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Synthesis of the antiepileptic tiagabine hydrochloride;2. Starting from tetrafuran, 2_(4_Aminosulfonylphenyl)_4H_1,2_thiazine_1_dioxide, an antiepileptic drug with special structure, was obtained via esterification, sulphonation, chloridization, condensation and cyclization.

以四氢呋喃为原料,经酯化、磺化、酰氯化、缩合、环化等步骤,合成了化学名为 4_(四氢_2H_1,2_噻嗪基_2 )苯磺酰胺_S_S_二氧化物的抗癫痫药舒噻嗪,通过IR、1HNMR和元素分析对其结构进行了表

It is found that the stereochemistry of the reactions of telluronium allylide,crotonylide and trimethylsilyallylide with α,β-unsaturated esters and amides can be tuned by thechoice of reaction conditions.

利用反应条件的变化首次实现了烯丙基、巴豆基、含硅烯丙基碲叶立德与α,β-不饱和酯、酰胺进行环丙烷反应的立体化学调控,能高立体选择性地、高效率地合成两种不同几何异构体中的一个。

Tang X, Gao J, Wang Y, et al. Effective protection of Terminalia catappa L.leaves from damage-induced by carbon tetrachloride in liver mitochondria[J].

本实验观察到环磷酰胺低、中剂量组的小鼠肝脏线粒体中VDAC的转录水平较对照组有所下降,而高剂量组则略高于正常对照组。

Diaminoalkanes react with sym - tetrachloroethane to give crystaline 2,2'- Bis -( hexahydropy-rimidine) derivatives 1 - 5, after treatment with aqua ammonia.

利用均四氯乙烷及二氯甲烷的胺化反应,合成了联氢化嘧啶衍生物1~5,4a,8b-反-4,5,8a,9a-四氮杂全氢芴(6)和8b,8c-顺-3a,4a,7a,8a-四氮杂环戊并全氢芴(7)。

Therefore, in the laboratory, a 2L gasliquid equilibrium measurement device was used to measure the equilibrium solubility of H2S, CO2, CH3SH and COS in the mixed solutions of Methyldiethanolamine, Tetramethylene sulfone respectively under different temperatures and different proportions. With the relevant parameters being correlated from the measured data, a corresponding thermodynamic calculation model was set up, based on the gasliquid two phase state equilibrium equation, and in combination with the overseas research results.

为此,在实验室利用容积为2 L的气液平衡测定装置,测定了不同温度和溶液配比条件下硫化氢、二氧化碳、甲硫醇、硫氧碳在甲基二乙醇胺(Methyldiethanolamine,MDEA)、环丁砜(Tetramethylene sulfone,TMS)水溶液中的平衡溶解度,并根据气液两相平衡状态方程,结合国外研究成果,利用测定的平衡溶解度数据关联出相关参数,建立了相应的热力学计算模型,用于预测该复杂体系中酸气分压与溶液负荷的气液平衡关系。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1,4-丁二胺催化氧化环己烷的催化活性被测试,结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性,而单核的Fe化合物是非催化活性的。

The pyrrole, oxazoles, pyridinones, quinolines, dibenzodiazepines, tetrahydrobenzoxazines and tetronic acids have been prepared from enaminones.

吡咯、唑烷、嘧啶酮、喹啉、二苯并二氮杂环类、四氢苯并噁嗪酮和特窗酸等都可以由烯胺酮类化合物制得。

Piperidine oxoammonium salts oxidize aromatic amines and N, S-containing heterocycles to the corresponding radical cations, and the isotope effects in electron transfer reactions between thianthrene and N-methylphenothiazine radical cations and their respective neutral parent molecules have been reported for the first time.

啶氧铵盐氧化芳95胺和含氮、硫芳杂环为相应的自由基正离子,首次报道了及甲基吩自由基正离子与其中性母体之间电子转移的同位素效应。

Piperidine oxoammonium salts oxidize aromatic amines and N, S-containing heterocycles to the corresponding radical cations, and the isotope effects in electron transfer reactions between thianthrene and N-methylphenothiazine radical cations and their respective neutral parent molecules have been reported for the first time.

哌啶氧铵盐氧化芳香胺和含氮、硫芳杂环为相应的自由基正离子,首次报道了噻蒽及甲基吩噻嗪自由基正离子与其中性母体之间电子转移的同位素效应。

This paper reviews the recent progress on the Chinese syntheic research of marine natural products according to type classifications: marine cyclopeptides, cembranes, cembrenss, cembranolides, quinolone derivativcs, triacetonamine and subergorgic acid analogues.

本文综述中国海洋天然产物合成研究的最新进展,包括海洋环肽、西松烷和西松烷型二萜内酯、喹啉酮衍生物和三丙酮胺以及柳珊瑚酸类似物等。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。