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Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料,经过亚硝化、还原、与乙酰丙酮加成环化生成2, 4-二甲基-3-乙酰基-5-苄氧羰基吡咯(5),通过选择性氧化反应制得目标化合物2-甲酰基-3-乙酰基-4-甲基-5-苄氧羰基吡咯(6),反应的总收率约为34%。

It was discovered that proteases, lipases and abzymes can be used for the regioselective acylation of sucrose.

酶催化合成蔗糖酯通常在N,N-二甲基甲酰胺,二甲基亚砜和吡啶等有毒溶剂中进行。

Aqua、Butylene Glycol、Dimethicone、Cyclomethicone、Glycerin And Glyceryl Acrylate/Acrylic Acid Copolymer And Propylene Glycol And PVM/MA Copolymer、Hydrolyzed Adansonia Digitata Extract、Commiphora Myrrha Extract、Hydrolyzed Callogen、Carbomer、Triethanolamine、Allantoin、Elastin 、Diazolidinyl Urea、Fragrance .

水、丁二醇、聚二甲基硅氧烷、环聚二甲基硅氧烷、甘油和甘油丙烯酸酯/丙烯酸共聚物和丙二醇和PVM /MA共聚物、水解猴面包树提取物、没药提取物、水解胶原、卡波姆、三乙醇胺、尿囊素、弹性蛋白、双咪唑烷基脲、香精。

Amino-2-methylpropanol was used as the chemical modifying reagent of fatty acids to modify the carboxyl group into nitrogen-containing heterocycle which would effectively prevent the migration of carbon double bonds of the alkenyl in the electron impact source.

以2-氨基-2-甲基-丙醇为脂肪酸的化学修饰试剂,气相色谱-电子轰击质谱分析葵子油脂肪酸。2-氨基-2-甲基-丙醇将脂肪酸羧基修改为含氮杂环,使在EI源中避免了链烯基中碳碳双键的移动。

Using N, N-dimethyl-ethylenediamine as cationic substitute and 2-hydroxyethyl methacrylate or allylamine as co-substitute, a kind of pH-sensitive polyorganophosphazenes bearing unsaturated side group was prepared.

以N,N-二甲基乙二胺为阳离子型取代基,甲基丙烯酸羟乙酯或烯丙胺为共取代基,制备了同时带有pH响应性侧基和不饱和双键侧基的聚膦腈。

Sodium 2-Acrylarnido-Acetate has been synthesized through the reaction of Aminoacetic acid with acryloyl chlorine, then Copolymer of sodium 2-acrylamido-acetate and dimethyl diallyl ammonium chloride with acrylamide had been prepared by free radical polymerization using (NH4)2S2O8 and NaHSO3 as the free radical initiator in water solution.

本论文首先以氨基乙酸和丙烯酰氯为原料制备丙烯酰胺基乙酸钠单体,然后以丙烯院胺丙烯酰胺基乙酸钠和二甲基二烯丙基氯化铵为单体,(NH4)2S2O8和NaHSO3为自由基引发剂,采用水溶液聚合法合成丙烯酰胺/丙烯既胺基乙酸钠/二甲基二烯丙基氯化铵共聚物。

Phthalimide,anthranilic acid,2methyleneglutaronitrile bromina 1bromobutane 1,2benzisothiazole3one.

邻苯二甲酰亚胺,邻氨基苯甲酸,2亚甲基戊二脯,2溴2溴甲基戊二脯,溴代正丁烷,1.2苯并异噻唑3酮。

We have not found any reports that o-toluidine and N,N-dimethylaniline can be used as antiknock. The electrochemical properties of aromatic amine are in line with its' antidetonating quality and actual application.

而实际上采用胺类化合物作抗爆剂时,一般使用N-甲基苯胺、苯胺、邻甲苯胺及间甲苯胺,尚未见到使用对甲苯胺和N,N-二甲基苯胺的报道。

The DNA methylation level in stem apices treated with 5-azaC was comparable to that of seedlings treated at 5℃ for 10 days.

本文研究了去甲基化因子5-氮杂胞苷(5-azaC)对萝卜开花及幼苗茎尖DNA甲基化水平的影响。

Methods PCR-SSCP and PCR product cloning, sequencing were performed to detect mutation of p16 gene exon 2 in peripheral blood of 60 patients with arseniasis caused by coal-burning pollution,at the same time,PCR-based methylation assay was performed to analyze the methylation of p16 gene exon 1. Results No p16 gene exon 2 mutation was found in 60 cases.

采用聚合酶链反应-单链构象多态性分析和PCR产物克隆测序技术对60例砷中毒患者外周血中p16基因第2外显子突变情况进行检测,同时采用甲基化敏感的限制性内切酶方法对p16基因第1外显子甲基化情况进行分析。

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