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A new imidazolinyl intermediate is prepared from phenylacetic acid and diethylenetriamine firstly, and then they react with the solution of sodium chloroacetate into the imidazolinyl quaternary ammonium salt.

以二甲苯为溶剂,苯乙酸和二乙烯三胺为原料,经酰胺化和环化脱水合成了新型咪唑啉化合物,并用氯乙酸钠溶液对其进行改性得到了苯乙酸咪唑啉季铵盐。

In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物,并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能,具体内容包括以下几个部分:设计合成了3个中位直接被三芳胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三芳胺共轭体10a-c,通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

Base on the result, a new antiarrhymic drug model was established, and the molecular mechanism was clarified why matrine and berbamine were not so effective on arrhythmia compared to amiodarone and RP58866. The antiarrhythmic mechanism of Chinese traditional drugs cyclovirobuxine D and water extracts from codyceps sinensis was investigated, and a scheme was produced to potentize the afficacy of antiarrhythmic Chinese traditional drugs.

在此基础上,建立了一种新的抗心律失常药物模型,阐明苦参碱和小檗胺抗心律失常作用弱于胺碘酮和RP58866的分子机制;并探讨了中药环维黄杨星D、冬虫夏草水提液抗心律失常作用机制,提出了增强抗心律失常中药效能的方案。

Biogenic amines are basic nitrogenous compounds formed mainly by decarboxylation of amino acids or by amination and transamination of aldehydes and ketones.

生物胺是一类含氮的脂肪族、芳香族或杂环类低分子化合物,主要是通过氨基酸的脱羧或醛和酮的胺化和转氨基作用形成的。

To study the relationship between the "tail" structure and the characteristics of Gemini surfactants, a new gemini surfactant CH(subscript 2s)-αω-Bis (dehydroabietyihydroxypropyltetramethylethyldiammonium Chloride) here s=2, has been synthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The affections of reacttants ratio, reaction temperature and time on the yield of aimed compound have been discussed.

研究了Gemini表面活性剂中疏水&尾巴&结构对性质的影响,以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯,再与四甲基乙二胺反应,得到1种以脱氢松香酰基为疏水链&尾巴&的对称Gemini型双季铵盐阳离子表面活性剂:二氯化-N,N'-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

To study the relationship between the hydrophobic "tail" structure and thecharacterizations of Gemini surfactants, a new gemini surfactant CsH2s-α,ω-bis(dehydroabietylhydroxypropylteteramethylethylammonium Chloride),here s=2, wassynthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The impact factorsin the two steps are discussed.

为研究gemini表面活性剂中疏水&尾巴&结构对性质的影响,本论文以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯,再与四甲基乙二胺反应,得到一种以脱氢松香酰基为疏水链&尾巴&的对称gemini型双季铵盐阳离子表面活性剂:二氯化-N,N′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

The structural characteristics of the ligand of the chiral Schiff base are that the ligand has phenol hydroxyl, alcoholic hydroxyl and an imine group, one to three bromine atoms are provided on the framework of double benzene nucleus, and chiral carbon is connected with the nitrogen atom of imine.

手性西佛碱配体的结构特征为含有酚羟基、醇羟基和亚胺基团,在萘环骨架上带有一至三个溴原子,手性碳与亚胺的氮原子相连。

Objective To study the effects of berbamine and batiolun on LDH metabolizability in the process of increasing leukocyte.Methods Enzyme biochemical techniques is used to study the effect of berbamine and batiolˉun in the process of inceasing leukocyte and also to study the effect of LDH metabolizability.

目的 研究小檗胺和鲨肝醇升高白细胞作用及对细胞内LDH的代谢的影响方法采用酶细胞化学方法,对两药物在治疗由免疫抑制剂环磷酰胺所致的白细胞减少症时,对乳酸脱氢酶活性的影响进行了比较观察。

Thermal imidization of the polyamic acid derived from BPADA and BAPS was investigated mainly by GPC and FTIR equipped with an in-situ hot cell.

利用GPC、原位FTIR测定了长链聚酰胺酸PAA由双酚A二酐与 4 ,4′-二(4-胺基苯氧基二苯酚制备的热环化过程。

The structures of the isomers were assigned by using 2D NMR techniques such as gCOSY. Comparing to the eluates from the chromatographic column, the first band contains the m2, the second band contains the ml.

利用一维及二维核磁共振(2D NMR)技术,结合三元胺中吡啶环的磁屏蔽效应,对两个异构体在溶液中的结构进行了解析,对应于Dowex 50Wx 2柱色层分离的第一包带的H离子为n2(cmen的2位胺基与Cl处于邻位):第二色带的阳离子为ml。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。