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Phenyl or m -tolyl selenoamides reacted with functionalized α-haloacetic acid in 1∶1 or 1∶2 molar ratio with no catalyst in various alcohols to undergo a selenium transfer reaction. This reaction in dif-ferent molar ratios furnished the same C—Se—Se—C coupling products with a special structure bis diselenide. A new and facile method for synthesis of such bis(alkoxycarbonyl-methyl) diselenides with the advantages of mild reaction conditions, high yields, easy availability of starting materials and good chemical selectivity was provided.

芳基硒代酰胺与氯乙酸在各种醇中无催化剂下以1∶1和1∶2的比例投入,发生硒转移反应,不同原料投入比下的反应生成了同一种C—Se—Se—C偶联产物——具有多功能团的二烷氧羰基甲基二硒醚,提供了一种新的合成二烷氧羰基甲基二硒醚的简便方法,且反应具有条件温和、产率高、原料易得和选择性好等优点。

Furthermore, besides considering changes in DNA methylation as mechanisms of disease, the role of epigenetics in general and DNA methylation in particular in transgenerational carcinogenesis, in memory formation and behavior establishment are brought about as mechanisms based on the cellular memory of gene expression patterns.

而且,除了考虑DNA甲基化改变作为疾病的机制外,表观遗传学一般的及DNA甲基化特别的在隔代致癌中的作用,在记忆形成和行为确立被引发作为基于基因表达模式的细胞记忆的机制。

In the derivatives of 2-(4-bromobenzyl-amino)-4-methyl-6-trifluoromethyl-1, 3, 5 triazine, the atoms of N(8), C (9) were the important active parts, it was considered to bind to the different amino acid residue at the D1 protein as traditional striazine herbicides.

对于2-(4-溴苄氨基)-4-甲基-6-三氟甲基-1,3,5-三氮苯中,N(8)和C(9)是重要的活性部位,和传统的均三氮苯类除草剂分子相比,与D1蛋白上不同的氨基酸残基发生了键合作用。

Nitratomethyl-3-ethyloxetane was synthesized by the process of cyclization, nitation from trimethlolpropane and diethyl carbonate, and the homopolymer of 3-nitratomethyl-3-ethyloxetane was synthesized with 1,4-butanediol as initator and boron trifluoride etherate as an catalyst by cationic ring-opening polymerization.

以三羟-甲基丙烷和碳酸二乙酯为原料经环化、硝化两步反应合成了化合物3-硝酸酯甲基-3-乙基氧丁环;采用1,4-丁二醇为引发剂,三氟化硼乙醚(BF3Et2O)为催化剂,NIMEO发生阳离子开环聚合得到一种端羟硝酸酯均聚醚PNIMEO。

In pH 5.3-6.8 Britton-Robinson buffer medium, Cefotaxime sodium can react with HgCl2 to form 1:1 anionic chelate, which can further react with basic triphenylmethane dye such as crystal violet, methyl violet, ethyl violet, brilliant green, iodine green, methyl green and malachite green to form ternary ion-association complexes. As a result, the resonance Rayleigh scattering spectrum was enhanced greatly.

在pH为5.3~6.8的Britton-Robinson缓冲溶液中,头孢噻肟钠与HgCl2形成摩尔比为1:1的螯合阴离子,它能进一步与结晶紫、甲基紫、乙基紫、亮绿、碘绿、甲基绿和孔雀石绿等碱性三苯甲烷类染料反应形成三元离子缔合物,导致共振瑞利散射的显著增强。

Accord- ing to the observation that the compounds were stable in low pH aqueous solution and their sta- bility decreased when pH increased, and they rapidly decomposed to form α-methylenecyclopen- tanones derivative when pH reached 6 to 7, we postulated that the compounds were unabsorbable in stomack (where pH1-3) and unstable in small intestine (where pH5-8). The decomposed product was indeed inactive.

对Ⅰ类化合物在稀溶液中的稳定性研究表明,低pH时化合物较稳定,随着pH值的升高稳定性逐渐降低,pH6~7时,化合物迅速分解成α-亚甲基环戊酮类化合物,由此而推测Ⅰ类化合物经口给药无效的原因为:它们在强酸性的胃中(pH1-3)呈离子状态,因而不易吸收,经胃的排空运动进入肠道后,随着pH逐渐升高(pH5-8)化合物迅速分解,而分解产物α-亚甲基环戊酮类化合物证明是无效的。

The dissipation rate constants of malathion and methyl parathion with a concentration of 3mg/L and ethion, dicofol and cyhalothrin with a concentration of 0.5mg/L in 2000ml of 55-60g canna planted water sulution were respectively increased by 77. 66%, 117. 44%, 64. 80%, 38. 11% and 15. 35% compared to those in unplanted water solutions.

与不种植植物的对照相比,50-60g美人蕉对2000ml分别含有3mg/L的马拉硫磷、甲基对硫磷及0.5mg/L乙硫磷、三氯杀螨醇和三氟氯氰菊酯培养液中的马拉硫磷、甲基对硫磷、乙硫磷、三氯杀螨醇和三氟氯氰菊酯的消解速率依次分别提高了77.66%、117.44%、64.80%、38.11%和15.35%。

The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10% NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6% NaOH/4% urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.

本论文的主要创新点:(1)以NaOH水溶液/无水乙醇为凝固液,采用溶液纺丝法制备出保水性壳聚糖/聚乙烯醇纤维,共混和戊二醛交联极大提高了壳聚糖纤维力学性能;(2)用壳聚糖和明胶共混,以溶液纺丝法制备出可控降解的壳聚糖/明胶纤维,并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度;(3)确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系;(4)利用纤维素新溶剂6%NaOH/4%尿素制备出抗凝血性纤维素/甲壳素共混膜;(5)利用上述纤维素新溶剂制备出抗菌性纤维素/羧甲基壳聚糖共混膜,揭示了羧甲基壳聚糖取代度与抗菌性能的关系;(6)制备出可控降解壳聚糖交联膜。

A study was made on the application of dimethyl silicone oil ,propanetriol and 1,2 propanediol to decrease the modulus of MVQ vulcanizate.

探讨了用增塑剂二甲基硅油、丙三醇和1,2-丙二醇降低甲基乙烯基硅橡胶硫化胶模量的途径。

The intermixture of positive ion surfactant Cetyltrimethyl Ammonium Bromide and zwitterion surfactant N,N-C12BE was used to modify the natural zeolite. Correlative parameters of modified zeolite adsorbing Cr and phenol from wastewater were studied.

摘 要:用阳离子表面活性剂十六烷基三甲基溴化铵与两性离子表面活性剂 N,N-二甲基十二烷基甜菜碱复配的混合表面活性剂对天然沸石改性,研究了改性沸石吸附废水中 Cr 和苯酚的相关参数。

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