通过苯乙烯与少量的甲基丙烯酸、马来酸酐或4—乙烯基吡啶的共聚及甲基丙烯酸正丁酯与马来酸酐的共聚，可在聚苯乙烯及聚甲基丙烯酸丁酯链上分别引入功能基因羧基、酸酐基和吡啶基对共聚物进行了红外光谱、酸碱滴定、元素分析、玻璃化转变温度、粘度及紫外光谱的测定。

Fine chemicals to add auxiliary Series: lubricating oil pour point depressant, calcium zinc magnesium methacrylate, methyl acrylic acid lauryl ester, tetradecane methacrylate ester, methacrylic acid octadecyl ester, a acid ethylene glycol, diethylene glycol methacrylic acid ester, glycidyl methacrylate, the second reduction of three ethylene glycol dimethyl acrylate, acrylic acid lauryl ester, tetradecyl acrylate, octadecyl acrylate, acrylic acid ethylene glycol, diethylene glycol acrylate esters, glycidyl, two shrink three acrylate such as ethylene glycol.

精细化工添加助剂系列：润滑油降凝剂，甲基丙烯酸钙锌镁，甲基丙烯酸月桂酯，甲基丙烯酸十四烷酯，甲基丙烯酸十八烷基酯，甲基丙烯酸乙二醇，甲基丙烯酸二乙二醇酯，甲基丙烯酸缩水甘油酯，二缩三乙二醇二甲基丙烯酸酯，丙烯酸月桂酯，丙烯酸十四酯，丙烯酸十八酯，丙烯酸乙二醇，丙烯酸二乙二醇酯，丙烯酸缩水甘油酯，二缩三乙二醇丙烯酸酯等。

A photosensitive resin for UV curing acrylic powder coating has been synthesized by esterification of methacrylic acid and GMA-type acrylic resin at the presence of ethyl acetate as solvent, tetramethylammonium chloride as catalyst, YK as inhibitor.

以醋酸丁酯为溶剂，四甲基氯化铵为催化剂，氮氧自由基为阻聚剂，由甲基丙烯酸缩水甘油酯类丙烯酸树脂与甲基丙烯酸酯化反应制得了UV固化粉末涂料用感光性丙烯酸树脂。

Polyurethane-acrylics hybrid latexes were prepared using isophorone diisocyanate, dimethylol propanoic acid and polypropylene oxides of different molecular weights as main materials for PU component, and butyl acrylate, methyl methacrylate and a crosslinker, trihydroxymethyl propanetriacrylate as main acrylic monomers. Hydroxyethyl acrylate was used as the coupling agent between PU and AC.

以异佛尔酮二异氰酸酯、二羟甲基丙酸和聚丙醚二醇等为聚氨酯原料，丙烯酸丁酯、甲基丙烯酸甲酯、三羟甲基丙烷三丙烯酸酯为丙烯酸酯类单体，丙烯酸羟乙酯为聚氨酯和聚丙烯酸酯间的偶联剂合成了丙烯酸酯改性水性聚氨酯乳液。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。