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With temperature increasing, granular outshoot prefer to grow along with vertical direction of surface of BN core, as well as the wrapped leaf-like shape form from granular ones. And the productions always kept complete morphology of sphere, which was due to the uniform growth of fluffy film on the BN core. Wrapped leaf-like structure of BN piece in fluffy film favored increasement of measured surface area and elimination of oxygen element.

凝并在球核表面的中间产物受到初始BN球核在空间上的诱导作用,随着温度的升高,突出物倾向沿着垂直于球面的方向向外生长,形貌由普通的粒状转变为卷叶状;绒膜的厚度均匀一致,产品得以保持规整的球状形貌,绒膜中卷叶状的BN结构利于氧杂元素的脱除,同时增加了比表面积。

Accounting for the characteristics of freeze-drying of granular material, a theoretical heat transfer model of atmospheric freeze-drying in spherical geometry was developed. The temperature distribution and movement distance of sublimation interface were calculated, then the speed of drying process can he deduced. Theoretical analysis was done on influence factors such as bed temperature, material size and adsorbent diameter.

以粒状物料为例,建立了球坐标下常压冷冻干燥的传热过程理论模型,计算了物料干燥过程中的温度和升华界面的移动距离,并对床温、物料尺寸和吸附剂粒径等影响因素进行了理论分析。

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