用合成法合成

IV. The total synthesis of dehydrodiconiferyl alcohol and its dihydro-derivative The benzofuran skeleton was constructed by chemically oxidative couplingstarting from vanillin, then selective reduction with LiAI〓/〓 andhydrogenation in the presence of Pd-C followed reduction with LiAl〓respectively, to give dehydrodiconideryl alcohol and its dihydro-derivative, usefulin treating and preventing digestive system disorders, esp.

四、Dehydrodiconiferyl alcohol及其二氢衍生物的全合成以香草醛为起始原料，用化学氧化法一步建立氢化苯骈呋喃骨架，LiAlH〓／〓选择性还原以及催化加氢还原接着〓还原，分别合成了对预防和治疗消化系统疾病尤其是胃溃疡有显著效果的Dehydrodiconiferylalcohol及其二氢衍生物。

First we found some limitation lying in the chemical metathesis, especially in the controlling of the quality of the product and the velocity of the reaction. In the following research, we did some comparison experiment of synthesizing various nickel boride nanocrystal in the same principle, but by the two methods respectively.

另外，在试验过程中，我们逐渐发现了化学交换法的局限性，尤其在对反应进程和反应产物质量的控制方面的缺陷，并进一步通过分别用两种方法合成纳米硼化镍颗粒，合成原理相同，但反应产物相应发生较大变化。

The antimony doped tin oxide nanoparticles were synthesized at 240℃for 17 h by the complexing hydrothermal oxidation method using stannate, antimony white and sulphuric acid as the starting materials, sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant. The resulting powders were characterized by means of differential thermal analysis, infrared spectrometry, X-ray diffraction and transmission electron microscope. The mechanism of the preparation of ATO powder was investigated as well.

摘 要：以锡酸钠、锑白和硫酸为原料，酒石酸氢钠为配合剂，双氧水为氧化剂，采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时，合成单分散性的蓝色锑掺杂二氧化锡粉末，用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征，并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

The antimony-doped tin oxide nanoparticles were synthesized at 240℃ for 17h by the complexing-hydrothermal oxidation method using stannate, antimony white and sulphuric acid as the starting materials, sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant. The resulting powders were characterized by means of differential thermal analysis, infrared spectrometry, X-ray diffraction and transmission electron microscope. The mechanism of the preparation of ATO powder was investigated as well.

以锡酸钠、锑白和硫酸为原料，酒石酸氢钠为配合剂，双氧水为氧化剂，采用配合－水热氧化法在水热氧化温度为240℃和水热保温时间为17h时，合成单分散性的蓝色锑掺杂二氧化锡粉末，用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征，并对ATO纳米粉体的配合－水热氧化合成机理进行探讨。

The antimonydoped tin oxide nanoparticles were synthesized at 240 ℃ for(17 h) by the complexinghydrothermal oxidation method using stannate,antimony white and sulphuric acid as the starting materials,sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant.

以锡酸钠、锑白和硫酸为原料，酒石酸氢钠为配合剂，双氧水为氧化剂，采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时，合成单分散性的蓝色锑掺杂二氧化锡粉末，用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征，并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

The antimonydoped tin oxide nanoparticles were synthesized at 240 ℃ for(17 h) by the complexing hydrothermal oxidation method using stannate,antimony white and sulphuric acid as the starting materials,sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant.

以锡酸钠、锑白和硫酸为原料，酒石酸氢钠为配合剂，双氧水为氧化剂，采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时，合成单分散性的蓝色锑掺杂二氧化锡粉末，用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征，并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

Peptide synthesis. PMAP-23 peptide was synthesized by the solid phase method using Fmoc(9-fluorenyl-methoxycarbonyl)-chemistry.Rink Amide 4-methyl benz hydrylamine resin (0.55mmol/g) was used as the support to obtain a C-terminal amidate peptide.

多肽合成。萨夫- 23肽合成固相法芴-化学 try.rink 酰胺4 -甲基奔驰hydrylamine树脂( 0.55mmol /克)，被用来作为支持以获得一个c端酰胺肽。

The article adopted the method of orthogonal design using Polyethylene Glycol and Methacrylic Acid to esterify Polythylene-glycol-mono Methacrylate, then using PMA, MAA and Methacrylic Acid Sulfonic Sodium as raw material to synthesize Polycarboxylic type water-reducer.

用正交实验法研究了聚乙二醇和甲基丙烯酸酯化合成聚乙二醇单甲基丙烯酸酯的合成工艺，以该酯化物与MAA和甲基丙烯酸磺酸钠为原料，在引发剂的作用下合成聚羧酸系减水剂。

Layered double hydroxides pillaring with organic anion s CoAl-LDH are directly synthesized by a homogeneous precipitation method using the urea as a precipitiant,and the LDH products have been characterized through XRD,FT-IR,TGA and TEM.

以尿素为沉淀剂用均匀沉淀法直接合成有机阴离子柱撑水滑石(LayeredDoubleHydroxides，LDH)及CoAl水滑石等，并用XRD，FT-IR，TGA，TEM等分析手段对所合成的水滑石进行了表征。

In this dissertation, several novel halogen-free fire-retardant epoxy-based copper clad laminates were developed. Two kinds of phosphrous-containing epoxy resins were synthesized by different method. A novel nitrogen-containing curing agent 2,4, 6-tri (phenol-methylene -amide)-trizone was synthesized for preparing high-performance epoxy polymers, and the synthesis kinetics, cure kinetics and mechanism of MFP cured with DGEBA have been investigated by Differential Scanning Calorimeter and in situ Infrared.

本论文以开发新型无卤阻燃环氧树脂基覆铜板为目标，合成了两类结构不同的含磷环氧树脂以及一种新型的含氮固化剂2，4，6-三-均三嗪，考察了它们合成过程中的影响因素，用DSC和原位红外光谱法探讨了MFP固化环氧树脂的固化反应机理。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失