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甘油酯

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In the presence of DMAc/LiCl solvent, disproportionated rosin glycide-cassava starch ester was synthesized from cassava starch and modified disproportionated glycide ester under microwave irradiation. The effect of reaction conditions on the degree of substitution has been discussed.

在微波辐照下,以DMAc/L iC l为溶剂体系,歧化松香缩水甘油酯和木薯淀粉亲核开环反应得到歧化松香缩水甘油木薯淀粉酯,探讨了各反应因素对产物取代度的影响。

When induced to differentiate in the presence of Oleaceae oil (35-130 mg/ml), 3T3-L1 preadipocytes dose- dependently reduced their ability to accumulate cellular triglycerides. Cytoplasmic triglyceride droplets could also be visualized by microscopic observation. Cells treated with 130 mg/ml Oleaceae oil retained their morphology as spindly fibroblasts, while normal adipocytes take on a rounded shape filled with triglyceride droplets.

在开始刺激细胞分化的同时,以 35 mg/ml 到 130 mg/ml 不同的木樨科精油浓度处理细胞,为期八天,将分化到第八天的细胞收下来测三酸甘油酯的浓度当作分化程度的指标,结果发现随著木樨科精油浓度的增加,细胞所累积的三酸甘油酯浓度就越低,用显微镜观察即可发现细胞中脂肪油滴所占的比例明显降低。

In this study, isolate 23 microbes with lipase activity from Wu-Jie scrap heap at Ilan and Taichung Environmental Protection Section. When the microbes incubator in 50oC, there are isolates B61 and M63 that lipase activity are better than others. Brevibacillus borstelensis SH168 isolated from NTU resterant food waste compost is used as control check. Isolates B61, M63 and Brevibacillus borstelensis SH168 determine the lipase activity by the LB with tributyrin. The lipase activity of isolates B61 and M63 are 2~3 fold higher than Brevibacillus borstelensis SH168. So isolates B61 and M63 are more useful in producing lipase. Isolate B61 can grow at pH 5~9, and at temperature 20oC ~ 60oC; isolate M63 can grow at pH 6~10, and at temperature 30oC ~ 50oC. Isolates B61 and M63 were identified by 16S rRNA. Isolate B61 is Bacillus circulans, and isolate M63 is Bacillus species.

本研究,於宜兰五结垃圾场和台中市环保局厨余堆肥样品中共分离出 23 株具脂肪酶活性菌株, 23 株菌株中经过三油酸甘油酯的洋菜培养基於 50℃培养 5 天后,发现有 2 株菌的脂肪酶活性较强,分别为分离株 B61 和 M63;以本实验室先前自台大女九餐厅蔬果厨余堆肥中所筛选出的耐高温脂解菌 Brevibacillus borstelensis SH168作为本实验对照菌株,将分离株 B61、M63 及 Brevibacillus borstelensis SH168 3 株菌株於含有三酪酸甘油酯液态培养基培养并测定其脂肪酶活性,发现分离菌株之活性皆比 Brevibacillus borstelensis SH168 高出 2~3 倍,认为分离株 B61、M63 适於产生脂肪酶的菌株,分离株 B61 在 pH 5~9 皆可生长,生长温度介於 20 oC ~ 60oC;分离株 M63 在 pH 6~10 可生长,生长温度介於 30 oC ~ 50oC; 2 株分离菌株以 16S rRNA定序结果分离株 B61 为 Bacillus circulans,分离株 M63 为 Bacillus 属。

Biodiesel enhancements: Fixed physical properties of triolein and added interaction parameters for triolein + water.

生物柴油的强化:修复了三油酸甘油酯的物性,增加了三油酸甘油酯和水的二元交互作用参数。

Using Novozym 435 as catalyst, transesterification of ethyl ferulate with triolein to form ferulyl oleins in solvent-free medium was investigated.

以Novozym435脂肪酶为催化剂,以阿魏酸乙酯和三油酸甘油酷为底物,合成阿魏酸双油酸甘油酯

Fat tissue is hydrolyzed and released fatty acid as well triolein by lipase; on the other hand, high fat diet can't be directly absorbed across the intestinal mucosa.it must be firstly decomposed into one 2-monoglyceride and two free fatty acids by pancreatic lipase ,which is delivered into the lumen of the gut as a constituent of pancreatic juice.

脂肪酶能够使体内的多余脂肪组织分解成三酸甘油酯,另一方面,人体摄入高脂肪食物,并不能直接被小肠粘膜吸收,而是先被小肠内的胰脂肪酶分解成2-单酸甘油酯和两个游离脂肪酸,然后和胰液一起被运输到肠道的内腔被吸收。

The composition of fatty acids in oil and fat was detected by gas chromatography and fire ionization detector at home,however,the reports about the separation and detection of triglyceride in oil and fat were very little.

对油脂的分析,国内主要是采用气相色谱分离和火焰离子化检测器检测其中的脂肪酸组成,而对甘油酯的分离和检测报道较少,国外研究者利用色谱和质谱联用技术对甘油三酯的分离和检测做了大量的研究。

Enzymatic synthesis of glycerides directly from glycerol and polyunsaturated fatty acids was studied.

研究了在脂肪酶N435的催化作用下,游离多不饱和脂肪酸与甘油酯化合成的工艺,分别考察了甘油与脂肪酸的质量比、反应时间、反应温度、酶用量、初始加水量等单因素对酯化效果的影响。

1H NMR ; 13C NMR ; Saturated fatty acid glycerides ; Unsaturatcd fatty acid glycerides ; Estimation of integration .

~1H NMR ;~(13)C NMR ;饱和脂肪酸甘油酯;不饱和脂肪酸甘油酯;积分值

Using N,N′-dimethy-p-toluidineas the catalyst,bisphenol A-glycidyl methacrylate,the resin matrix in most dental composite restorative materials,was synthesized by the reaction of bisphenol A and glycidyl methacrylate,and characterized by FTIR,~1HNMR and M S.

以N,N-二甲基对甲苯胺为催化剂,双酚A和甲基丙烯酸缩水甘油酯为原料合成了一种常用的口腔修复材料树脂基质———双酚A双甲基丙烯酸缩水甘油酯,并用FTIR1、HNMR和质谱对其结构进行表征。

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