环铵

We have used GC to follow up the formation of epoxy acid and established the acidify condition; we have done series of parallel experiments to better the pivotal condensation reaction between acid and amine; In the cyclization step, we use cheap and available reagent-Lithium amide , rather than expensive LiHMDS, to proceed the reaction; and at last, we introduced green reagent-ozone to clear the phenyl group of nitrogen to avoid using heavy metal reagent-CAN. The total yield for this method is 29.8%.

通过GC监测，确定环氧酸的最佳酸化条件；对关键的酸和胺的缩合步骤，平行试验了多种条件；在环合一步，用价廉易得的氨基锂及催化量的HMDS代替昂贵的LiHMDS进行反应；氮上苯基的脱除采用臭氧，避免了重金属试剂-硝酸铈铵的使用，总收率为29.8％。

Main products: Ifosfamide,Ifosfamide acylate,2-Deoxy-D-Glucose, Vecuronium Bromide Oteracil Potassium,Gimeracil,Cinildipine,, Ceftiofur Hcl,Ceftiofur Sodium,Buflomedil Hcl

主要产品有：异环磷酰胺、异环磷酰胺酰化物、2-脱氧-D-葡萄糖、维库溴铵、盐酸头孢噻呋、头孢噻呋钠、氧嗪酸钾、吉莫斯特、西尼地平、盐酸马尼地平、培美曲塞、培美曲塞酸、培美曲塞二钠、尼索地平、消旋卡多曲、雷尼酸锶、盐酸丁咯地尔、1-(3-三氟甲基苯基)哌嗪盐酸盐、4-溴-2-甲基苯甲酸。

Main products: Ifosfamide,Ifosfamide acylate,2-Deoxy-D-Glucose,Vecuronium Bromide, Ceftiofur Hcl,Ceftiofur Sodium,Buflomedil Hcl,Oteracil Potassium,Gimeracil,Cinildipine,Manidipine dihydrochloride,Pemetrexed intermediate,Pemetrexed acid,Pemetrexed Disodium, Nisoldipine, Racecadotril, Strontium Ranelate, 1-(3-Trifluoromethylphenyl)piperazine hydrochloride, 4-Bromo-2-methylbenzoic acid.

主要产品有：异环磷酰胺、异环磷酰胺酰化物、2-脱氧-D-葡萄糖、维库溴铵、盐酸头孢噻呋、头孢噻呋钠、氧嗪酸钾、吉莫斯特、西尼地平、盐酸马尼地平、培美曲塞、培美曲塞酸、培美曲塞二钠、尼索地平、消旋卡多曲、雷尼酸锶、盐酸丁咯地尔、1-(3-三氟甲基苯基)哌嗪盐酸盐、4-溴-2-甲基苯甲酸。

Main products: Ifosfamide,Ifosfamide acylate,2-Deoxy-D-Glucose,Vecuronium Bromide, Ceftiofur Hcl,Ceftiofur Sodium,Buflomedil Hcl,Oteracil Potassium,Gimeracil,Cinildipine

主要产品有：异环磷酰胺、异环磷酰胺酰化物、2-脱氧-D-葡萄糖、维库溴铵、头孢噻呋、头孢噻呋钠、氧嗪酸钾、吉莫斯特、西尼地平、马尼地平、培美曲塞、培美曲塞酸、培美曲塞二钠、尼索地平、消旋卡多曲、雷尼酸锶、盐酸丁咯地尔、1-(3-三氟甲基苯基)哌嗪、4-溴-2-甲基苯甲酸。

Main products: Ifosfamide,Ifosfamide acylate,2-Deoxy-D-Glucose,Vecuronium Bromide, Ceftiofur Hcl,Ceftiofur Sodium,Buflomedil Hcl,Oteracil Potassium,Gimeracil,Cinildipine, Manidipine dihydrochloride,Pemetrexed intermediate,Pemetrexed acid,Pemetrexed Disodium, Nisoldipine, Racecadotril, Strontium Ranelate, 1-(3-Trifluoromethylphenyl)piperazine hydrochloride, 4-Bromo-2-methylbenzoic acid.

主营业务：主要产品有：异环磷酰胺、异环磷酰胺酰化物、2-脱氧-D-葡萄糖、维库溴铵、盐酸头孢噻呋、头孢噻呋钠、氧嗪酸钾、吉莫斯特、西尼地平、盐酸马尼地平、培美曲塞、培美曲塞酸、培美曲塞二钠、尼索地平、消旋卡多曲、雷尼酸锶、盐酸丁咯地尔、1-(3-三氟甲基苯基)哌嗪盐酸盐、4-溴-2-甲基苯甲酸。

The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法，包括二异氰酸酯在催化剂的存在下进行反应，其中所述催化剂由盐化合物组成，该盐化合物由选自1，2，3-或1，2，4-三唑、1，2，3-或1，2，4-三唑的取代系列者、1，2，4-三唑的碳环稠合系列者、1，2，3-或1，2，4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

With trimethyl,4-dodecylbenezyl ammonium chloride and 18-crown-6 as pase-transfer catalysts, the azidation of polyepichlorohydrin in poly and H2O were studied. The reaction discipline and mechanism were discussed. The results show that the system with trimethyl, 4-dodecylbenezyl ammonium chloride as phase transfer catalyst and PEG as medium is a safe and effective approach to glycidyl azide polymer preparation, and azidational ratio of PECH can reach 97% above within 15 h.

研究了氯化十二烷基苄基三甲基铵和18-冠－6为相转移催化剂时端羟基聚环氧氯丙烷在聚环氧乙烷和水为介质中的叠氮化反应，探讨了反应规律和反应机理，结果表明：以PECH为介质，十二烷基苄基三甲基氯化铵(TMDA-1)为相转移催化剂的反应体系，可在15h内使PECH叠氮化转化率达到97%以上，无主链断裂等副反应，是一条较为安全快速的制备叠氮粘合剂的方法。

In this paper, varied factors which influenced the synthesis of epoxypropyl trimethyl ammonium chloride by the reaction of epichlorlhydrin with trimethylamine were studied.

研究了由环氧氮丙烷与三甲胺反应合成环氧丙基三甲基氮化铵沥青乳化剂中间体的各种影响因素。

The different catalytic systems are discussed. The results show that sodium tungstate has effective catalytic ability.

实验结果表明，钨酸钠和双季铵盐催化体系能在温和的条件下，催化稀过氧化氢溶液氧化环己醇、苯甲醇、环己烯。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺；NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢；NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失