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The recent research progress of oxidation carbonylation of amines/β-amino alcohols, alkoxycarbonylation of epoxides, carbonylative Suzuki coupling, carbonylative Sonogashira, and double carbonylation of aryl iodides has been presented, focusing on the carbonylation reactions studied by us in the past few years, with 81 references.

综述了胺/氨基醇类化合物氧化羰化、环氧化合物氢酯基化、碘代芳烃的羰化Suzuki偶联、羰化Sonogashira以及双羰基化等重要羰基化反应的研究状况,特别是结合本课题组近年来在该领域中的工作,并对羰基化反应的发展及应用前景进行了展望。

Ketamine , the phencyclidine derivative described in 1965 , is an intravenous anesthetic with a variety of applications .

氯胺酮,苯环衍生的描述于1965年,是一个与静脉麻醉的各种应用。

Epoxy resin hardener ; aromatic amine ; Low-melting point ; heat resistance.

环氧固化剂;芳香胺;低熔点;耐高温

Keywords: polynuclear complexes; bridged-ligands; anti-cancer drug; 1,10-phenanthroline; dioxotetraamine macrocycle

中文关键词:多核配合物;桥联配体;抗癌药物; 1,10-菲罗啉;二氧四胺大环

Examples of metal chelating groups include hydroxides especially aryl or heteroaryl hydroxides such as phenolic hydroxides; amines which may be aliphatic aryl or heteroaryl; mercaptans which may be aliphatic aryl or heteroaryl; carboxylic acids which may be aliphatic aryl or heteroaryl; oximes and ketoximines; acetarylamides; hydroxy silanes and silicones; N-containing heterocycles such as imidazoles benzimidazoles triazoles benzotriazoles thiazoles isothiazoles acid anhydrides and more preferably acid groups (especially carboxylic acid groups phosphoric acid groups polyphosphoric acid groups phosphonic acid groups sulphuric acid groups and sulphonic acid groups).

金属螯合组的例子包括氢氧化物,特别是芳基或如酚醛氢氧化物杂氢氧化物;胺可能是脂肪族,芳基或杂;硫醇可能是脂肪族,芳基或杂,这可能是脂肪族,芳基或羧酸杂;肟和ketoximines; acetarylamides;羟基硅烷和有机硅,含N,如咪唑,苯并咪唑类,三唑类,苯并三氮唑,噻唑类,isothiazoles,酸酐杂环,多最好酸组(特别是羧酸团体,磷酸,团体,多聚酸组,膦酸组,硫酸团体和磺酸组)。

A novel ligand, N, N'-bis (2-hydroxy-1-naphthylidene)-3-oxa-1, 5-diaminopentane , and its Zn , Ni , Co , Cu complex were synthesized. The compositions and structures of the ligand and its complexes were characterized by elemental analyses, MS , IR spectra, DTA-TG and molar conductivity.

合成了含萘酚环Schiff碱开链冠醚配体H〓L〓(N,N'-双-二甘醇二胺)及其过渡金属(Zn、Ni、Co、Cu)配合物,通过元素分析、质谱、红外光谱、摩尔电导对配体及配合物的组成、结构进行了详细的表征,对配体和配合物的溶液和固体荧光性质进行了研究。

Adoping the simple and easy anthology to gather the unit to gather urine of 5 hours measures, Watch different series of urine quantitative changeization .(2) Experiment of immunity: Adopted CY methods copy immunity to repress the little rat pattern, To divide randomly small healthy white mice originated from kunming into normal contrast group ,pattern group, Fulin group, Guizhi group,Fulin and Guizhi group (Two medicine are according to 1 : 1、2: 1、 1: 2、 4: 3 the proportion compose ).Be total to 8 groups . To observed Fulin and Guizhi different combinition adjust the repressing small mice's spleen and thymus, Ascertaining by measuring little rat phagocyte the gobbleing uprate and serum IL-2 -* TNF — a 's content.

2免疫实验采用环磷酰胺法复制免疫抑制小鼠模型,健康昆明种小鼠随机分为正常对组、模型组、茯苓组、桂枝组、茯苓与桂枝配伍组(两药按1:1、2:1、1:2、4:3比例进行组合)共8组,观察茯苓桂枝药对及其各配伍组对免疫抑制小鼠脾、胸腺的影响,测定小鼠吞噬细胞吞噬率及血清IL-2、TNF—α含量。

Cyclometalated IrIII complexes with mixed phenylpyridine and diimine ligands have also been demonstrated to be versatile luminophores for biolabelling and bioimaging with tuneable luminescent colour.

3混合苯基环金属配合物IrIII 与二亚胺配体也被证明要为biolabelling和bioimaging多功能发光用可调谐发光颜色。

Objective To investigate the cel lular immune function influence on postoperative patients with hepatocellular carcinoma and clinical effect of TILs, rIL-2 and cyclophosphamide treat ment.

目的 探讨肿瘤浸润性淋巴细胞、rIL-2和环磷酰胺治疗对原发性肝细胞癌患者术后细胞免疫功能的影响和临床疗效。

Methods Eight postoperative HCC patien ts were treated with TILs, rIL-2 and cyclophosphamide.Six patients were infu sed from the hepatic artery, and the other 2 infused from the portal vein.

方 法 对8例HCC术后患者进行了TIL、rIL-2和环磷酰胺治疗,6例从肝动脉插管输入,2例从门静脉插管输入。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。