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3A biomimetic catalytic system M_n/CH_3CHO has been used in the selective oxidation of p-chlorotoluene.The effects of the center metal ions,the amount of catalyst and ethanal,the oxygen pressure,the reaction time,and the reaction solvents on the selective oxidation were investigated.

3将M_n/CH_3CHO仿生催化体系用于对氯甲苯的选择性氧化,研究了不同中心金属离子、催化剂用量、乙醛用量、氧气压力、反应时间及反应介质对反应的影响。

The results show that among the acetoacetonate complexes,Co_3 has the best catalytic activity.The optimum reaction conditions were as follows:0.764 mmol of Co_3,mole fraction of ethanal 10%based on the substrate,room temperature,oxygen pressure 2 MPa,reaction time 11h and solvent acetonitrile.Under these conditions,13.3%p-chlorobenzaldehyde was obtained with 15.3%conversion and 87.2%selectivity.The oxidation can also be carried out without solvent with 8.1%conversion,89.1%selectivity and 7.2%yield respectively.

在金属配合物中Co_3的催化性能最好,在其用量为0.764 mmol、乙醛用量为反应物物质的量的10%、氧气压力为2MPa时,以乙腈为反应介质,室温下反应11h,反应的转化率和选择性可达15.3%,87.2%,对氯苯甲醛收率可达13.3%;反应也可在无溶剂时进行,此时反应的转化率、选择性及醛的收率分别为:8.1%,89.1%,7.2%。

The optimum reaction condition was as follows: catalyst dosage=4.3% of the amount of ethanediol,reaction time 50 min.1,4-dioxane yield of 84.82% was obtained under the optimum condition.

考察了催化剂用量、反应时间和反应温度等因素对收率的影响,得出最佳反应条件:催化剂用量为乙二醇质量的4.3%,反应时间50 min,收率可达84.82%。

The effects of processing parameters on the OAF performance, such as the species and dosage of neutral oils, dosage of frother, pH value of the pulp, agitation time and rate, were investigated.

研究了中性油种类与用量、起泡剂用量、矿浆pH值、团聚时间及搅拌强度等因素对油团聚浮选过程的影响。

Among several neutral oils, transformer oil shows the best agglomeration effect. For the complex tailings, in which over 90% of molybdenum distributed in the range of -0.038 mm, the optimal dosage of transformer oil and frother was about 12 kg/t and 0.5 kg/t respectively, and the least agitation time and rate should above 3 min and 400 r/min, respectively.

结果表明,在众多中性油中,变压器油表现出了较好的油团聚浮选效果,对于钼金属分布率高于90%的-0.038mm粒级的浮选尾矿,其合适用量需达到12kg/t左右,与之配合的起泡剂用量在0.5kg/t左右,油团聚时间及搅拌强度分别需达到3min和400r/min以上。

As the foaming agent is the continued increase in frother dosage of 400g / t, the gas holdup appears the phenomenon of axial turning point was not obvious, the axial distribution of gas holdup tends to uniform.

随着起泡剂用量的继续增加,在起泡剂用量为400g/t时,气含率出现轴向拐点现象不明显,气含率轴向分布趋于均匀。

Implementation of conservation tillage, decrease of chemical fertilizer application, increment the rate of straw returning to field and organic fertilizer, should be the primary regulation direction of geoponic management in the future.

实施保护性耕作、降低化肥用量、提高秸秆还田量和有机肥的用量成为今后农业生产管理方式调整的主要方向。

Implementation of conservation tillage, decrease of chemical fertilizer application, increment the rate of straw returning to field and organic fertilizer, should be the primary regulation direction of geoponic management in the future.

实施保护性耕作、降低化肥用量、提高秸秆还田量和有机肥的用量成为今后农业生產管理方式调整的主要方向。

Results: All patients anemia were improved, the value of hemoglobulin in venofor group increased 19.2g per month, and was higher than that of Niferex (14.8g/month)(P.01). The dose of Epo in venofer group was lower than the Niferex group.

结果:用Epo后,2组患者贫血均改善,多糖铁复合物组Hb每月上升14.8 g/L,Epo用量比蔗糖铁组多19.5%;而蔗糖铁组可迅速改善CRF透析患者贫血,Hb每月上升19.2 g/L,Epo用量较小,与多糖铁复合物组比较差异有显著性(P.01)。

The Effect of different reaction conditions (solvent, reaction temperature, molar ratio of iodobenzene and acrylic acid, kind and amount of base, amount of catalyst, reaction time) on the yield was investigated. The suitable condition of the reaction was obtained.

考察了不同反应因素(溶剂、温度、原料比、缚酸剂及其用量、催化剂用量、反应时间)对反应的影响,确定了该催化剂对碘代苯与丙烯酸交叉偶联生成反式-肉桂酸的适宜反应条件。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?