环胺

A novel epoxy resin was obtained through the condensation reaction of the azomethine and epichlorohydrin in NaOH solution.

通过对羟基苯甲醛双缩对苯二胺席夫碱与环氧氯丙烷在NaOH液中缩合，合成一种新型环氧树脂。

The key step involves reduction-amination of benzamine and -acetonide glycealdehyde 20 synthesized from cheap and available ascorbic acid . The hydrolysis product of 21 condensed with triphosgene to get 6, key intermediates of Linezolid and Eperizolid. After a series of reactions, we got Linezolid and Eperizolid in reasonable yields and purity. The spectrum and 〓 values of compounds 6 and other intermediates were identical with literature reported.

我们以国内非常便宜易得的维生素C为原料合成得到-丙酮保护的甘油醛20，20和取代苯胺经还原胺化反应制备得到二噁烷21，21水解后与三光气缩合成环得到利奈唑酮和埃皮唑酮的关键中间体6.6经一系列的反应合成得到了利奈唑酮和埃皮唑酮。6及一些中间体的〓D值与文献报道的数据相吻合。

In the three systems, system realizes the crosslinking of PVC bases on the peroxide crosslinking mechanism, the tensile strength of crosslinked PVC has been improved somewhat, the IR spectrum of gel demonstrates that there are characteristic absorption peaks of n-alcohol that belongs to ethanol amine and benzenoid group. From the analysis of gel structure , deduces that the mechanism of crosslinking reaction: under the initiations of peroxide and high temperature, PVC yields macromolecules free radicals, at the same time , styrene"s polymerization and grafting onto PVC takes place, at last the system forms crosslinking structure through coupling between radicals; confirms that triethanol amine can absorb HC1 produced by degradation of PVC, so improves the crosslinking efficiency of peroxide, decreases the HCl"s promotion for PVC"s degradation; deduces that triethanol amine can activate the PVC macromolecules and prolong the free radicals" life-time of PVC macromolecules; the effect to the PVC macromolecule makes styrenes graft reaction easy, and thus improves the crosslinking efficiency.

三种体系中三乙醇胺/过氧化二异丙苯/苯乙烯体系基于过氧化物交联机理实现了聚氯乙烯的交联，聚氯乙烯交联后拉伸强度有一定提高，凝胶红外光谱分析证实了凝胶结构中含有乙醇胺的伯醇基团特征吸收和苯环的特征吸收，由凝胶结构分析，推断出交联反应的机理：聚氯乙烯在过氧化物和热作用下产生大分子自由基，苯乙烯在过氧化物和大分子自由基的作用下发生聚合和接枝反应，最终通过自由基之间的偶合产生交联；证实三乙醇胺可以吸收聚氯乙烯分解产生的HCl，提高了过氧化物的交联效率，消弱了HCl对聚氯乙烯降解的促进作用；推断三乙醇胺可以活化聚氯乙烯大分子并有可能使聚氯乙烯大分子自由基存在的时间得以延长，对聚氯乙烯大分子的作用使苯乙烯的接枝反应易于发生，从而提高了交联效率。

A series of 2-acetylformanilides were prepared,followed by thiolation with Lowesson reagent to afford 2-acetylthioformanilides,which further reacted with Mn3·2H2O in glacial acetic acid under microwave irradiation to afford 2-acetyl benzothiazole s.

合成了一系列的硫代酰胺，研究了它们在微波辐射醋酸锰作用下发生氧化自由基环化反应，成功地合成了一系列2-乙酰基苯并噻唑衍生物，其结构经红外光谱、核磁共振谱和质谱得到了证实

Objective: To study the effects of the benzylamine compounds on antifungal activities after introducing large substitutes to the α-C of side chain of naphthalene ring.

目的：研究在萘环侧链α位引入大基团对苄胺类化合物抗真菌活性的影响。

The introduction of large substitutes to the α-C of side chain of the naphthalene ring reduces the antifungal activitie s of benzylamine compounds.

在萘环侧链α位引入大基团降低了苄胺类化合物的抗真菌活性。

The resonance stabilization is shown to be absent in the bicyclic β-lactams.

指出在双环β-内酸胺中缺乏共振稳定性。

Among the organophosphorus flame retardants, caged bicyclic phosphates have been in greatfavor, and many investigations have been done about them. It is found that caged bicyclicphosphates and their derivatives can serve as effective flame retardants to some polymers.

以季戊四醇为基的双环笼状磷酸酯及其衍生物兼具丰富的碳源和酸源，与三聚氰胺等配合使用可发挥良好的膨胀阻燃作用，因此它们的合成和应用倍受研究者的关注。

The separation of optical isomers of 2, 2'-dihydroxy-1, 1'-binaphthyl and 2, 2'-diamino-1, 1'-binaphthyl was studied by reversed-phase high performance liquid chromatography on a chiral stationary phase consisting of-hydroxypropyl-β-cyclodextrin (Cyclobond Ⅰ 2000 SP)using methanol/water as the mobile phase. The effects of mobile phase ratio, flow rate and column temperature on separation of optical isomers of DHBN and DABN were investigated.

在S-羟丙基－β-环糊精手性柱(CyclobondⅠ2000 SP)上用反相高效液相色谱法研究了2，2'-二氨基－1，1'-联萘和2，2'-二羟基－1，1'-联萘光学异构体的分离，考察了流动相组成、流速以及柱温等对联二萘胺和联二萘酚光学异构体分离的影响。

In the fifth chapter, six compounds formed between nitrogen-containing ligands such as 2, 2'-bipyridyl, isonicotinamide and 1, 4, 8, 11-tetraazacyclotetradecane and the solution cadmium sulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate, 4, 4'-bipenyldisulfonate and 4, 4'-penyletherdisulfonate have been synthesized and structurally characterized. Besides, another compound has been synthesized with cadmium carbonate reacting with 1, 5-naphthalenedisulfonate acid.

第五章以2，2'-联吡啶、异烟酰胺和1，4，8，11-四氮杂环十四癸烷与含有Cd〓和1，5-萘二磺酸根离子、2，6-萘二磺酸根离子、4，4'-联苯二磺酸根离子和4，4'-苯醚二磺酸根离子的水溶液反应，合成了六个化合物，另外以1，5-萘二磺酸与碳酸镉反应合成出一个化合物。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失