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玻璃化

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Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示:复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素,它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性,还有乳液涂膜的接触角等造成不同程度的影响;引发剂主要影响反应速率和凝胶率;丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度,有机硅单体主要影响涂膜的吸水率等;聚合反应温度主要影响乳液的反应速率和转化率等;搅拌强度主要是影响到聚合过程的凝胶率。

We analysed precursor solidification mechanism,pointing out that solidification mechanism is crystallization,congelation and glass transition.

文章分析了纤维的固化机理,指出固化机理有三个:冻胶、结晶和玻璃化转变,其中蕴晶结构对聚丙烯腈基碳纤维原丝结构有重要影响。

Firstly, the characteristic of CPA is investigated.

首先对联合玻璃化保护剂的特性进行了研究。

The conformation of disulfide bonds, secondary structures, crystallinity and α-crystallinity of the cashmere fiber are changed after the cashmere yarn is steamed above 120℃ in relaxed and stretched state or crabbed at 98 ℃, 130℃ for different time, which is firstly found out. These structure changes of the treated cashmere fiber are related to temperature, time, and moisture content and tensile during heat treatment.

首次提出了山羊绒纱线在张紧状态、松弛状态经120℃蒸汽处理不同时间、经98℃、130℃的沸水松弛热处理后纤维二硫键构象、蛋白质分子链二级结构、结晶度以及玻璃化温度均发生变化,这些变化与热处理过程中的温度、时间、含水率及张力等因素有关。

There are two decalescence peak of the composite of wheat straw-PVC, and its melting point is not clear.

应用熔点和玻璃化转变温度这两项高分子材料的重要指标对麦秸与EVA、PE、PVC之间的热反应特征进行分析,可以了解它们之间的反应状况。

The first polymer particles have a glass transition temperature in the range of from -20 DEG C.

该第一聚合物颗粒的玻璃化转变温度为-20至25℃。

The model correctly predicted and explained the effect of cooling rate and warming rate on the intracellular ice formation during the cooling and warming process. The cooling and warming rate which can realize vitrification and avoid devitrification was gained. This is to say, when the cooling rate is not less than 400℃/min and the warming rate is not less than 500℃/min, intracellular ice formation can be avoided.

模型预测和解释了降温和复温过程中冷却速率和复温速率对胞内冰形成的影响,同时提出了成功实现脐带血干细胞玻璃化的降温速率和复温速率应不低于400℃/min和500℃/min的结论。

The high temperature of drying GFCMP results in the devitrification of final product with the of fluor apatite and quartz, and greatly lowered dissipation in water, based on Xray diffractionanalysis.

通过圆盘式破碎机湿料破碎及喷流传热恒温干燥这 2项关键技术创新,对原 2万 t/ a粒状钙镁磷肥生产工艺进行了改进使之达产,并使产品完全避免了反玻璃化,达到国际市场的品质要求。

The effects of the dosages of initiators, emulsifier, organicsilicon and 2-Hyciroxypropyl acrylate on conversion and graft efficiency were studied. Moreover, the particle morphology, particle size distribution and glass transition temperature of latex were characterized by Transmission Electron Microscopy, size distribution analyzer and Differential Scanning Calorimetry.

考察了引发剂用量、乳化剂用量、有机硅用量、丙烯酸羟丙酯用量对硅-丙核/壳乳液转化率、接枝率的影响,并借助透射电镜、粒度分布仪和差示扫描量热仪分别对乳胶粒形貌、粒径分布及其玻璃化转变温度进行了表征。

In order to understand the polymer chain conformations above and below the glass transition temperature, dihedral angle distributions of polymer chains at various temperatures are also studied.

为了了解高分子链构象在玻璃化转变温度之上和之下的变化,对高分子链在不同温度下二面角分布也进行了研究

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